3-Bromocyclohexene 3-溴环己烯

CAS 1521-51-3 MFCD00013775

化学结构图

1521-51-3
SMILES: BrC1C=CCCC1

化学属性

Mol. FormulaC6H9Br
Mol. Weight161.04
Density1.400
Refractive index1.5270 to 1.5320
Boiling Point57-58 °C at 12 mmHg
Flash Point54°C(lit.)
TSCANo
Melting Point131-134 °C

别名和识别编码

Chemical Name3-Bromocyclohexene
Synonym 3-Bromocyclohex-1-ene {LY} 3-Bromocyclohex-1-ene {} {LY} 3-Bromocyclohex-1-ene {} {} {LY} 3-Bromocyclohex-1-ene {} {} {} {LY} 3-Bromocyclohex-1-ene {} {} {} {} {LY} 3-Bromocyclohex-1-ene {} {} {} {} {} {LY} 3-Bromocyclohex-1-ene {} {} {} {} {} {} {LY} 3-Bromocyclohex-1-ene {} {} {} {} {} {} {} {LY} 3-Bromocyclohex-1-ene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromocyclohex-1-ene {} {} {} {} {} {} {} {} {} {LY} 3-Bromocyclohex-1-ene {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromocyclohex-1-ene {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromocyclohex-1-ene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromocyclohex-1-ene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromocyclohex-1-ene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromocyclohex-1-ene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromocyclohex-1-ene {} {} {}
MDL NumberMFCD00013775
CAS Number1521-51-3
EC Number250-023-7
Beilstein Registry Number635953
PubChem Substance ID137057
Chemical Name Translation3-溴环己烯
Reaxys-RN635953
InChIKeyAJKDUJRRWLQXHM-UHFFFAOYSA-N
LabNetwork Molecule IDLN00189579
InChIInChI=1S/C6H9Br/c7-6-4-2-1-3-5-6/h2,4,6H,1,3,5H2
Canonical SMILESBrC1C=CCCC1
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分类

  • {uni_hamburg} no charge; carbocycle; alicycle; 6RingOnly; 6ring; 1fragment
  • {SNA} Alkenyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

相关文献及参考

  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • In peptide synthesis, can be used to protect the hydroxyl group of serine and threonine as the cyclohexyl (Chx) ether, by reaction with the sodium alkoxide (generated with NaH), followed by hydrogenation. The group is stable to TFA and 20% piperidine in DMF, but can be cleaved with TfOH in TFA, in the presence of thioanisole as a cation scavenger: J. Chem. Soc., Perkin 1, 1949 (2000). See Appendix 6.

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R10 Flammable 易燃
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P305+P351+P338+P337+P313
  • P303+P361+P353
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupIII
UN Number
Hazard Codes
Hazard Class3
Storage condition -20°C {LY} -20°C 0-10 0-10°C 2-8°C Store at room temperature {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 3-溴环己烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0943 3-溴环己烯 3-Bromocyclohexene 25ML 2330元 2014/06/02 B0943 3-溴环己烯 3-Bromocyclohexene 5ML 662元 2010/06/21 335120100 3-溴环己烯 3-Bromocyclohexene 95% 10 ML 634元
  • MOL 文件:1521-51-3.mol
  • Alfa Aesar:3-溴环己烯,95% 3-Bromocyclohexene, 95%(1521-51-3)
  • TCI Shanghai:3-溴环己烯 3-Bromocyclohexene,>;95.0%(GC)(1521-51-3)
  • Acros Organics:3-溴环己烯 3-Bromocyclohexene, 95%(1521-51-3)
  • F:10
  • Sigma Aldrich:1521-51-3(sigmaaldrich)

系列性分类


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