2,6-Dibromo-N-chloro-p-benzoquinoneimine 2,6-二溴喹柄-4-氯亚胺

CAS 537-45-1 MFCD00013792

化学结构图

537-45-1
SMILES: O=C1C(Br)=CC(=NCl)C=C1Br

化学属性

Mol. FormulaC6H2Br2ClNO
Mol. Weight299.35
Melting Point76-84 °C
TSCAYes
Density2.18
Boiling Point295.9±50.0 °C at 760 mmHg
Flash Point132.8±30.1 °C

别名和识别编码

Chemical Name2,6-Dibromo-N-chloro-p-benzoquinoneimine
Synonym 2,6-Dibromo-4-(chloroimino)cyclohexa-2,5-dienone {LY} 2,6-Dibromo-4-(chloroimino)cyclohexa-2,5-dienone {} {LY} 2,6-Dibromo-4-(chloroimino)cyclohexa-2,5-dienone {} {} {LY} 2,6-Dibromo-4-(chloroimino)cyclohexa-2,5-dienone {} {} {} {LY} 2,6-Dibromo-4-(chloroimino)cyclohexa-2,5-dienone {} {} {} {} {LY} 2,6-Dibromo-4-(chloroimino)cyclohexa-2,5-dienone {} {} {} {} {} {LY} 2,6-Dibromo-4-(chloroimino)cyclohexa-2,5-dienone {} {} {} {} {} {} {LY} 2,6-Dibromo-4-(chloroimino)cyclohexa-2,5-dienone {} {} {} {} {} {} {} {LY} 2,6-Dibromo-4-(chloroimino)cyclohexa-2,5-dienone {} {} {} {} {} {} {} {} {LY} 2,6-Dibromo-4-(chloroimino)cyclohexa-2,5-dienone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dibromo-4-(chloroimino)cyclohexa-2,5-dienone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dibromo-4-(chloroimino)cyclohexa-2,5-dienone {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Dibromo-4-(chloroimino)cyclohexa-2,5-dienone
MDL NumberMFCD00013792
CAS Number537-45-1
EC Number208-667-1
Merck Number3026
Beilstein Registry Number7(2)584
PubChem Substance ID10835
Chemical Name Translation2,6-二溴喹柄-4-氯亚胺
Reaxys-RN2094249
Wiswesser Line NotationL6V DYJ BE DUNG FE
LabNetwork Molecule IDLN00198724
InChIInChI=1S/C6H2Br2ClNO/c7-4-1-3(10-9)2-5(8)6(4)11/h1-2H
Canonical SMILESCl/N=C(C=C1Br)/C=C(Br)C1=O
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; ketone; 1fragment

产品应用

  • 测定氰化物、酚（CN-, phenols），检测磷酸酶（phosphatase）。

相关文献及参考

  • Short: III/20a
  • Short: III/20b
  • Short: EINECS
  • Merck:14,3026 Beilstein:7(2)584
  • Merck:14,3026
  • Reagent for determination of phenols.

安全信息

RTECSGU5435000
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Risk Statements
Hazard Codes Xn
GHS Symbol
WGK Germany3
Hazard statements
  • H240 Heating may cause an explosion 加热可能会引起爆炸
  • H312 Harmful in contact with skin 皮肤接触有害
  • H312+H332
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P312+P362+P364
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P370+P380+P375
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P411 Store at temperatures not exceeding … oC/…oF. 储存在温度不超过…oC /…oF。
  • P420 Store away from other materials. 远离其他材料。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { 
TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,21,1953

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 63 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JMCMAR Journal of Medicinal Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC
   20037)  V.6-    1963-  Volume(issue)/page/year: 21,11,1978

其他信息

  • 类别:有毒物质
  • Alfa Aesar:2,6-二溴苯醌-4-氯酰亚胺,98% 2,6-Dibromoquinone-4-chloroimide, 98%(537-45-1)
  • 可燃性危险特性:可燃; 火场分解有毒氮氧化物, 溴化物和氯化物烟雾
  • Acros Organics:2,6-二溴-N-氯-对苯醌酰亚胺 2,6-Dibromo-N-chloro-p-benzoquinoneimine, 97%(537-45-1)
  • 毒性分级:中毒
  • MOL 文件:537-45-1.mol
  • TCI Shanghai:2,6-二溴苯醌-4-氯亚胺 2,6-Dibromoquinone-4-chloroimide,>;98.0%(T)(537-45-1)
  • 爆炸物危险特性:室温可能爆炸
  • 灭火剂:水, 二氧化碳, 干粉
  • F:4.4
  • 2，6-二溴喹柄-4-氯亚胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0209 2,6-二溴苯醌-4-氯亚胺 2,6-Dibromoquinone-4-chloroimide 5G 1220元 2010/06/21 406470050 2，6-二溴喹柄-4-氯亚胺 2,6-Dibromo-N-chloro-p-benzoquinoneimine 97% 5 GR 2083元 2010/05/25 A12207 2,6-二溴苯醌-4-氯酰亚胺, 98% 2,6-Dibromoquinone-4-chloroimide, 98% 50g 2324元
  • 储运特性:库房低温, 通风, 干燥
  • 图谱信息:2，6-二溴喹柄-4-氯亚胺(537-45-1)红外图谱(IR2) 2，6-二溴喹柄-4-氯亚胺(537-45-1)核磁图( 1 HNMR) 2，6-二溴喹柄-4-氯亚胺(537-45-1)红外图谱(IR3) 2，6-二溴喹柄-4-氯亚胺(537-45-1)质谱(MS) 2，6-二溴喹柄-4-氯亚胺(537-45-1)核磁图( 13 CNMR) 2，6-二溴喹柄-4-氯亚胺(537-45-1)红外图谱(IR1)
  • 急性毒性:口服-大鼠 LD: >; 500 毫克/公斤; 腹腔-小鼠 LD50: 63 毫克/公斤
  • 用途一:测定氰化物、酚（CN-, phenols），检测磷酸酶（phosphatase）。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Amides - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Lactones - Carbonyl Compounds
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Analytical Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (alphabetic sort)
  4. TLC Reagents, A-C
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (by application)
  4. Barbituates
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (by application)
  4. Peroxides
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (by application)
  4. Phenols
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (alphabetic sort)
  5. TLC Reagents, A-C
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (by application)
  5. Barbituates
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (by application)
  5. Peroxides
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (by application)
  5. Phenols
  1. Functional Group 官能团索引
  2. vinyl bromide 乙烯基溴

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