Tetrabromobisphenol A 四溴双酚A

CAS 79-94-7 MFCD00013962

化学结构图

79-94-7
SMILES: CC(C)(c1cc(Br)c(O)c(Br)c1)c1cc(Br)c(O)c(Br)c1

化学属性

Mol. FormulaC15H12Br4O2
Mol. Weight543.88
Melting Point178-181°C
Density1.76
TSCAYes
Boiling Point417.9 °C at 760 mmHg
Solubility不溶
Appearance 白色粉末

别名和识别编码

Chemical NameTetrabromobisphenol A
CAS Number79-94-7
Alfabeta NamePROPANEDIYLBISDIBROMOPHENOL 442226(())---,,,'
MDL NumberMFCD00013962
Synonym 4,4'-(Propane-2,2-diyl)bis(2,6-dibromophenol) {LY} 4,4'-(Propane-2,2-diyl)bis(2,6-dibromophenol) {} {LY} 4,4'-(Propane-2,2-diyl)bis(2,6-dibromophenol) {} {} {LY} 4,4'-(Propane-2,2-diyl)bis(2,6-dibromophenol) {} {} {} {LY} 4,4'-(Propane-2,2-diyl)bis(2,6-dibromophenol) {} {} {} {} {LY} 4,4'-(Propane-2,2-diyl)bis(2,6-dibromophenol) {} {} {} {} {} {LY} 4,4'-(Propane-2,2-diyl)bis(2,6-dibromophenol) {} {} {} {} {} {} {LY} 4,4'-(Propane-2,2-diyl)bis(2,6-dibromophenol) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-(Propane-2,2-diyl)bis(2,6-dibromophenol) {} {} {} {} {} {} {} {} {LY} 4,4'-(Propane-2,2-diyl)bis(2,6-dibromophenol) {} {} {} {} {} {} {} {} {} {LY} 4,4'-(Propane-2,2-diyl)bis(2,6-dibromophenol) {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-(Propane-2,2-diyl)bis(2,6-dibromophenol) {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-(Propane-2,2-diyl)bis(2,6-dibromophenol) {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-(Propane-2,2-diyl)bis(2,6-dibromophenol) {} {} {} {} {}
PubChem Substance ID6618
EC Number201-236-9
Beilstein Registry Number1889048
Reaxys-RN1889048
Chemical Name Translation四溴双酚A
LabNetwork Molecule IDLN00158738
InChIInChI=1S/C15H12Br4O2/c1-15(2,7-3-9(16)13(20)10(17)4-7)8-5-11(18)14(21)12(19)6-8/h3-6,20-21H,1-2H3
Canonical SMILESCC(C1=CC(Br)=C(O)C(Br)=C1)(C2=CC(Br)=C(O)C(Br)=C2)C
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信息真实价格透明    资金保障    专业采购外包团队在线服务   
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分类

  • {SNA} Bioactive Small Molecules, Bisphenol and Sulfonyldiphenol Monomers, Cell Biology, Materials Science, Monomers, Polymer Science, T
  • {SNA} Bioactive Small Molecules, Bisphenol and Sulfonyldiphenol Monomers, Materials Science, Monomers, Polymer Science, T,
  • {SNA} Bisphenol and Sulfonyldiphenol Monomers, Monomers, Polymer Science, 材料科学
  • {SNA} Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Flame Retardants
  • {SNA} Analytical Standards, Analytical/Chromatography, Chromatography, Flame retardants
  • {SNA} Analytical Standards, Organic Pollutant Standards,

产品应用

  • 用于塑料、橡胶、纺织、纤维和造纸等工业作阻燃剂，如用于环氧、聚碳酸酯、聚酯、酚醛及ABS等树脂中，使制品具有良好的阻燃性和自熄性。目前正式用于电视高压包灌注环氧树脂中。

相关文献及参考

  • Merck: 14,10400 Beilstein: 6,III,5462
  • Merck: 14,10400

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany2
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes 9
RTECSSM0894500
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P203
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P263 Avoid contact during pregnancy/while nursing. 怀孕/哺乳期间避免接触。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P302+P350
  • P302+P352
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P318
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
UN Number 3077 UN 3077 9/PG 3 UN3077
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R50/53
Packing GroupIII
Hazard Class9 
TYPE OF TEST            : LC - Lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >500 mg/m3/8H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0525426

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : >500 mg/m3/8H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0525426

TYPE OF TEST            : LC - Lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >10920 mg/m3/4H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - effect, not otherwise specified
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0525426

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >3160 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • 上游原料:乙醇 --> 溴 --> 氯 --> 双酚 A
  • 用途一:作为反应型阻燃剂，可用于环氧树脂、聚氨酯树脂等；作为添加型阻燃剂可用于聚苯乙烯、SAN树脂及ABS树脂等
  • Acros Organics:四溴双酚A Tetrabromobisphenol A, 97%(79-94-7)
  • Sigma Aldrich:79-94-7(sigmaaldrich)
  • Alfa Aesar:四溴双酚A,97% 3,3',5,5'-Tetrabromobisphenol A, 97%(79-94-7)
  • 方法一:双酚在室温下加溴，通氯，经溴化反应、过滤、水洗、干燥，得成品。原料消耗定额：双酚 A　840kg/t、溴素350kg/t、液氯（98%）800kg/t。
  • MOL 文件:79-94-7.mol
  • 用途二:用于塑料、橡胶、纺织、纤维和造纸等工业作阻燃剂，如用于环氧、聚碳酸酯、聚酯、酚醛及ABS等树脂中，使制品具有良好的阻燃性和自熄性。目前正式用于电视高压包灌注环氧树脂中。
  • TCI Shanghai:四溴双酚A Tetrabromobisphenol A,>;98.0%(T)(79-94-7)
  • MSDS 信息:Tetrabromobisphenol A(79-94-7).msds
  • 下游产品:6-巯基嘌呤 --> 四溴双酚 A 双(二溴丙基)醚 --> 四溴双酚 A 双烯丙基醚
  • 四溴双酚 A价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0032 四溴双酚A Tetrabromobisphenol A 500G 818元 2014/06/02 T0032 四溴双酚A Tetrabromobisphenol A 25G 239元 2010/06/21 352651000 四溴双酚 A Tetrabromobisphenol A 97% 100 GR 402元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Flame retardants - Chemical Class
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Polyols - Oxygen Compounds
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Bisphenol and Sulfonyldiphenol Monomers - Monomers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Aromatic alcohols 芳香醇
  1. Materials Science 材料科学
  2. Pressure & Heat Sensitive Recording Materials

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