Diphenylzinc 二苯锌

CAS 1078-58-6 MFCD00014071

化学结构图

1078-58-6
SMILES: c1ccc([Zn]c2ccccc2)cc1

化学属性

Mol. FormulaC12H10Zn
Mol. Weight219.59
Boiling Point280-285 °C at 760 mmHg
Melting Point102-106 °C
TSCANo
Flash Point280-285°C

别名和识别编码

Chemical NameDiphenylzinc
Synonym Diphenylzinc {LY} Diphenylzinc {} {LY} Diphenylzinc {} {} {LY} Diphenylzinc {} {} {} {LY} Diphenylzinc {} {} {} {} {LY} Diphenylzinc {} {} {} {} {} {LY} Diphenylzinc {} {} {} {} {} {} {LY} Diphenylzinc {} {} {} {} {} {} {} {LY} Diphenylzinc {} {} {} {} {} {} {} {} {LY} Diphenylzinc {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylzinc {} {} {} {} {} {} {} {} {} {} {LY} Diphenylzinc {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylzinc {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylzinc {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylzinc {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylzinc {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylzinc {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylzinc {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00014071
PubChem Substance ID517896
CAS Number1078-58-6
EC Number214-082-2
Chemical Name Translation二苯锌
InChIKeyBUNROVZNGITPIX-UHFFFAOYSA-N
InChIInChI=1S/2C6H5.Zn/c2*1-2-4-6-5-3-1;/h2*1-5H;/q2*-1;+2
LabNetwork Molecule IDLN01815711
Canonical SMILESC1([Zn]C2=CC=CC=C2)=CC=CC=C1
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分类

  • {uni_hamburg} no charge; metal-organic; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} CVD and ALD Precursors by Metal, Chemical Synthesis, Dialkylzincs, Materials Science, Micro/NanoElectronics, Organometallic Reagents, Rieke and Organozinc Reagents, Vapor Deposition Precursors, Zinc
  • {SNA} CVD and ALD Precursors by Metal, Chemical Synthesis, Dialkylzincs, Micro/NanoElectronics, Organometallic Reagents, Rieke and Organozinc Reagents, Vapor Deposition Precursors, Zinc, 材料科学

相关文献及参考

  • Short: IV/1a Title: Densities of Liquid Systems: Nonaqueous Systems and Ternary Aqueous Systems Author: Lacmann, R.; Synowietz, C. Editor: Schäfer, Kl. Source: Landolt-Börnstein, New Series Volume: IV/1a Year: 1974 ISBN: 3-540-06269-6 ISBN: 978-3-540-06269-1 Internet Resource: DOI:10.1007/b20003 RefComment: X, 716 pages. Hardcover Abstract: Volume IV/1 contains information on the densities of liquid systems. It may be considered as a supplement to volume II/1 of the 6th Edition, which contains only a few data on nonaqueous systems. Data are not listed for all systems but primarily for those of greater interest where data for a larger range of concentrations were available.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Beil. 16 ,I,557

安全信息

WGK Germany3
Hazard Codes T F,T
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S1 Keep locked up 上锁；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
UN Number UN 3077 9/PG 3 UN3181
Risk Statements
  • R45 May cause cancer 可能致癌
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R46 May cause inheritable genetic damage 可能引起遗传基因损害
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R48/20/21/22
  • R17 Spontaneously flammable in air 在空气中能够自燃
  • R11 Highly flammable 非常易燃
  • R1 Explosive when dry 干燥时易爆
Storage condition Air & Moisture Sensitive Flammables area
Packing GroupIII
Hazard Class4.1
GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P222 Do not allow contact with air. 不要与空气接触。
  • P231 Handle under inert gas. 在惰性气体中操作。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P334
  • P308+P313
  • P370+P378
  • P422 Store contents under… 存储目录在…之下。
Signal word Danger
Hazard statements
  • H228 Flammable solid 易燃固体
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H340 May cause genetic defects 可能导致遗传性缺陷
  • H350 May cause cancer 可能致癌
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官

其他信息

  • Sigma Aldrich:1078-58-6(sigmaaldrich)
  • MOL 文件:1078-58-6.mol
  • Acros Organics:二苯基锌 Diphenylzinc, 95%(1078-58-6)
  • 二苯基锌价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 353500010 二苯基锌 Diphenylzinc 95% 1 GR 1064元 2010/05/25 87908 Diphenylzinc, 98+% 5g 5208元 2010/05/25 87908 Diphenylzinc, 98+% 1g 1141元
  • Alfa Aesar:Diphenylzinc, 98+%(1078-58-6)
  • 敏感性:Air & Moisture Sensitive

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organozinc Reagents 有机锌试剂
  4. Dialkylzincs - Rieke® and Organozinc Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organozinc Reagents 有机锌试剂
  4. Dialkylzincs - Rieke® and Organozinc Reagents
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors by Metal - Vapor Deposition Precursors
  5. Vapor Deposition Precursors for Zinc Thin Films
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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