Arsenic triiodide 碘化亚砷(III)

CAS 7784-45-4 MFCD00014170

化学结构图

7784-45-4
SMILES: I[As](I)I

化学属性

Mol. FormulaAsI3
Mol. Weight455.62
Density4.39
Melting Point140°
SolubilitySoluble in carbon disulfide, chloroform, benzene, toluene, and xylene
TSCAYes
Boiling Point424°
Flash Point424°C

别名和识别编码

Chemical NameArsenic(Iii) Iodide
Synonym ARSENIC (OUS) IODIDE ARSENIC COMPOUNDS ARSENIC IODIDE ARSENIC IODIDE, 99.999% ARSENIC TRIIODIDE ARSENIC(III) IODIDE Arsen(III)-iodid Arsen(III)-jodid Arsenic iodide (AsI3) Arsenic triiodide Arsenic(III) iodide Arsenic(III) iodide, 99.999% (metals basis) Arsenic(III)iodide,98% Arsenic(III)iodide,99%(metalsbasis) Arsenous iodide Arsenous triiodide Arsenous-triiodide- Arsenousiodide Arsenoustriiodide Arsentriiodid Arsentrijodid AsI3 NA 1557 Triiodoarsine arsenic (III) iodide arsenic iodide arsenic iodide,solid arsenic triiodide arseniciodide(asi3) {} {
MDL NumberMFCD00014170
CAS Number7784-45-4
EC Number232-068-4
Merck Number14,803
PubChem Substance ID24575
Chemical Name Translation碘化亚砷(III)
Wiswesser Line Notation.AS..I3
LabNetwork Molecule IDLN01251807
InChIInChI=1S/AsI3/c2-1(3)4
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Arsenic, Arsenic Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Crystal Grade Inorganics, Materials Science, Metal and Ceramic Science, Salts

相关文献及参考

  • Short: II/25A Title: Structure Data Of Free Polyatomic Molecules: Inorganic Molecules Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25A Year: 1998 Keyword: Free Polyatomic Molecules; Inorganic Molecules; Molecules ISBN: 3-540-61713-2 ISBN: 978-3-540-61713-6 Internet Resource: DOI:10.1007/b59072 RefComment: VII, 359 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/20c Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Zr ... Bi. Diagrams

安全信息

Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S20/21 When using do not eat, drink or smoke 使用时，不得进食，饮水或吸烟；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Packing GroupII
UN Number UN 1557 6.1/PG 1 UN1557
Risk Statements
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
  • R50/53
Storage condition Moisture Sensitive
RTECSCG1950000
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P301+P316
  • P304+P340
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H331 Toxic if inhaled 吸入中毒
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
GHS Symbol
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes T,N
Hazard Class6.1
Warnings 危化品目录(2015) 危险化学品

其他信息

  • 上游原料:砷
  • 可燃性危险特性:不可燃物质; 遇热放出有毒砷化物和碘化物蒸气
  • MSDS 信息:三碘化砷(7784-45-4).msds
  • Sigma Aldrich:7784-45-4(sigmaaldrich)
  • 用途一:用于电子、试剂
  • 毒性分级:高毒
  • 职业标准:TWA 0.01 毫克 (砷)/ 立方米
  • 外观性质:橙红色鳞状或粉状结晶。
  • Alfa Aesar:三碘化砷,99.999%(metalsbasis) Arsenic(III) iodide, 99.999% (metals basis)(7784-45-4)
  • 爆炸物危险特性:遇金属钠、钾可爆
  • 储运特性:库房通风低温干燥; 与碱、酸类、食品添加剂分开存放
  • MOL 文件:7784-45-4.mol
  • 敏感性:Moisture Sensitive
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Arsenic - Catalysis and Inorganic Chemistry

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