2-Chloro-132-Dioxaphospholane 2-氯-1,3,2-二氧磷杂环戊烷
CAS 822-39-9 MFCD00014511
化学结构图
SMILES: ClP1OCCO1
化学属性
| Mol. Formula | C2H4ClO2P |
|---|---|
| Mol. Weight | 126 |
| Density | 1.422 g/mL at 25 °C(lit.) |
| Refractive index | n20/D 1.489(lit.) |
| Flash Point | 70°C(lit.) |
| TSCA | Yes |
| Boiling Point | 47°C/5mmHg(lit.) |
别名和识别编码
| Chemical Name | 2-Chloro-132-Dioxaphospholane |
|---|---|
| CAS Number | 822-39-9 |
| Synonym | Ethylene glycol, cyclic phosphorochloridite Ethylene phosphorochloridite 2-氯-1,3,2-二氧磷杂环戊 Cyclic ethylene chlorophosphite Cyclic O,O-Ethylene Phosphorochloridite 2-Chlor-1,3,2-dioxaphospholan 1,3,2-Dioxaphospholane, 2-chloro- ethylenephosphorous acid chloride Cyclic ethylene chlorophosphite Cyclic ethylene phosphorochloridite Ethylene phosphorochloridite（2-chloro-1,3,2-dioxaphospholane) 1,3,2-Dioxaphospholanyl chloride ETHYLENE CHLOROPHOSPHITE 1,3,2-Dioxaphosphorane.2-chloro- 2-氯-1,3,2-二氧磷杂环戊烷 2-dioxaphospholane,2-chloro-3 氯亚磷酸乙烯酯 Cyclic O,O-ethylene phosphorochloridite 2-Chloro-1,3-dioxaphospholane 环氯亚磷酸乙烯酯 2-氯-1，3，2-三乙酸乙酯 {uni_hambur |
| MDL Number | MFCD00014511 |
| EC Number | 212-499-4 |
| Beilstein Registry Number | 1(4)2417 |
| PubChem Substance ID | 87566237 |
| Chemical Name Translation | 2-氯-1,3,2-二氧磷杂环戊烷 |
| Reaxys-RN | 506179 |
| InChIKey | OLSFRDLMFAOSIA-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN01266495 |
| InChI | InChI=1S/C2H4ClO2P/c3-6-4-1-2-5-6/h1-2H2 |
信息真实价格透明
资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
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分类
- {uni_hamburg} no charge; oxygen heterocycle; other heterocycle; alicycle; 5ring; 1fragment
- Phosphorylating and Phosphitylating Agents
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors
产品应用
- Highly reactive cyclic phosphitylating reagent which provides fast coupling rates, and hydrolytic cleavage occurs more readily than with acyclic analogs.
相关文献及参考
- Bannwarth,W. & Kung, E.: Tetrahedron Lett., 30, 4219 (1989)
- Short: II/25B Title: Structure Data Of Free Polyatomic Molecules: Molecules containing One or Two Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25B Year: 1999 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-63645-5 ISBN: 978-3-540-63645-8 Internet Resource: DOI:10.1007/b68834 RefComment: IX, 512 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
- Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
- Short: EINECS
安全信息
- R34 Causes burns 会导致灼伤
- R14 Reacts violently with water 遇水会猛烈反应
- R37 Irritating to respiratory system 刺激呼吸道
- S8 Keep container dry 保持容器干燥；
- S25 Avoid contact with eyes 避免眼睛接触；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
GHS Symbol
- H227 Combustible liquid 可燃液体
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331+P310
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+P340
- P304+P340+P310
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P370+P378
- P403+P235
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
其他信息
- TCI Shanghai:2-氯-1,3,2-二氧磷杂环戊烷 2-Chloro-1,3,2-dioxaphospholane,>;97.0%(GC)(822-39-9)
- MSDS 信息:Ethylene glycol chlorophosphite(822-39-9).msds
- Hazard Note:Highly reactive cyclic phosphitylating reagent which
- MOL 文件:822-39-9.mol
- 图谱信息:2-氯-1,3,2-二氧磷杂环戊烷(822-39-9)核磁图( 1 HNMR) 2-氯-1,3,2-二氧磷杂环戊烷(822-39-9)质谱(MS) 2-氯-1,3,2-二氧磷杂环戊烷(822-39-9)核磁图( 13 CNMR)
- 2-氯-1,3,2-二氧磷杂环戊烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1215 2-氯-1,3,2-二氧磷杂环戊烷 2-Chloro-1,3,2-dioxaphospholane 25G 682元 2010/05/25 A12724 2-氯-1,3,2-二氧磷杂环戊烷, 97% Ethylene chlorophosphite, 97% 500g 11942元 2010/05/25 A12724 2-氯-1,3,2-二氧磷杂环戊烷, 97% Ethylene chlorophosphite, 97% 25g 1046元
- F:1-10
- Sigma Aldrich:822-39-9(sigmaaldrich)
- Alfa Aesar:2-氯-1,3,2-二氧磷杂环戊烷,97% Ethylene chlorophosphite, 97%(822-39-9)
- 敏感性:Moisture Sensitive
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