4-Nitrophenyl formate 4-硝基苯基甲酸酯
CAS 1865-01-6 MFCD00014713
化学结构图
SMILES: O=COc1ccc([N+](=O)[O-])cc1
化学属性
| Mol. Formula | C7H5NO4 |
|---|---|
| Mol. Weight | 167.12 |
| Melting Point | 71-74 °C |
| TSCA | Yes |
| Boiling Point | 279.0±32.0 °C at 760 mmHg |
别名和识别编码
| Chemical Name | p-Nitrophenyl Formate |
|---|---|
| CAS Number | 1865-01-6 |
| Synonym | 4-Nitrophenyl formate {LY} 4-Nitrophenyl formate {} {LY} 4-Nitrophenyl formate {} {} {LY} 4-Nitrophenyl formate {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitrophenyl formate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitrophenyl formate |
| MDL Number | MFCD00014713 |
| PubChem Substance ID | 74628 |
| Beilstein Registry Number | 1950897 |
| EC Number | 217-473-6 |
| Chemical Name Translation | 4-硝基苯基甲酸酯 |
| InChIKey | IEXRKQFZXJSHOB-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN01303809 |
| Canonical SMILES | O=COC1=CC=C([N+]([O-])=O)C=C1 |
| InChI | InChI=1S/C7H5NO4/c9-5-12-7-3-1-6(2-4-7)8(10)11/h1-5H |
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分类
- {SNA} Amine Protection, Chemical Biology, Chemical Synthesis, Others, Peptide Chemistry, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
- Aromatics
- Miscellaneous Reagents
产品应用
- A selective formylating agent for one of two amino groups in such basic amino acids as ornithine or lysine.
相关文献及参考
- Schiller, P., et al.: J. Med. Chem., 43, 551 (2000),
- Schreiner, E., et al.: Bioorg. Med. Chem. Lett., 14, 4999 (2004),
- Convenient and selective reagent for the formylation of amino groups: Bull. Chem. Soc. Jpn., 36, 754 (1963); Synthesis, 979 (1982); Synth. Commun., 29, 1819 (1999).
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352
- P304+P340
- P305+P351+P338
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P319
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P332+P313
- P332+P317
- P337+P313
- P337+P317
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P362+P364
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
其他信息
- 甲酸对硝基苯酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 L00316 4-硝基苯酚甲酯, 98% 4-Nitrophenyl formate, 98% 5g 451元 2010/05/25 L00316 4-硝基苯酚甲酯, 98% 4-Nitrophenyl formate, 98% 25g 1806元
- F:8-9-21
- Sigma Aldrich:1865-01-6(sigmaaldrich)
- 敏感性:Moisture & Light Sensitive
- MOL 文件:1865-01-6.mol
- Alfa Aesar:4-硝基苯酚甲酯,98% 4-Nitrophenyl formate, 98%(1865-01-6)
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