(Allylsulfonyl)Benzene (烯丙基磺酰基)苯

CAS 16212-05-8 MFCD00014739

化学结构图

16212-05-8
SMILES: C=CCS(=O)(=O)C1C=CC=CC=1

化学属性

Mol. FormulaC9H10O2S
Mol. Weight182
Refractive index1.5460 to 1.5500
Boiling Point128°C/0.9mmHg(lit.)
Density1.189 g/mL at 25 °C(lit.)
Flash Point>110°(230°F)
TSCAYes

别名和识别编码

Chemical Name(Allylsulfonyl)Benzene
PubChem Substance ID87562897
EC Number240-338-8
Beilstein Registry Number6(4)1480
MDL NumberMFCD00014739
CAS Number16212-05-8
Synonym sulfone, allyl phenyl ALLYL PHENYL SULFONE Prop-2-enylsulfonylbenzene (Allylsulphonyl)benzene (2-propenylsulfonyl)-benzen Allyl Phenyl sulone Phenyl (2-propenyl) sulfone 烯丙基苯基砜 烯丙基苯砜 3-(Phenylsulfonyl)-1-propene (allylsulphonyl)benzene Phenyl allyl sulfone. 烯丙基苯磺酸 Benzene, (2-propenylsulfonyl)- Phenyl 2-propenyl sulfone ALLYL PHENYL SULPHONE Allyl phenyl sulfone ALLYLSULFONYLBENZENE
Alfabeta NameALLYLSULFONYLBENZENE ()
Chemical Name Translation(烯丙基磺酰基)苯
Reaxys-RN1863561
Wiswesser Line NotationWSR&2U1
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfones, Sulfur Compounds

相关文献及参考

  • Alkylation of the lithio-derivative and rearrangement to the (E)-ɑß-unsaturated sulfone, followed by cleavage with alkali metal, provides a route to alkenes: J. Chem. Soc., Perkin 1, 123 (1977):
  • For review of allylic and benzylic carbanions substituted by heteroatoms, see: Org. React., 27, 1 (1982).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSWR2400000
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
Signal word Warning
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Storage condition Light Sensitive 2-8°C
Hazard Codes Xi
Warnings IRRITANT
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 320 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02689

其他信息

  • Alfa Aesar:烯丙基苯砜,98% Allyl phenyl sulfone, 98%(16212-05-8)
  • 图谱信息:烯丙基苯砜(16212-05-8)核磁图( 1 HNMR) 烯丙基苯砜(16212-05-8)核磁图( 13 CNMR) 烯丙基苯砜(16212-05-8)质谱(MS) 烯丙基苯砜(16212-05-8)红外图谱(IR1)
  • MOL 文件:16212-05-8.mol
  • MSDS 信息:Allyl phenyl sulfone(16212-05-8).msds
  • TCI Shanghai:烯丙基苯砜 Allyl Phenyl Sulfone,>;95.0%(GC)(16212-05-8)
  • TSCA:T
  • 烯丙基苯砜价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 A1444 烯丙基苯砜 Allyl Phenyl Sulfone 5G 676元 2011/04/16 A1444 烯丙基苯砜 Allyl Phenyl Sulfone 25G 2360元 2010/06/21 308220050 烯丙基苯砜 Allyl phenyl sulfone 98% 5 GR 464元
  • Acros Organics:烯丙基苯基砜 Allyl phenyl sulfone, 98%(16212-05-8)
  • Sigma Aldrich:16212-05-8(sigmaaldrich)
  • F:8-10
  • 敏感性:Light Sensitive

系列性分类


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