Disilathiane, hexamethyl- 双(三甲基硅基)硫醚

CAS 3385-94-2 MFCD00014851

化学结构图

3385-94-2
SMILES: C[Si](C)(C)S[Si](C)(C)C

化学属性

Mol. FormulaC6H18SSi2
Mol. Weight178.44
Density0.846
Refractive index1.4590 to 1.4620
Flash Point23°C(lit.)
TSCAYes
Boiling Point163°C(lit.)
Appearance colorless liq.
Stabilitystore cold

别名和识别编码

Chemical NameBis(Trimethylsilyl) Sulfide
Synonym Bis(trimethylsilyl)sulfur {LY} Bis(trimethylsilyl)sulfur {} {LY} Bis(trimethylsilyl)sulfur {} {} {LY} Bis(trimethylsilyl)sulfur {} {} {} {LY} Bis(trimethylsilyl)sulfur {} {} {} {} {LY} Bis(trimethylsilyl)sulfur {} {} {} {} {} {} {} {} {} {} {LY} Bis(trimethylsilyl)sulfur {} {} {} {} {} {} {LY} Bis(trimethylsilyl)sulfur {} {} {} {} {} {} {} {LY} Bis(trimethylsilyl)sulfur {} {} {} {} {} {} {} {} {LY} Bis(trimethylsilyl)sulfur {} {} {} {} {} {} {} {} {} {LY} Bis(trimethylsilyl)sulfur {} {} {} {} {} {} {} {} {} {} {LY} Bis(trimethylsilyl)sulfur {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(trimethylsilyl)sulfur {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(trimethylsilyl)sulfur {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(trimethylsilyl)sulfur {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(trimethylsilyl)sulfur {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(trimethylsil
MDL NumberMFCD00014851
CAS Number3385-94-2
EC Number222-201-4
Beilstein Registry Number1698358
PubChem Substance ID76920
Reaxys-RN1698358
Chemical Name Translation双(三甲基硅基)硫醚
InChIKeyRLECCBFNWDXKPK-UHFFFAOYSA-N
LabNetwork Molecule IDLN01742638
InChIInChI=1S/C6H18SSi2/c1-8(2,3)7-9(4,5)6/h1-6H3
Canonical SMILESC[Si](S[Si](C)(C)C)(C)C
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分类

  • {SNA} Chemical Synthesis, Organometallic Reagents, Organosilicon, Others
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Chemical Synthesis, Organometallic Reagents, Organosilicon, Other Organosilicon

相关文献及参考

  • Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
  • Short: III/35C4 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds Author: Gupta, R.R.; Platzer, N. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35C4 Year: 2001 Keyword: Hydrogen 1; Nuclear Magnetic Resonance ISBN: 3-540-41059-7 ISBN: 978-3-540-41059-1 Internet Resource: DOI:10.1007/b76570 RefComment: VII, 299 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive

安全信息

Packing GroupIII
UN Number 1993
Risk Statements
  • R10 Flammable 易燃
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H301 Toxic if swallowed 吞食有毒
  • H301+H311+H331
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H331 Toxic if inhaled 吸入中毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P312+P330
  • P301+P316
  • P302+P352
  • P302+P352+P312+P362+P364
  • P303+P361+P353
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P316
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Storage condition -20°C, stored under nitrogen {LY} -20°C, stored under nitrogen Air Sensitive Flammables area {} {LY} -20°C, stored under nitrogen {} {} {LY} -20°C, stored under nitrogen {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under
Hazard Codes 3 T
Hazard Class3

其他信息

  • Acros Organics:双(三甲基硫化硅) Bis(trimethylsilyl)sulfide, 95%(3385-94-2)
  • Alfa Aesar:六甲基二硅硫烷,98% Bis(trimethylsilyl)sulfide, 98%(3385-94-2)
  • F:10-13-21
  • MOL 文件:3385-94-2.mol
  • 双(三甲基硫化硅)价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0871 双(三甲基硅基)硫醚 Bis(trimethylsilyl) Sulfide 5G 1310元 2014/06/02 H0871 双(三甲基硅基)硫醚 Bis(trimethylsilyl) Sulfide 25G 4640元 2010/06/21 367370050 双(三甲基硫化硅) Bis(trimethylsilyl)sulfide 95% 5 GR 1451元
  • Sigma Aldrich:3385-94-2(sigmaaldrich)
  • TCI Shanghai:双(三甲基硅基)硫醚 Bis(trimethylsilyl) Sulfide,>;95.0%(GC)(3385-94-2)
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Others - Organosilicon
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Silanes 硅烷
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfur Compounds for Organic Synthesis 有机合成硫化物
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organolithium 有机锂
  4. Others Organosilicon 其他有机硅
  1. Silanes
  2. Silicon

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