Bis(Dimethylthiocarbamoyl) Sulfide 四甲基一硫化秋兰姆

CAS 97-74-5 MFCD00014870

化学结构图

97-74-5
SMILES: CN(C)C(=S)SC(=S)N(C)C

化学属性

Mol. FormulaC6H12N2S3
Mol. Weight208.37
Melting Point107-111 °C
Density1.37
TSCAYes
Solubility不溶
Flash Point156 °C
Boiling Point260.9±23.0 °C at 760 mmHg

别名和识别编码

Chemical NameBis(Dimethylthiocarbamoyl) Sulfide
MDL NumberMFCD00014870
CAS Number97-74-5
Synonym Tetramethylthiuram monosulfide {LY} Tetramethylthiuram monosulfide {} {LY} Tetramethylthiuram monosulfide {} {} {LY} Tetramethylthiuram monosulfide {} {} {} {LY} Tetramethylthiuram monosulfide {} {} {} {} {LY} Tetramethylthiuram monosulfide {} {} {} {} {} {LY} Tetramethylthiuram monosulfide {} {} {} {} {} {} {LY} Tetramethylthiuram monosulfide {} {} {} {} {} {} {} {LY} Tetramethylthiuram monosulfide {} {} {} {} {} {} {} {} {LY} Tetramethylthiuram monosulfide {} {} {} {} {} {} {} {} {} {LY} Tetramethylthiuram monosulfide {} {} {} {} {} {} {} {} {} {} {LY} Tetramethylthiuram monosulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetramethylthiuram monosulfide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetramethylthiuram monosulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetramethylthiuram monosulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetramethylthiuram monosulfide {} {} {} {} {} {}
PubChem Substance ID7347
EC Number202-605-7
Beilstein Registry Number1775650
Reaxys-RN1775650
Chemical Name Translation四甲基一硫化秋兰姆
Wiswesser Line Notation1N1&YUS&SYUS&N1&1
LabNetwork Molecule IDLN00221644
InChIInChI=1S/C6H12N2S3/c1-7(2)5(9)11-6(10)8(3)4/h1-4H3
Canonical SMILESS=C(SC(N(C)C)=S)N(C)C
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfur Compounds, Thiocarbonyl Compounds
  • {uni_hamburg} no charge; chiral; 1fragment

相关文献及参考

  • Short: II/27B Title: Diamagnetic Susceptibility of Organic Compounds, Oils, Paraffins and Polyethylenes Author: Kumar, M.; Gupta, R. Editor: Gupta, Radha Raman Source: Landolt-Börnstein, New Series Volume: II/27B Year: 2008 Keyword: diamagnetic susceptibility; organic compounds ISBN: 978-3-540-44359-9 (print) ISBN: 978-3-540-45860-9 (online) Internet Resource: doi:10.1007/978-3-540-45860-9 RefComment: VIII, 503 p. With CD-ROM., Hardcover RefComment: Written for: Scientists and researchers in the fields of physics, chemistry, materials science RefComment: Supplement and Revised Editon to II/16 Abstract: The volume II/27 has been divided into three subvolumes according to the classes of compounds: Subvolume A: Diamagnetic susceptibility and magnetic anisotropy of inorganic and organometallic compounds; Subvolume B: Diamagnetic susceptibility of organic compounds, oils, paraffins and polyethylenes; Subvolume C: Diamagnetic susceptibility and magnetic anisotropy of organic compounds. The data presented in this volume are based on the literature survey of the chemical abstracts up to 2005. The calculated values of diamagnetic susceptibility of organic compounds in the present subvolume II/27B are presented along with their experimental values. They have been calculated with the use of structural parameters in structural formula by using different theoretical methods available in the literature.
  • Short: III/5a Title: Structure Data of Organic Crystals: C ... C 13 Author: Schudt, E.; Weitz, G. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/5a Year: 1971 ISBN: 3-540-05177-5 ISBN: 978-3-540-05177-0 Internet Resource: DOI:10.1007/b19970 RefComment: XXI, 736 pages, and VII, 890 pages. Hardcover Abstract: Volume III/5 offers a compitation as complete as possible of the space groups and lattice con-stants of all crystals which have been studied by means of X-rays, neutron and electron diffraction.
  • {uni_ham

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RTECSWQ1750000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P302+P352+P333+P313+P362+P364
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P333+P313
  • P301+P312+P330
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P302+P350
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
Signal word Warning
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R51/53
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R22 Harmful if swallowed 吞咽有害
Hazard Codes Xn;N Xn,N
Packing GroupIII
UN Number UN 3077 9/PG 3 3077
Hazard Class9
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Blood - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-159

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - cat
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   RCTEA4 Rubber Chemistry and Technology.  (American Chemical Soc., Rubber
   Division, c/o Mrs. M.E. Bauer, Univ. of Akron, Akron, OH 44325)  V.1- 1928- 
   Volume(issue)/page/year: 44,512,1971

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   RCTEA4 Rubber Chemistry and Technology.  (American Chemical Soc., Rubber
   Division, c/o Mrs. M.E. Bauer, Univ. of Akron, Akron, OH 44325)  V.1- 1928- 
   Volume(issue)/page/year: 44,512,1971

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 10 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   IPSTB3 International Polymer Science and Technology.  (Rapra Technology
   Ltd., Shawbury, Shrewsbury, Shropshire SY4 4NR, UK) Volume(issue)/page/year:
   3,93,1976

TYPE OF TEST

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 850 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FATOAO Farmakologiya i Toksikologiya (Moscow).  For English translation, see
   PHTXA6 and RPTOAN. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.2-   
   1939-  Volume(issue)/page/year: 32,356,1969

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 100 nmol/L
REFERENCE :
   SWEHDO Scandinavian Journal of Work, Environment and Health. (Haartmaninkatu
   1, SF-00290 Helsinki, 29, Finland)  V.1-    1975- Volume(issue)/page/year:
   9(Suppl 2),27,1983

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - hamster
DOSE/DURATION           : 250 mg/kg
REFERENCE :
   SWEHDO Scandinavian Journal of Work, Environment and Health. (Haartmaninkatu
   1, SF-00290 Helsinki, 29, Finland)  V.1-    1975- Volume(issue)/page/year:
   9(Suppl 2),27,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 68,313,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 900 mg/kg
SEX/DURATION            : female 6-14 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-160

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • 一硫化四甲基秋兰姆价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0157 一硫化四甲基秋兰姆 Tetramethylthiuram Monosulfide 500G 502元 2014/06/02 T0157 一硫化四甲基秋兰姆 Tetramethylthiuram Monosulfide 25G 132元 2010/06/21 402432500 一硫化四甲基秋兰姆 Bis(dimethylthiocarbamyl) sulfide 97% 250 GR 956元
  • 用途一:用于制造电缆、轮胎、胶管、胶带等艳色和透明制品
  • 外观性质:黄色粉末或颗粒。
  • Acros Organics:双二甲基硫 Bis(dimethylthiocarbamyl) sulfide, 97%(97-74-5)
  • 类别:农药
  • 毒性分级:高毒
  • 方法一:将二硫化四甲基秋兰姆用氰化钠脱硫即得该品。
  • 可燃性危险特性:可燃; 受热分解有毒氮氧化物,硫氧化物烟雾
  • 图谱信息:一硫化四甲基秋兰姆(97-74-5)红外图谱(IR1) 一硫化四甲基秋兰姆(97-74-5)红外图谱(IR3) 一硫化四甲基秋兰姆(97-74-5)质谱(MS) 一硫化四甲基秋兰姆(97-74-5)核磁图( 13 CNMR) 一硫化四甲基秋兰姆(97-74-5)红外图谱(IR2) 一硫化四甲基秋兰姆(97-74-5)核磁图( 1 HNMR)
  • MSDS 信息:四甲基一硫化秋兰姆(97-74-5).msds
  • 上游原料:氰化钠 --> 促进剂 T --> 脱硫
  • Alfa Aesar:一硫化四甲基秋兰姆,97% Tetramethylthiuram monosulfide, 97%(97-74-5)
  • MOL 文件:97-74-5.mol
  • Sigma Aldrich:97-74-5(sigmaaldrich)
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • 急性毒性:腹腔-大鼠 LD50: 383 毫克/公斤; 口服-小鼠 LD50: 818 毫克/公斤
  • 用途二:橡胶促进剂,主要用于制造电缆、轮胎、胶管、胶带、艳色制品和透明制品、鞋类、耐热制品等。
  • TCI Shanghai:一硫化四甲基秋兰姆 Tetramethylthiuram Monosulfide,>;98.0%(T)(97-74-5)
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水

系列性分类


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