Bis(4-methoxyphenyl)amine 双(4-甲氧基苯基)胺

CAS 101-70-2 MFCD00014895

化学结构图

101-70-2
SMILES: COc1ccc(Nc2ccc(OC)cc2)cc1

化学属性

Mol. FormulaC14H15NO2
Mol. Weight229.27
Melting Point101-102°C
TSCAYes
Density1.126
Stability对空气敏感
Boiling Point371.1°C at 760 mmHg

别名和识别编码

Chemical NameBis(4-methoxyphenyl)amine
MDL NumberMFCD00014895
CAS Number101-70-2
EC Number202-968-1
Beilstein Registry Number2214262
Synonym Bis(4-methoxyphenyl)amine {LY} Bis(4-methoxyphenyl)amine {} {LY} Bis(4-methoxyphenyl)amine {} {} {LY} Bis(4-methoxyphenyl)amine {} {} {} {LY} Bis(4-methoxyphenyl)amine {} {} {} {} {LY} Bis(4-methoxyphenyl)amine {} {} {} {} {} {LY} Bis(4-methoxyphenyl)amine {} {} {} {} {} {} {LY} Bis(4-methoxyphenyl)amine {} {} {} {} {} {} {} {LY} Bis(4-methoxyphenyl)amine {} {} {} {} {} {} {} {} {LY} Bis(4-methoxyphenyl)amine {} {} {} {} {} {} {} {} {} {LY} Bis(4-methoxyphenyl)amine {} {} {} {} {} {} {} {} {} {} {LY} Bis(4-methoxyphenyl)amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(4-methoxyphenyl)amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(4-methoxyphenyl)amine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(4-methoxyphenyl)amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(4-methoxyphenyl)amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(4-m
Alfabeta NameBISMETHOXYPHENYLAMINE NN4()--,
Chemical Name Translation双(4-甲氧基苯基)胺
Reaxys-RN2214262
PubChem Substance ID7571
LabNetwork Molecule IDLN00182496
InChIInChI=1S/C14H15NO2/c1-16-13-7-3-11(4-8-13)15-12-5-9-14(17-2)10-6-12/h3-10,15H,1-2H3
Canonical SMILESCOC1=CC=C(NC2=CC=C(OC)C=C2)C=C1
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分类

  • {SNA} Organic and Printed Electronics, Synthetic Intermediates, Synthetic Tools and Reagents, 材料科学
  • {SNA} Materials Science, Organic and Printed Electronics, Synthetic Intermediates, Synthetic Tools and Reagents
  • {SNA} Materials Science, New Products for Materials Research and Engineering, Organic and Printed Electronics, Synthetic Intermediates, Synthetic Tools and Reagents

安全信息

RTECSDU9085000
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {}
Warnings IRRITANT
Hazard Codes Xn
GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P302+P352+
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H351 Suspected of causing cancer 怀疑致癌
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H303 May be harmfully swallowed 吞食可能有害
Signal word Warning
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2500 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - changes in motor activity (specific assay)
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   KCRZAE Kauchuk i Rezina.  Crude and Vulcanized Rubber.  (V/O Mezhdunarodnaya
   Kniga, 113095 Moscow, USSR)  V.11-    1937- Volume(issue)/page/year:
   26(9),28,1967

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2470 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - changes in motor activity (specific assay)
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   KCRZAE Kauchuk i Rezina.  Crude and Vulcanized Rubber.  (V/O Mezhdunarodnaya
   Kniga, 113095 Moscow, USSR)  V.11-    1937- Volume(issue)/page/year:
   26(9),28,1967

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 30 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 241,175,1990

其他信息

  • Alfa Aesar:4,4'-二甲氧基二苯基胺,98% 4,4'-Dimethoxydiphenylamine, 98%(101-70-2)
  • 毒性分级:中毒
  • 敏感性:Air Sensitive
  • 4,4'-二甲氧基二苯安价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0632 4,4'-二甲氧基二苯胺 4,4'-Dimethoxydiphenylamine 5G 1670元 2014/06/02 D0632 4,4'-二甲氧基二苯胺 4,4'-Dimethoxydiphenylamine 1G 539元 2010/05/25 L01322 4,4'-二甲氧基二苯基胺,98% 4,4'-Dimethoxydiphenylamine, 98% 5g 1484元
  • 急性毒性:口服-大鼠 LD50: 2470 毫克/公斤; 口服-小鼠 LD50: 2500 毫克/公斤
  • TCI Shanghai:4,4'-二甲氧基二苯胺 4,4'-Dimethoxydiphenylamine,>;98.0%(GC)(T)(101-70-2)
  • 灭火剂:干粉,泡沫,砂土,二氧化碳, 雾状水
  • MOL 文件:101-70-2.mol
  • Sigma Aldrich:101-70-2(sigmaaldrich)
  • 图谱信息:4,4'-二甲氧基二苯安(101-70-2)核磁图( 1 HNMR) 4,4'-二甲氧基二苯安(101-70-2)红外图谱(IR2) 4,4'-二甲氧基二苯安(101-70-2)核磁图( 13 CNMR) 4,4'-二甲氧基二苯安(101-70-2)红外图谱(IR1) 4,4'-二甲氧基二苯安(101-70-2)Raman光谱 4,4'-二甲氧基二苯安(101-70-2)红外图谱(IR3) 4,4'-二甲氧基二苯安(101-70-2)质谱(MS)
  • 储运特性:库房通风低温干燥
  • 可燃性危险特性:可燃; 受热分解有毒氮氧化物烟雾
  • 类别:有毒物品

系列性分类


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