Tetraisopropyl methylenediphosphonate 亚甲基二磷酸四异丙酯
CAS 1660-95-3 MFCD00015021
化学结构图
SMILES: CC(C)OP(=O)(CP(=O)(OC(C)C)OC(C)C)OC(C)C
化学属性
| Mol. Formula | C13H30O6P2 |
|---|---|
| Mol. Weight | 344.33 |
| Refractive index | 1.4310 to 1.4340 |
| Boiling Point | 155°C at 0.5 mmHg |
| Density | 1.08 |
| Flash Point | 209.2±43.5 °C |
| TSCA | Yes |
别名和识别编码
| Chemical Name | Tetraisopropyl (methylene)bisphosphonate |
|---|---|
| CAS Number | 1660-95-3 |
| PubChem Substance ID | 74266 |
| EC Number | 216-765-0 |
| Beilstein Registry Number | 1080180 |
| MDL Number | MFCD00015021 |
| Reaxys-RN | 1080180 |
| Synonym | Tetraisopropyl methylenebis(phosphonate) {LY} Tetraisopropyl methylenebis(phosphonate) {} {LY} Tetraisopropyl methylenebis(phosphonate) {} {} {LY} Tetraisopropyl methylenebis(phosphonate) {} {} {} {LY} Tetraisopropyl methylenebis(phosphonate) {} {} {} {} {LY} Tetraisopropyl methylenebis(phosphonate) {} {} {} {} {} {LY} Tetraisopropyl methylenebis(phosphonate) {} {} {} {} {} {} {LY} Tetraisopropyl methylenebis(phosphonate) {} {} {} {} {} {} {} {LY} Tetraisopropyl methylenebis(phosphonate) {} {} {} {} {} {} {} {} {LY} Tetraisopropyl methylenebis(phosphonate) {} {} {} {} {} {} {} {} {} {LY} Tetraisopropyl methylenebis(phosphonate) {} {} {} {} {} {} {} {} {} {} {LY} Tetraisopropyl methylenebis(phosphonate) {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraisopropyl methylenebis(phosphonate) {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraisopropyl methylenebis(phosphonate) {} {} {} {} {} {} {} {} {} {} { |
| Chemical Name Translation | 亚甲基二磷酸四异丙酯 |
| LabNetwork Molecule ID | LN00008124 |
| InChI | InChI=1S/C13H30O6P2/c1-10(2)16-20(14,17-11(3)4)9-21(15,18-12(5)6)19-13(7)8/h10-13H,9H2,1-8H3 |
| Canonical SMILES | O=P(CP(OC(C)C)(OC(C)C)=O)(OC(C)C)OC(C)C |
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分类
- {SNA} Analytical Standards, EP Standards, EP Standards L - M, Pharmacopeia Metrological Institutes Standards, 分析/色谱
- {SA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphonates/Phosphinates, Phosphorus Compounds
- {SNA} Analytical Standards, Analytical/Chromatography, Chromatography, EP Standards, EP Standards L - M, Pharmaceutical Standards, Pharmacopeia Standards
相关文献及参考
- gem-Bisphosphonates have application in bone tissue therapy: Synthesis, 661 (1991).
- Horner-Wadsworth-Emmons olefination (see Appendix 1) with carbonyl compounds yields vinylphosphonates: Synth. Commun., 10, 299 (1980). A synthesis of allenes via a double HWE olefination has been described: Tetrahedron, 58, 83 (2002):
安全信息
GHS Symbol
- H301 Toxic if swallowed 吞食有毒
- H302 Harmful if swallowed 吞食有害
- H311 Toxic in contact with skin 皮肤接触中毒
- H312 Harmful in contact with skin 皮肤接触有害
- H315 Causes skin irritation 会刺激皮肤
- H318 Causes serious eye damage 严重伤害眼睛
- H319 Causes serious eye irritation 严重刺激眼睛
- H331 Toxic if inhaled 吸入中毒
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
- H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310
- P301+P312
- P301+P316
- P301+P317
- P302+P350
- P302+P352
- P302+P352+P332+P313+P362+P364
- P304+P340
- P305+P351+P338
- P305+P351+P338+P310
- P305+P354+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P316
- P317
- P319
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
- P330 Rinse mouth. 漱口
- P332+P313
- P337+P313
- P337+P317
- P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
- P361+P364
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P362+P364
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S39 Wear eye/face protection 戴眼睛/面孔保护装置；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
其他信息
- 下游产品:亚甲基二磷酸
- Acros Organics:四异丙基亚甲基二磷酸盐 Tetraisopropyl methylenediphosphonate, 98%(1660-95-3)
- Alfa Aesar:亚甲基二磷酸四异丙酯,98% Tetraisopropyl methylenediphosphonate, 98%(1660-95-3)
- MOL 文件:1660-95-3.mol
- MSDS 信息:Tetraisopropyl methylenediphosphonate(1660-95-3).msds
- 图谱信息:亚甲基二磷酸四异丙酯(1660-95-3)质谱(MS)
- 亚甲基二磷酸四异丙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M1319 亚甲基二膦酸四异丙酯 Tetraisopropyl Methylenediphosphonate 25G 870元 2010/05/25 A13484 亚甲基二磷酸四异丙酯, 98% Tetraisopropyl methylenediphosphonate, 98% 50g 1890元 2010/05/25 A13484 亚甲基二磷酸四异丙酯, 98% Tetraisopropyl methylenediphosphonate, 98% 250g 8372元
- Sigma Aldrich:1660-95-3(sigmaaldrich)
- TCI Shanghai:亚甲基二膦酸四异丙基酯 Tetraisopropyl Methylenediphosphonate,>;97.0%(GC)(1660-95-3)
- 亚甲基二磷酸四异丙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 M1319 亚甲基二膦酸四异丙酯 Tetraisopropyl Methylenediphosphonate 25G 1300元 2010/05/25 A13484 亚甲基二磷酸四异丙酯, 98% Tetraisopropyl methylenediphosphonate, 98% 50g 1890元 2010/05/25 A13484 亚甲基二磷酸四异丙酯, 98% Tetraisopropyl methylenediphosphonate, 98% 250g 8372元
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