Triisopropylphosphine 三异丙基磷

CAS 6476-36-4 MFCD00015029

化学结构图

6476-36-4
SMILES: CC(C)P(C(C)C)C(C)C

化学属性

Refractive index1.466
Flash Point-17°(1°F)
TSCANo
Mol. Formula(i-C3H7)3P
Mol. Weight160
Density0.82
Appearance colorless liq.
Boiling Point176-178°C
Stabilityair sensitive

别名和识别编码

Chemical NameTriisopropylphosphine
PubChem Substance ID80969
EC Number229-333-1
Beilstein Registry Number906732
Synonym PHOSPHORUS TRIISOPROPYL TRI-I-PROPYLPHOSPHINE Triisopropylphosphine, 90+% 三异丙基膦, 90+% Tri-i-propylphosphine, tech. gr., min. 90% Tris(1-methylethyl)phosphine 三异丙基膦 Tri-i-propylphosphine,98%(Sure/Sealbottle) 三异丙基磷 TRI-I-PROPYLPHOSPHINE (10% WT. IN HEXANE) Triisopropylphosphine,98% insuresealbottle TRI-I-PROPYLPHOSPHINE: TECH., 90% Tri-i-propylphosphine,98% TRI-ISOPROPYLPHOSPHINE (SURE/SEAL BOTTLE) TRIISOPROPYLPHOSPHINE TripropylphosphineSureSealbottlecolorlessliq TRIISOPROPYLPHOSPHINE, TECH., 90% Tri-i-propylphosphine,98%(10wt%inhexane) Tri-i-propylphosphine,tech.gr.,min.90% Trisisopropylphosphine Triipropylphosphinetechgrmincolorlessliq Triipropylphosphinewtinhexane
Chemical Name Translation三异丙基磷
InChIKeyIGNTWNVBGLNYDV-UHFFFAOYSA-N
LabNetwork Molecule IDLN01796303
MDL NumberMFCD00015029
CAS Number6476-36-4
InChIInChI=1S/C9H21P/c1-7(2)10(8(3)4)9(5)6/h7-9H,1-6H3
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分类

  • {SNA} Basic Phosphine Ligands, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Phosphine Compounds, Phosphine Ligands

相关文献及参考

  • Beilstein: 4,III,1767

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P222 Do not allow contact with air. 不要与空气接触。
  • P231 Handle under inert gas. 在惰性气体中操作。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P302+P334
  • P302+P335+P334
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P405 Store locked up. 上锁保管。
  • P422 Store contents under… 存储目录在…之下。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupI
UN Number UN2845 UN 2845 4.2/PG 1 2845
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R17 Spontaneously flammable in air 在空气中能够自燃
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S17 Keep away from combustible material 远离可燃物料；
Storage condition Flammables area 储存温度2-8℃ 对空气敏感 Air Sensitive
Hazard Codes F,C F;C
Hazard Class4.2

其他信息

  • Sigma Aldrich:6476-36-4(sigmaaldrich)
  • Acros Organics:三异丙基磷 Triisopropylphosphine, 98%(6476-36-4)
  • 敏感性:Air Sensitive
  • F:10-13-23
  • MOL 文件:6476-36-4.mol
  • 三异丙基磷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 317330050 三异丙基磷 Triisopropylphosphine 98% 5 GR 2650元 2010/06/21 317330010 三异丙基磷 Triisopropylphosphine 98% 1 GR 773元 2010/05/25 33572 三异丙基膦, 90+% Triisopropylphosphine, 90+% 2g 692元
  • Alfa Aesar:三异丙基膦,98% Triisopropylphosphine, 98%(6476-36-4)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cross-Coupling - Catalysis and Inorganic Chemistry
  4. Basic Phosphine Ligands - Cross-Coupling
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cross-Coupling 交叉偶联
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds
  4. Elemental Phosphorus
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus

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