Tris(2-methylpropyl)phosphine Tri-i-butylphosphine,

CAS 4125-25-1 MFCD00015049

化学结构图

4125-25-1
SMILES: CC(C)CP(CC(C)C)CC(C)C

化学属性

Mol. Formula[(CH3)2CHCH2]3P
Mol. Weight202.32
Refractive indexn20/D 1.451(lit.)
Boiling Point126 °C/50 mmHg(lit.)
Density0.811 g/mL at 25 °C(lit.)
Appearance colorless to light yellow liq.
Stabilityair sensitive

别名和识别编码

Chemical Namemin. 93%
Synonym 三(2-甲基丙基)膦 三异丁基膦烷
PubChem Substance ID107228
EC Number223-934-2
Beilstein Registry Number1738664
MDL NumberMFCD00015049
Chemical Name TranslationTri-i-butylphosphine,
InChIKeyDAGQYUCAQQEEJD-UHFFFAOYSA-N
LabNetwork Molecule IDLN02178370
InChIInChI=1S/C12H27P/c1-10(2)7-13(8-11(3)4)9-12(5)6/h10-12H,7-9H2,1-6H3
CAS Number4125-25-1
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P222 Do not allow contact with air. 不要与空气接触。
  • P422 Store contents under… 存储目录在…之下。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P231 Handle under inert gas. 在惰性气体中操作。
Signal word Danger
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Hazard Codes F,C
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R17 Spontaneously flammable in air 在空气中能够自燃
  • R34 Causes burns 会导致灼伤

系列性分类


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