Tetraethylgermane 四乙基锗

CAS 597-63-7 MFCD00015096

化学结构图

597-63-7
SMILES: CC[Ge](CC)(CC)CC

化学属性

Mol. FormulaC8H20Ge
Mol. Weight188.88
Density0.998
Refractive index1.4410 to 1.4450
Flash Point35°C(lit.)
TSCAYes
Boiling Point165°C
Melting Point-90 °C
Appearance colorless liq.

别名和识别编码

Chemical NameTetraethylgermane
Synonym (C2H5)4Ge GERMANIUM TETRAETHYL Germane, tetraethyl- Germanium tetraethyl TETRAETHYLGERMANE TETRAETHYLGERMANIUM TETRAETHYLGERMANIUM LIQ Tetraethyl germane Tetraethylgermane Tetraethylgermane,99% Tetraethylgermanium germanium, tetraethyl- tetraethyl-german tetraethyl-germane tetraethyl-germaniu tetraethylgermane tetraethylgermanium 四乙基锗 四乙基锗,99%
MDL NumberMFCD00015096
CAS Number597-63-7
EC Number209-905-7
PubChem Substance ID11703
Chemical Name Translation四乙基锗
Reaxys-RN3660242
InChIKeyQQXSEZVCKAEYQJ-UHFFFAOYSA-N
Wiswesser Line Notation2-GE-2&2&2
Beilstein Registry Number3660242
LabNetwork Molecule IDLN01246915
InChIInChI=1S/C8H20Ge/c1-5-9(6-2,7-3)8-4/h5-8H2,1-4H3
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分类

  • {uni_hamburg} no charge; metal-organic; 1fragment
  • {SNA} CVD and ALD Precursors by Metal, Chemical Synthesis, Germanium, Materials Science, Micro/NanoElectronics, Organogermanium, Organometallic Reagents, Vapor Deposition Precursors

相关文献及参考

  • Short: III/38A Title: Refractive Indices of Inorganic, Organometallic, and Organononmetallic Liquids and Binary Liquid Mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38A Year: 1996 Keyword: organicmetallic compounds; inorganic compounds; refractive index; liquids; mixtures ISBN: 3-540-60539-8 ISBN: 978-3-540-60539-3 Internet Resource: DOI:10.1007/b55612 RefComment: VII, 400 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: IV/16 Title: Surface tension of pure liquids and binary mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/16 Year: 1997 Keyword: organic compounds; surface tension; liquids; mixtures ISBN: 3-540-63276-X ISBN: 978-3-540-63276-4 Internet Resource: DOI:10.1007/b60566 RefComment: VII, 439 pages.
  • Short: IV/18A Title: Viscosity of Pure Organic Liquids and Binary Liquid Mixtures: Pure Organometallic and Organononmetallic Liquids, Binary Liquid Mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/18A Year: 2001 Keyword: organic compounds; viscosity; liquids; mixtures ISBN: 3-540-64584-5 ISBN: 978-3-540-64584-9 Internet Resource: DOI:10.1007/b68239 RefComment: VII, 409 pages.
  • Short: IV/6 Title: Static Dielectric Constants of Pure Liquids and Binary Liquid Mixtures Author: Wohlfarth, Ch. Editor: Madelung, O. Source: Landolt-Börnstein, New Series Volume: IV/6 Year: 1991 Keyword: organic compounds; dielectric constant; liquids; mixtures ISB

安全信息

RTECSLY5290000
Packing GroupIII
UN Number 1993 UN 1993 3/PG 3 UN1993
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R10 Flammable 易燃
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P301+P312+P330
  • P303+P361+P353
  • P337+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P302+P352+P332+P313+P362+P364
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P403+P235
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P305+P351+P338+P337+P313
  • P241+P242+P243
  • P233 Keep container tightly closed. ?保持容器密闭。
Signal word Warning
Hazard Class3
Hazard Codes Xn
Storage condition Flammables area 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1241,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 780 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   31ZUAV "Investigations in the Field of Organogermanium Chemistry," Rijkens,
   F., and G.J.M. Van Der Kerk, Utrecht, Netherlands, Schotanus & Jens Utrecht
   N.V.,  1964  Volume(issue)/page/year: -,95,1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2870 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1241,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3580 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   31ZUAV "Investigations in the Field of Organogermanium Chemistry," Rijkens,
   F., and G.J.M. Van Der Kerk, Utrecht, Netherlands, Schotanus & Jens Utrecht
   N.V.,  1964  Volume(issue)/page/year: -,95,1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSUR

其他信息

  • TCI Shanghai:四乙基基锗 Tetraethylgermane,>;98.0%(GC)(597-63-7)
  • 图谱信息:四乙基锗(597-63-7)质谱(MS) 四乙基锗(597-63-7)核磁图( 1 HNMR) 四乙基锗(597-63-7)红外图谱(IR1) 四乙基锗(597-63-7)核磁图( 13 CNMR)
  • Sigma Aldrich:597-63-7(sigmaaldrich)
  • 四乙基锗价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1157 四乙基锗 Tetraethylgermane 1G 325元 2010/05/25 H27625 四乙基锗,99% Tetraethylgermanium, 99% 5g 1035元 2010/05/25 H27625 四乙基锗,99% Tetraethylgermanium, 99% 1g 311元
  • MOL 文件:597-63-7.mol
  • Alfa Aesar:四乙基锗,99% Tetraethylgermanium, 99%(597-63-7)
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. CVD & ALD Precursors
  1. CVD & ALD Precursors
  2. Germanium
  1. Metal Alkyls
  2. Germanium

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