Diethyl allylphosphonate 烯丙基膦酸二乙酯

CAS 1067-87-4 MFCD00015134

化学结构图

1067-87-4
SMILES: C=CCP(=O)(OCC)OCC

化学属性

Mol. FormulaC7H15O3P
Mol. Weight178.17
Boiling Point46 °C at 0.35 mmHg
Refractive indexn20/D 1.4340(lit.)
Density1.022
Flash Point>61°(141°F)
TSCANo

别名和识别编码

Chemical NameDiethyl allylphosphonate
Synonym Diethyl allylphosphonate {LY} Diethyl allylphosphonate {} {LY} Diethyl allylphosphonate {} {} {LY} Diethyl allylphosphonate {} {} {} {LY} Diethyl allylphosphonate {} {} {} {} {LY} Diethyl allylphosphonate {} {} {} {} {} {LY} Diethyl allylphosphonate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diethyl allylphosphonate {} {} {} {} {} {} {} {LY} Diethyl allylphosphonate {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} Diethyl allylphosphonate {} {} {} {} {} {} {} {} {} {LY} Diethyl allylphosphonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diethyl allylphosphonate {} {} {} {} {} {} {} {} {} {} {} {LY} Diethyl allylphosphonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diethyl allylphosphonate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diethyl allylphosphonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diethyl allylphosphonate {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00015134
PubChem Substance ID573014
CAS Number1067-87-4
Reaxys-RN1766603
Beilstein Registry Number4(4)3571
EC Number250-023-7
Chemical Name Translation烯丙基膦酸二乙酯
LabNetwork Molecule IDLN01115275
InChIInChI=1S/C7H15O3P/c1-4-7-11(8,9-5-2)10-6-3/h4H,1,5-7H2,2-3H3
Canonical SMILESC=CCP(=O)(OCC)OCC
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Horner-Wadsworth-Emmons Reagents, Olefination, Synthetic Reagents

相关文献及参考

  • 1. C. Negrell-Guirao, et al., J. Polym. Sci., A: Polym. Chem. 49 , 3905-3910, (2011)
  • 2. H. Konno, et al., Tetrahedron 66 , 7946-7953, (2010)
  • 3. P. Fourgeaud, et al., Tetrahedron 66 , 758-764, (2010)
  • 4. A. B. Smith III, et al., Tetrahedron 65 , 6470-6488, (2009) 摘要
  • 5. Y. Lang, et al., J. Org. Chem. 74 , 5429-5439, (2009)
  • 6. T. Hjelmgaard, et al., Org. Lett. 10 , 841-844, (2008)

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word Warning
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • Acros Organics:烯丙基磷酸二乙酯 Diethyl allylphosphonate, 97%(1067-87-4)
  • 烯丙基磷酸二乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D3069 烯丙基磷酸二乙酯 Diethyl Allylphosphonate 5G 865元 2014/06/02 D3069 烯丙基磷酸二乙酯 Diethyl Allylphosphonate 1G 319元 2010/06/21 336110050 烯丙基磷酸二乙酯 Diethyl allylphosphonate 97% 5 GR 883元
  • Sigma Aldrich:1067-87-4(sigmaaldrich)
  • Alfa Aesar:烯丙基膦酸二乙酯,95+% Diethyl allylphosphonate, 96%(1067-87-4)
  • TCI Shanghai:烯丙基磷酸二乙酯 Diethyl Allylphosphonate,>;95.0%(GC)(1067-87-4)
  • MOL 文件:1067-87-4.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphonates/Phosphinates - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Horner-Wadsworth-Emmons Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Horner-Wadsworth-Emmons Reagents - Olefination

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