Phosphine, diethyl- Diethylphosphine,
CAS 627-49-6 MFCD00015169
化学结构图
SMILES: CCPCC
化学属性
| Mol. Formula | C4H11P |
|---|---|
| Mol. Weight | 90.10 |
| Density | 0.782 g/mL at 25 °C |
| Appearance | colorless liq. |
| Boiling Point | 85°C |
| Stability | air sensitive |
别名和识别编码
| Chemical Name | 99% (10 wt% in hexanes) |
|---|---|
| Synonym | diethyl-phosphine {uni_hamburg} Diethylphosphine |
| CAS Number | 627-49-6 |
| MDL Number | MFCD00015169 |
| Chemical Name Translation | Diethylphosphine, |
| InChIKey | VZZJVOCVAZHETD-UHFFFAOYSA-N |
| PubChem Substance ID | 82948 |
| InChI | InChI=1S/C4H11P/c1-3-5-4-2/h5H,3-4H2,1-2H3 |
| LabNetwork Molecule ID | LN01477919 |
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分类
- {uni_hamburg} no charge; 1fragment
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
相关文献及参考
- Short: III/35A Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31 Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35A Year: 1997 ISBN: 3-540-60366-2 ISBN: 978-3-540-60366-5 Internet Resource: DOI:10.1007/b53033 RefComment: VIII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.
- Short: III/35C4 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds Author: Gupta, R.R.; Platzer, N. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35C4 Year: 2001 Keyword: Hydrogen 1; Nuclear Magnetic Resonance ISBN: 3-540-41059-7 ISBN: 978-3-540-41059-1 Internet Resource: DOI:10.1007/b76570 RefComment: VII, 299 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in
安全信息
GHS Symbol
- P222 Do not allow contact with air. 不要与空气接触。
- P422 Store contents under… 存储目录在…之下。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P231 Handle under inert gas. 在惰性气体中操作。
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H332 Harmful if inhaled 吸入有害
- H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
- H312 Harmful in contact with skin 皮肤接触有害
- H302 Harmful if swallowed 吞食有害
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R17 Spontaneously flammable in air 在空气中能够自燃
- R34 Causes burns 会导致灼伤
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