1-Ethoxyprop-1-ene, mixture of cis and trans 乙基丙烯醚，顺反异构体混合物

CAS 928-55-2 MFCD00015184

化学结构图

928-55-2
SMILES: C/C=C/OCC

化学属性

Mol. FormulaC5H10O
Mol. Weight86.13
Refractive index1.3960 to 1.4000
Boiling Point67-76 °C at 760 mmHg
Density0.778
Flash Point20°C(lit.)
TSCANo
Solubility可溶
Melting Point-140 °C

别名和识别编码

Chemical Name1-Ethoxyprop-1-ene, mixture of cis and trans
Synonym Ethyl propenyl ether {LY} Ethyl propenyl ether {} {LY} Ethyl propenyl ether {} {} {LY} Ethyl propenyl ether {} {} {} {LY} Ethyl propenyl ether {} {} {} {} {LY} Ethyl propenyl ether {} {} {} {} {} {LY} Ethyl propenyl ether {} {} {} {} {} {} {LY} Ethyl propenyl ether {} {} {} {} {} {} {} {LY} Ethyl propenyl ether {} {} {} {} {} {} {} {} {LY} Ethyl propenyl ether {} {} {} {} {} {} {} {} {} {LY} Ethyl propenyl ether {} {} {} {} {} {} {} {} {} {} {LY} Ethyl propenyl ether {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl propenyl ether {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl propenyl ether {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl propenyl ether {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl propenyl ether {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl propenyl ether {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00015184
CAS Number928-55-2
PubChem Substance ID253660783
EC Number213-176-0
Beilstein Registry Number1735974
Chemical Name Translation乙基丙烯醚，顺反异构体混合物
Reaxys-RN1735974
Wiswesser Line Notation2U1O2
LabNetwork Molecule IDLN00224832
Canonical SMILESC/C=C/OCC
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分类

  • {SNA} Monomers, Polymer Science, Vinyl Ethers, 材料科学
  • {uni_hamburg} no charge; ether; 1fragment
  • {SNA} Materials Science, Monomers, Polymer Science, Vinyl Ethers

相关文献及参考

  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of t
  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSKO0525000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P332+P313
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P305+P351+P338+P337+P313
  • P303+P361+P353
Signal word
Packing GroupII
UN Number UN3271
Risk Statements
  • R11 Highly flammable 非常易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
Hazard Codes F;Xi
Hazard Class3
Storage condition 2-8°C {LY} 2-8°C Flammables area {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8° 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4660 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   28,313,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 3970 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   28,313,1974

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 8000 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   28,313,1974

其他信息

  • 职业标准:75°F
  • 乙基丙烯醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 410371000 乙基丙烯醚 Ethyl propenyl ether 98%, mixture of cis- and trans-isomers 100 GR 2570元 2010/06/21 410370250 乙基丙烯醚 Ethyl propenyl ether 98%, mixture of cis- and trans-isomers 25 GR 1139元 2010/06/21 410370100 乙基丙烯醚 Ethyl propenyl ether 98%, mixture of cis- and trans-isomers 10 GR 589元
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生刺激烟雾;化学反应性能强; 燃烧产生刺激烟雾
  • Sigma Aldrich:928-55-2(sigmaaldrich)
  • 毒性分级:中毒
  • 急性毒性:口服- 大鼠LD50: 4.660 毫升/ 公斤; 吸入- 大鼠 LC50: 8000 PPM/ 4小时
  • MSDS 信息:1-Ethoxypropene(928-55-2).msds
  • 用途一:用于有机合成，也用于涂料、胶粘剂、助剂、增塑剂等
  • 类别:易燃液体
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
  • 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
  • MOL 文件:928-55-2.mol
  • 爆炸物危险特性:储藏和蒸馏过程中形成过氧化物可爆
  • Acros Organics:乙基丙烯基醚 Ethyl propenyl ether, mixture of cis- and trans-isomers, 98%(928-55-2)
  • 刺激数据:皮肤- 兔子 8.276 毫克/ 24小时 轻度; 眼睛- 兔子 500 毫克/ 24小时 轻度
  • Alfa Aesar:乙基丙烯基醚,cis+trans,97% Ethyl propenyl ether, cis + trans, 97%(928-55-2)

系列性分类

  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Vinyl Ethers - Monomers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Monomers
  4. Vinyl Esters
  1. Functional Group 官能团索引
  2. enol ether

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