[1,3-Bis(diphenylphosphino)propane]dichloronickel(II) [1,3-双(二苯基膦)丙烷]二氯化镍(II)

CAS 15629-92-2 MFCD00015318

化学结构图

15629-92-2
SMILES: Cl[Ni]Cl.c1ccc(P(CCCP(c2ccccc2)c2ccccc2)c2ccccc2)cc1

化学属性

Mol. FormulaC27H26Cl2NiP2
Mol. Weight542.05
TSCANo
Melting Point213
Density1.422
Solubility不溶
Stability对湿度敏感

别名和识别编码

Chemical Name[1,3-Bis(diphenylphosphino)propane]dichloronickel(II)
MDL NumberMFCD00015318
Synonym 1,3-双(二苯基磷)丙烷氯化镍 (1,3-dppp)NiCl2 1,3-双(二苯基膦)丙烷氯化镍(II) Ni(dppp)Cl2
CAS Number15629-92-2
PubChem Substance ID2724937
EC Number250-023-7
Beilstein Registry Number13876693
Reaxys-RN13876693
Chemical Name Translation[1,3-双(二苯基膦)丙烷]二氯化镍(II)
LabNetwork Molecule IDLN00190460
InChIInChI=1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Nickel

产品应用

  • 有机试剂,医药中间体。

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
  • S22 Do not breathe dust 不要吸入粉尘;
  • S24 Avoid contact with skin 避免皮肤接触;
Risk Statements
WGK Germany3
GHS Symbol
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P302+P350
  • P337+P313
  • P308+P313
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P302+P352+P333+P313+P362+P364
  • P304+P341
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H350 May cause cancer 可能致癌
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes T T;Xn

系列性分类


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