(Methoxymethyl)diphenylphosphine oxide (甲氧基甲基)二苯基磷氧

CAS 4455-77-0 MFCD00015451

化学结构图

4455-77-0
SMILES: COCP(=O)(c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC14H15O2P
Mol. Weight246.24
Melting Point113-120 °C
TSCANo
Boiling Point334.7±25.0 °C at 760 mmHg

别名和识别编码

Chemical Name[(methoxymethyl)(phenyl)phosphoroso]benzene
MDL NumberMFCD00015451
CAS Number4455-77-0
Synonym (Methoxymethyl)diphenylphosphine oxide {LY} (Methoxymethyl)diphenylphosphine oxide {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Me
PubChem Substance ID78203
Beilstein Registry Number649558
EC Number224-704-4
Chemical Name Translation(甲氧基甲基)二苯基磷氧
Reaxys-RN649558
InChIKeyOEPKDBQOTLDTNC-UHFFFAOYSA-N
LabNetwork Molecule IDLN00222937
InChIInChI=1S/C14H15O2P/c1-16-12-17(15,13-8-4-2-5-9-13)14-10-6-3-7-11-14/h2-11H,12H2,1H3
Canonical SMILESCOCP(C1=CC=CC=C1)(C2=CC=CC=C2)=O
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands

相关文献及参考

  • Horner olefination with aldehydes and ketones gives vinyl ethers (and hence higher aldehydes). The method is reported to be superior to the Wittig alternative. The two diastereoisomeric adducts can also be isolated and each converted to a single stereoisomer of the enol ether: J. Chem. Soc., Perkin 1, 3099 (1979):

安全信息

GHS Symbol
Hazard statements
  • H302 Harmful if swallowed 吞食有害
WGK Germany3
RTECSSZ0199360
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Hazard Codes Xn
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P330 Rinse mouth. 漱口
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   KHFZAN Khimiko-Farmatsevticheskii Zhurnal.  Chemical Pharmaceutical Journal.
    For English translation, see PCJOAU.  (V/O Mezhdunarodnaya Kniga, 113095
   Moscow, USSR)  V.1-    1967-  Volume(issue)/page/year: 24(4),22,1990

Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr

系列性分类


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