Tris(trimethylsilyl) phosphite 亚磷酸三(三甲基硅)酯
CAS 1795-31-9 MFCD00015588
化学结构图
SMILES: C[Si](C)(C)OP(O[Si](C)(C)C)O[Si](C)(C)C
化学属性
| Mol. Formula | C9H27O3PSi3 |
|---|---|
| Mol. Weight | 298.54 g/mol |
| Refractive index | 1.3990 to 1.4130 |
| Boiling Point | 73°C/10mmHg(lit.) |
| Density | 0.893 |
| TSCA | No |
| Flash Point | >;230 °F |
别名和识别编码
| Chemical Name | Tris(Trimethylsilyl)Phosphite |
|---|---|
| CAS Number | 1795-31-9 |
| PubChem Substance ID | 137213 |
| Beilstein Registry Number | 2043814 |
| MDL Number | MFCD00015588 |
| Reaxys-RN | 2043814 |
| Synonym | (三甲基硅基)亚磷酸盐 PHOSPHOROUS ACID TRIS(TRIMETHYLSILYL) ESTER Phosphorous acid tri(trimethylsilyl) ester Phosphorous acid, tristrimethylsilyl Phosphorousacidtrimethylsilylester TRIS(TRIMETHYLSILYL) PHOSPHITE 95% TRIS(TRIMETHYLSILYL)PHOSPHITE TRIS(TRIMETHYLSILYL)PHOSPHITE 97+% Tris(trimethylsiloxy)phosphine Tris(trimethylsily)phosphite Tris(trimethylsilyl) Phosphite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} |
| Chemical Name Translation | 亚磷酸三(三甲基硅)酯 |
| InChIKey | VMZOBROUFBEGAR-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN01746256 |
| InChI | InChI=1S/C9H27O3PSi3/c1-14(2,3)10-13(11-15(4,5)6)12-16(7,8)9/h1-9H3 |
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分类
- Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds
- {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds
相关文献及参考
- 1. M. Sekine, T. Hata J. Chem. Soc., Chem. Commun. , 285, (1978)
- 2. M. Sekine et al. J. Org. Chem. 46 , 2097, (1981)
- 3. L.E. Dreef et al. Tetrahedron Lett. 29 , 1199, (1988)
- 4. L. Wozniak, J. Chojnowski Tetrahedron 45 , 2465, (1989)
- FT-IR 2 (3), 4413:D / Structure Index 1 , 474:B:5
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P350
- P302+P352
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P332+P313
- P332+P317
- P337+P313
- P337+P317
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P362+P364
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
其他信息
- TCI Shanghai:亚磷酸三(三甲基硅)酯 Tris(trimethylsilyl) Phosphite,>;97.0%(T)(1795-31-9)
- Sigma Aldrich:1795-31-9(sigmaaldrich)
- F:10-21
- Alfa Aesar:亚磷酸三（三甲硅烷基）,96% Tris(trimethylsilyl) phosphite, 96%(1795-31-9)
- TSCA:No
- 三（三甲代甲硅烷基）亚磷酸盐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1217 亚磷酸三(三甲基硅)酯 Tris(trimethylsilyl) Phosphite 5ML 653元 2014/06/02 P1217 亚磷酸三(三甲基硅)酯 Tris(trimethylsilyl) Phosphite 25ML 2190元 2010/05/25 17159 亚磷酸三（三甲硅烷基）, 96% Tris(trimethylsilyl) phosphite, 96% 500mg 126元
- 敏感性:Air & Moisture Sensitive
- MOL 文件:1795-31-9.mol
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