[1,1’-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) [1,1-双(二苯基磷)二茂铁]二氯化钯

CAS 72287-26-4 MFCD00015757

化学结构图

72287-26-4
SMILES: Cl[Pd]Cl.[CH]1[CH][CH][C](P(c2ccccc2)c2ccccc2)[CH]1.[CH]1[CH][CH][C](P(c2ccccc2)c2ccccc2)[CH]1.[Fe]

化学属性

Mol. FormulaC36H46Cl2FeP2Pd
Mol. Weight731.70
Melting Point275-280°C
Density1.422
TSCANo
Stability对空气和湿度敏感
RedoxReduction

别名和识别编码

Chemical Name[1,1’-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
CAS Number72287-26-4
Alfabeta NameBISDIPHENYLPHOSPHINOFERROCENEDICHLOROPALLADIUM II11[](())--,'
MDL NumberMFCD00015757
Synonym [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {} {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {} {} {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {} {} {} {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {} {} {} {} {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {} {} {} {} {} {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {} {} {} {} {} {} {} {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {} {} {} {} {} {} {} {} {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichlorop
EC Number460-040-3
Beilstein Registry Number2384789
Chemical Name Translation[1,1-双(二苯基磷)二茂铁]二氯化钯
PubChem Substance ID87564938
LabNetwork Molecule IDLN01358266
Canonical SMILES[][Fe][].Cl[Pd]([P](C1=CC=CC=C1)(C2=CC=CC=C2)c3cccc3)([P](C4=CC=CC=C4)(C5=CC=CC=C5)c6cccc6)Cl
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium Catalysts
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium

产品应用

  • A catalyst for Suzuki and Stille couplings

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P304+P340+P312
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P305+P351+P338
  • P302+P352+P312+P362+P364
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302+H312+H332
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr

其他信息

  • This product is useful for the borylation of triflate with pinacolborane.
  • 不溶于水,溶于氯仿,微溶于二氯甲烷。

系列性分类


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