[1,1’-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) [1,1-双(二苯基磷)二茂铁]二氯化钯

CAS 72287-26-4 MFCD00015757

化学结构图

72287-26-4
SMILES: Cl[Pd]Cl.[CH]1[CH][CH][C](P(c2ccccc2)c2ccccc2)[CH]1.[CH]1[CH][CH][C](P(c2ccccc2)c2ccccc2)[CH]1.[Fe]

化学属性

Mol. FormulaC36H46Cl2FeP2Pd
Mol. Weight731.70
Melting Point275-280°C
Density1.422
TSCANo
Stability对空气和湿度敏感
RedoxReduction

别名和识别编码

Chemical Name[1,1’-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
CAS Number72287-26-4
Alfabeta NameBISDIPHENYLPHOSPHINOFERROCENEDICHLOROPALLADIUM II11[](())--,'
MDL NumberMFCD00015757
Synonym [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {} {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {} {} {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {} {} {} {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {} {} {} {} {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {} {} {} {} {} {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {} {} {} {} {} {} {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {} {} {} {} {} {} {} {} {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {} {} {} {} {} {} {} {} {} {LY} [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) {} {} {} {} {} {
EC Number460-040-3
Beilstein Registry Number2384789
Chemical Name Translation[1,1-双(二苯基磷)二茂铁]二氯化钯
PubChem Substance ID87564938
LabNetwork Molecule IDLN01358266
Canonical SMILES[][Fe][].Cl[Pd]([P](C1=CC=CC=C1)(C2=CC=CC=C2)c3cccc3)([P](C4=CC=CC=C4)(C5=CC=CC=C5)c6cccc6)Cl
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium Catalysts
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium

产品应用

  • A catalyst for Suzuki and Stille couplings

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P304+P340+P312
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P305+P351+P338
  • P302+P352+P312+P362+P364
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302+H312+H332
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr

其他信息

  • This product is useful for the borylation of triflate with pinacolborane.
  • 不溶于水，溶于氯仿，微溶于二氯甲烷。

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Titration - Analytical Reagents
  4. Karl Fischer Titration HYDRANAL® Reagents for Water Determination
  5. Coulometric Reagents for Coulometric Karl Fischer Titration
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Palladium Catalysis 钯催化剂
  4. Homogeneous Pd Catalysts - Palladium
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metallocenes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  4. Palladium 钯催化剂
  5. Heterogeneous Pd Catalysts
  1. Functional Group 官能团索引
  2. phosphine
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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