Tetrarhodium Dodecacarbonyl 十二羰基四铑

CAS 19584-30-6 MFCD00016310

化学结构图

19584-30-6
SMILES: [Rh].[Rh].[Rh].[Rh].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

化学属性

Mol. FormulaC12O12Rh4
Mol. Weight747.75
Density2.52
Appearance dark red xtl.
Stabilityair sensitive, light sensitive, store cold

别名和识别编码

Chemical NameTetrarhodium Dodecacarbonyl
Synonym {uni_hamburg} Dodecacarbonyltetrarhodium Rhodium, tri-μ-carbonylnonacarbonyltetra-, tetrahedro tri μ carbonylnonacarbonyl tetrahedro tetrarhodium Rhodium carbonyl (Rh4(CO)12), tetrahedro- Rhodium, tri-μ-carbonylnonacarbonyltetra-, tetrahedro- Rhodium, tri μ carbonylnonacarbonyltetra-, tetrahedro 十二羰基四铑 Tetrarhodium dodecacarbonyl Rhodium carbonyl (Rh4(CO)12) Tri(μ-carbonyl)nonacarbonyltetrarhodium tri-μ-carbonylnonacarbonyl-tetrahedro-tetrarhodium Tetrakis[tricarbonylrhodium]
PubChem Substance ID24863783
EC Number243-171-9
Chemical Name Translation十二羰基四铑
MDL NumberMFCD00016310
CAS Number19584-30-6
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分类

  • {uni_hamburg} no charge; metal-organic; other heterocycle; alicycle; large ring; fused rings; 3ring; 4ring; 5ring; 6ring; 7ring; 8ring; metal carbonyl; 1fragment
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium

相关文献及参考

  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1
  • Short: III/35D5 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 5: Organometallic Compounds Author: Mikhova, Bozhana Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D5 Year: 2008 Keyword: Carbon-13; chemical shift; magnetic properties of nuclei; nuclear magnetic resonance data ISBN: 978-3-540-74188-6 (print) ISBN: 978-3-540-74189-3 (electronic) Internet Resource: DOI:10.1007/978-3-540-74189-3 RefComment: VIII, 241 p., Hardcover RefComment: Written for Scientists and engineers in the fields of physics, chemistry and physical chemistry who intend to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, oriented by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 Nuclear Magnetic Resonance (NMR) Data is therefore of major interest to all scientists and engineers who intend to use NMR to study the structure and the binding of molecules. Volume III/35 "NMR-Data" is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei 11B and 31P, subvolume III/35B contains the nuclei 19F and 15N, subvolume III/35C contains the nucleus 1H, subvolume III/35D contains the nucleus 13C, subvolume III/35E contains the nucleus 17O, and subvolume III/35G contains the nucleus 77Se. More nuclei will be presented later.

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Signal word Warning
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害

系列性分类


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