Dibenzyl diazene-1,2-dicarboxylate 偶氮二羟酸二苄酯

CAS 2449-05-0 MFCD00016737

化学结构图

2449-05-0
SMILES: O=C(N=NC(=O)OCc1ccccc1)OCc1ccccc1

化学属性

Mol. FormulaC16H14N2O4
Mol. Weight298.30
Density1.19
Melting Point43-47°C
Flash Point>110°C
TSCAYes
Boiling Point456.8°C at 760 mmHg

别名和识别编码

Chemical NameDibenzyl Azodicarboxylate
CAS Number2449-05-0
EC Number219-508-0
Beilstein Registry Number2298734
MDL NumberMFCD00016737
Synonym Dibenzyl diazene-1,2-dicarboxylate {LY} Dibenzyl diazene-1,2-dicarboxylate {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {} {} {} {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {} {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {} {} {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {} {} {} {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {} {} {} {} {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibenzyl diazene-1,2-dicarboxylate {} {} {} {} {} {}
PubChem Substance ID75557
Alfabeta NameDIBENZYLAZODICARBOXYLATE
Reaxys-RN5292523
Chemical Name Translation偶氮二羟酸二苄酯
LabNetwork Molecule IDLN00226655
InChIInChI=1S/C16H14N2O4/c19-15(21-11-13-7-3-1-4-8-13)17-18-16(20)22-12-14-9-5-2-6-10-14/h1-10H,11-12H2
Canonical SMILESO=C(OCC1=CC=CC=C1)\N=N\C(=O)OCC1=CC=CC=C1
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分类

  • {SNA} Azo/Diazo Compounds, Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • For the formation of functionalized ß-amino alcohols by the three-component asymmetric assembly with an aldehyde and a ketone, see: Org. Lett, 5, 1685 (2003).
  • Beilstein: 6,IV,2467
  • Aza-dienophile; the cycloaddition products can be debenzylated by hydrogenolysis: J. Am. Chem. Soc., 109, 285 (1987); 110, 5229 (1988); 111, 2995 (1989). Compare Di-tert-butyl­ azodicarboxyl­ate, L00294, Diethyl­ azodicarboxyl­ate, L19348, and Diisopropyl­ azodicarboxyl­ate, L10386. Effects enantioselective ɑ-amination of aldehydes, mediated by L-Proline, A10199: J. Am. Chem. Soc., 124, 5656 (2002):

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R11 Highly flammable 非常易燃
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H242 Heating may cause a fire 加热可能会引起火灾
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes F;Xi
Warnings IRRITANT
Storage condition 2-8°C {LY} 2-8°C Light Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {}
UN Number 3223
Hazard Class4.1

其他信息

  • 外观性质:柠檬黄结晶固体。 熔点：44℃-46℃
  • Acros Organics:Dibenzyl azodicarboxylate, 94%(2449-05-0)
  • 偶氮二甲酸二苄酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0776 偶氮二甲酸二苄酯(40%的二氯甲烷溶液,约1.7mol/L） Dibenzyl Azodicarboxylate (40% in Dichloromethane, ca. 1.7mol/L) 25G 1170元 2010/06/21 270270050 偶氮二甲酸二苄酯 Dibenzyl azodicarboxylate 94% 5 GR 666元 2010/06/21 270270250 偶氮二甲酸二苄酯 Dibenzyl azodicarboxylate 94% 25 GR 2294元
  • MSDS 信息:Dibenzyl azodicarboxylate(2449-05-0).msds
  • Sigma Aldrich:2449-05-0(sigmaaldrich)
  • Alfa Aesar:偶氮二羟酸二苄酯,98% Dibenzyl azodicarboxylate, 98%(2449-05-0)
  • MOL 文件:2449-05-0.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Azo/Diazo Compounds - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Azo/Diazo Compounds - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Oximes - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Mitsunobu Reaction
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺
  6. C9 to C10
  1. Functional Group 官能团索引
  2. azo compound

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