Tetrahydrofurfuryl bromide 四氢呋喃甲基溴

CAS 1192-30-9 MFCD00016894

化学结构图

1192-30-9
SMILES: BrCC1CCCO1

化学属性

Mol. FormulaC5H9BrO
Mol. Weight165.03
Refractive index1.4850 to 1.4890
Density1.452
Flash Point73°C(lit.)
TSCAYes
Boiling Point181.4°C at 760 mmHg
Appearance 液体。沸点168-170℃（98.95kPa），69-70℃（2.93kPa），60-61℃（1.6kPa），相对密度1.3653（20/4℃），折光率1.4850。溶于乙醚和乙醇。

别名和识别编码

Chemical NameTetrahydrofurfuryl bromide
Synonym 2-(Bromomethyl)tetrahydrofuran {LY} 2-(Bromomethyl)tetrahydrofuran {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {} {}
MDL NumberMFCD00016894
CAS Number1192-30-9
Reaxys-RN102717
Beilstein Registry Number17(5)1,80
PubChem Substance ID14501
EC Number214-750-3
Alfabeta NameBROMOMETHYLTETRAHYDROFURAN 2()-
Chemical Name Translation四氢呋喃甲基溴
Wiswesser Line NotationT5OTJ B1E
InChIKeyVOHILFSOWRNVJJ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00182489
InChIInChI=1S/C5H9BrO/c6-4-5-2-1-3-7-5/h5H,1-4H2
Canonical SMILESBrCC1CCCO1
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分类

  • {SNA} Building Blocks, C4 to C7, Chemical Synthesis, Furans, Halogenated Heterocycles, Heterocyclic Building Blocks
  • {uni_hamburg} no charge; oxygen heterocycle; alicycle; 5ring; ether; racemate; 1fragment

相关文献及参考

  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: IV/16 Title: Surface tension of pure liquids and binary mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/16 Year: 1997 Keyword: organic compounds; surface tension; liquids; mixtures ISBN: 3-540-63276-X ISBN: 978-3-540-63276-4 Internet Resource: DOI:10.1007/b60566 RefComment: VII, 439 pages.

安全信息

RTECSLU6000000
Storage condition 2-8°C {LY} 2-8°C Refrigerator {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C
Signal word Warning
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Hazard Codes Xn Xi
Warnings IRRITANT
UN Number 1993
GHS Symbol 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03416

WGK Germany3

其他信息

  • 2-溴甲基四氢呋喃价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1808 四氢呋喃甲基溴 Tetrahydrofurfuryl Bromide 500G 2950元 2014/06/02 T1808 四氢呋喃甲基溴 Tetrahydrofurfuryl Bromide 25G 416元 2010/06/21 210940500 2-溴甲基四氢呋喃 Tetrahydrofurfuryl bromide 90%, tech. 50 GR 1646元
  • 上游原料:四氢糠醇
  • 用途一:医药中间体。
  • Acros Organics:(2-溴甲基)四氢呋喃 Tetrahydrofurfuryl bromide, tech., 90%(1192-30-9)
  • 下游产品:alpha-(1-萘甲基)-2-四氢呋喃丙酸二乙胺基乙基酯草酸盐 --> 1-甲基-1H-吡唑-5-甲酸乙酯
  • TCI Shanghai:2-溴甲基四氢呋喃 Tetrahydrofurfuryl Bromide,>;95.0%(GC)(1192-30-9)
  • Alfa Aesar:溴化氢糠,95% Tetrahydrofurfuryl bromide, 95%(1192-30-9)
  • MOL 文件:1192-30-9.mol
  • 图谱信息:2-溴甲基四氢呋喃(1192-30-9)质谱(MS) 2-溴甲基四氢呋喃(1192-30-9)红外图谱(IR1) 2-溴甲基四氢呋喃(1192-30-9)核磁图( 13 CNMR) 2-溴甲基四氢呋喃(1192-30-9)核磁图( 1 HNMR)
  • 方法一:由四氢呋喃甲醇溴化而得。将苯和三溴化磷加入反应锅，搅拌冷却至0℃左右，均匀滴加四氢呋喃甲醇和吡啶的混合液，滴加完毕，搅拌1h，升温至20℃搅拌1h。放置过夜，减压蒸馏，收集55-130℃（2.67kPa）馏分，得四氢呋喃甲基溴。
  • MSDS 信息:2-(Bromomethyl)tetrahydrofuran(1192-30-9).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Furans 呋喃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Furans 呋喃
  5. C4 to C7 - Furans

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