Triphenylfluorosilane 三苯甲基氟硅烷

CAS 379-50-0 MFCD00017899

化学结构图

379-50-0
SMILES: F[Si](c1ccccc1)(c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC18H15FSi
Mol. Weight278.40
Melting Point62-64°C
Boiling Point347.3 °C at 760 mmHg
Flash Point>200°C
Density1,212 g/cm3

别名和识别编码

Chemical NameTriphenylfluorosilane
Synonym Fluorotriphenylsilane {LY} Fluorotriphenylsilane {} {LY} Fluorotriphenylsilane {} {} {LY} Fluorotriphenylsilane {} {} {} {LY} Fluorotriphenylsilane {} {} {} {} {LY} Fluorotriphenylsilane {} {} {} {} {} {LY} Fluorotriphenylsilane {} {} {} {} {} {} {LY} Fluorotriphenylsilane {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {LY} Fluorotriphenylsilane {} {} {} {} {} {} {} {} {LY} Fluorotriphenylsilane {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} Fluorotriphenylsilane {} {} {} {} {} {} {} {} {} {} {LY} Fluorotriphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorotriphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorotriphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorotriphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorotriphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorotriphenylsilane
MDL NumberMFCD00017899
CAS Number379-50-0
PubChem Substance ID87570203
Beilstein Registry Number16(4)1484
EC Number206-832-2
Reaxys-RN2941368
Chemical Name Translation三苯甲基氟硅烷
InChIKeyUBGXLEFOIVWVRP-UHFFFAOYSA-N
LabNetwork Molecule IDLN01360876
InChIInChI=1S/C18H15FSi/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
Canonical SMILESF[Si](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Chemical Synthesis, Protecting and Derivatizing Reagents, Protection and Derivatization, Silicon-Based, Synthetic Reagents

相关文献及参考

  • Short: III/35F Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Silicon-29 Author: Marsmann, H.C.; Uhlig, F.; Gupta, R.R.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35F Year: 2008 Keyword: NMR; Si-29; chemical shifts; coupling constants; nuclear magnetic resonance; silicon-29 ISBN: 978-3-540-45277-5 (print) ISBN: 978-3-540-45278-2 (electronic) Internet Resource: DOI: 10.1007/978-3-540-45278-2 RefComment: X, 463 p. 40 illus., Hardcover RefComment: Written for: Scientists and engineers in the fields of physics, chemistry, and physical chemistry who intend to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, oriented by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment, i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 "Nuclear Magnetic Resonance (NMR) Data" is therefore of major interest to all scientists and engineers who intend to use NMR to study the structure and the binding of molecules. Volume III/35 ''NMR-Data'' is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei B-11 and P-31, subvolume III/35B contains the nuclei F-19 and N-15, subvolume III/35C contains the nucleus H-1, subvolume III/35D contains the nucleus C-13, subvolume III/35E contains the nucleus O-17, subvolume III/35F contains the nucleus Si-29, and subvolume III/35G contains the nucleus Se-77. More nuclei will be presented later.
  • Short: EINECS Title: EINECS (European Inventory of Existin

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P304+P340
  • P304+P340+P310
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P305+P351+P338
  • P301+P330+P331
  • P303+P361+P353+P310+P363
  • P405 Store locked up. 上锁保管。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Danger
Hazard Codes C C,Xi
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R14 Reacts violently with water 遇水会猛烈反应
UN Number UN 3261 8/PG 2 3261
Packing GroupII
Hazard Class8
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Sigma Aldrich:379-50-0(sigmaaldrich)
  • MOL 文件:379-50-0.mol
  • Hazard Note:Irritant
  • TCI Shanghai:三苯甲基氟硅烷 Fluorotriphenylsilane(379-50-0)
  • F:10
  • 三苯甲基氟硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 F0439 三苯甲基氟硅烷 Fluorotriphenylsilane 5G 824元 2014/06/02 F0439 三苯甲基氟硅烷 Fluorotriphenylsilane 25G 2440元
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Protecting and Derivatizing Reagents - Protection and Derivatization
  5. Silicon-Based - Protecting and Derivatizing Reagents

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