Methyl 2-(2,4-Dichlorophenoxy)Acetate 2-(2,4-二氯苯氧基)乙酸甲酯

CAS 1928-38-7 MFCD00018356

化学结构图

1928-38-7
SMILES: COC(=O)COc1ccc(Cl)cc1Cl

化学属性

Mol. FormulaC9H8Cl2O3
Mol. Weight235.06
Flash Point-26 °C
Melting Point119 °C
Boiling Point335.78 °C at 760 mmHg

别名和识别编码

Chemical NameMethyl 2-(2,4-Dichlorophenoxy)Acetate
Synonym 2,4-D methyl ester {LY} 2,4-D methyl ester {} {LY} 2,4-D methyl ester {} {} {LY} 2,4-D methyl ester {} {} {} {LY} 2,4-D methyl ester {} {} {} {} {LY} 2,4-D methyl ester {} {} {} {} {} {LY} 2,4-D methyl ester {} {} {} {} {} {} {LY} 2,4-D methyl ester {} {} {} {} {} {} {} {LY} 2,4-D methyl ester {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} 2,4-D methyl ester {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} 2,4-D methyl ester {} {} {} {} {} {} {} {} {} {} {LY} 2,4-D methyl ester {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-D methyl ester {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-D methyl ester {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-D methyl ester {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-D methyl ester {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-D methyl ester {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00018356
PubChem Substance ID1488
Beilstein Registry Number2053392
CAS Number1928-38-7
EC Number217-670-7
Alfabeta NameMETHYLDICHLOROPHENOXYACETATE 24()-,
Chemical Name Translation2-(2,4-二氯苯氧基)乙酸甲酯
Wiswesser Line NotationGR CG DO1VO1
LabNetwork Molecule IDLN00182999
InChIInChI=1S/C9H8Cl2O3/c1-13-9(12)5-14-8-3-2-6(10)4-7(8)11/h2-4H,5H2,1H3
Canonical SMILESO=C(COC1=CC=C(C=C1Cl)Cl)OC
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分类

  • {SNA} 2,4-D metabolites, 2000/60/EC, Alphabetical Index of Analytical Standards, Analytical Standards, Chromatography, D, Environmental Standards, European Community: ISO, DIN and DL 152, M, META - METH, Method and Regulation Specific, Phenoxy structure, 代谢物, 农残和代谢标准品, 分析/色谱, 按照字母排序, 灭草剂
  • 2,4-D metabolites, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Herbicides, M, META - METH,
  • {SNA} 2,4-D metabolites,

相关文献及参考

  • Short: IV/20A Title: Vapor Pressure and Antoine Coefficients for Hydrocarbons and Sulfur-, Selenium-, Tellurium-, and Halogen-Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20A Year: 1999 Keyword: organic compounds; vapor pressure ISBN: 3-540-64735-X ISBN: 978-3-540-64735-5 Internet Resource: DOI:10.1007/b71086 RefComment: VIII, 373 pages.
  • Short: IV/20B Title: Vapor Pressure and Antoine Coefficients for Oxygen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20B Year: 2000 Keyword: organic compounds; vapor pressure ISBN: 3-540-64968-9 ISBN: 978-3-540-64968-7 Internet Resource: DOI:10.1007/b71424 RefComment: VII, 320 pages.
  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSAG8810000
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P302+P352
  • P304+P312
  • P304+P340
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P333+P313
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H332 Harmful if inhaled 吸入有害
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Hazard Codes Xn,N F,Xn,N
WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Signal word Warning
Warnings IRRITANT
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S46 If swallowed, seek medical advice immediately and show this container or label 食入时，立即求医并出示容器/标签；
  • S29 Do not empty into drains 不要排入下水道；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
Risk Statements
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R11 Highly flammable 非常易燃
  • R48/20
  • R38 Irritating to skin 刺激皮肤
  • R51/53
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R22 Harmful if swallowed 吞咽有害
  • R50/53
Packing GroupIII
Storage condition 0-6°C
Hazard Class6.1(b)
UN Number 3345 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 945 mg/kg
SEX/DURATION            : female 6-14 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-160

其他信息

  • MOL 文件:1928-38-7.mol
  • Sigma Aldrich:1928-38-7(sigmaaldrich)

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Metabolites - Pesticides & Metabolites
  7. 2,4-D metabolites - Metabolites
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. M - Alphabetic
  5. META - METH - M
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. D - Alphabetic
  5. DA - DH - D
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. D - Alphabetic
  5. DA - DH - D

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