2,3,4,6-Tetrachlorophenol 2,3,4,6-四氯苯酚(含约的五氯苯酚)

CAS 58-90-2 MFCD00019979

化学结构图

58-90-2
SMILES: Oc1c(Cl)cc(Cl)c(Cl)c1Cl

化学属性

Mol. FormulaC6H2Cl4O
Mol. Weight232
Density1.839
Melting Point69-70°C
TSCAYes
Boiling Point164°C
Flash Point11 °C
Solubility难溶于水,溶于丙酮、苯、乙醚、氯仿、四氯化碳、乙醇。

别名和识别编码

Chemical Name2,3,4,6-Tetrachlorophenol
CAS Number58-90-2
Synonym 1-Hydroxy-2,3,4,6-tetrachlorobenzene 2 2,3,4,6-TCP 2,3,4,6-TECP 2,3,4,6-TETRACHLOROPHENOL 2,3,4,6-TETRACHLOROPHENOL, 100MG, NEAT 2,3,4,6-TETRACHLOROPHENOL, 1X1ML, MEOH 5 000UG/ML 2,3,4,6-TETRACHLOROPHENOL: TECH., 90% 2,3,4,6-Tetrachlor-phenol 2,3,4,6-Tetrachloro-phenol 2,3,4,6-Tetrachlorophenate 2,3,4,6-Tetrachlorophenol 2,3,4,6-Tetrachlorophenol (contains ca. 10% Pentachlorophenol) 2,3,4,6-Tetrachlorphenol 2,3,4,6-tetrachloro-pheno 2,3,4,6-tetrachloro-phenol 2,3,4,6-tetrachlorophenol 2,3,4,6-四氯苯酚 2,3,4,6-四氯苯酚, TECH 2,3,4,6-四氯酚 2,3,4,6-四氯酚 溶液 2,3,4,6-四氯酚;2,3,4,6-四氯苯酚 2,4,5,6-Tetrachlorophenol 2,3,4,6-四氯苯酚 2,4,5,6-Tetrachlorophenol 3 4 6-四氯苯酚 6-四氯酚 Chlorophenols DOWICIDE 6(R) Dowicide 6 NSC 2428 Phenol, 2,3,4,6-tetrachloro- RCRA waste number U212 SONTOX 6(R) TCP dowicide6 phenol, 2,3,4,6-tetrachloro- rcrawastenumberu212 {} {uni_hamburg} 砷原子吸收标样
PubChem Substance ID6028
EC Number200-659-6
Beilstein Registry Number0779754
MDL NumberMFCD00019979
Chemical Name Translation2,3,4,6-四氯苯酚(含约的五氯苯酚)
Wiswesser Line NotationQR BG CG DG FG
LabNetwork Molecule IDLN01300104
InChIInChI=1S/C6H2Cl4O/c7-2-1-3(8)6(11)5(10)4(2)9/h1,11H
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分类

  • Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Pesticides & Metabolites, Q-Z, T, TA - TE
  • {SNA} Alphabetical Index of Analytical Standards, Chemical Class, Method and Regulation Specific, Alpha Sort, Analytical Standards, Analytical
  • {SNA} All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Pesticides & Metabolites, Q-Z, T, TA - TE

产品应用

  • 用作杀虫剂、消毒剂和木材、乳胶、皮革防腐剂。

相关文献及参考

  • Beilstein:6(4)1021
  • Gulcan, H., et al.: Chem. Res. Toxicol., 21, 1503 (2008),
  • Short: III/35D2
  • Short: IV/20A
  • Toropov, A., et al.: Bioorg. Med. Chem., 16, 5999 (2008),

安全信息

GHS Symbol
WGK Germany1
Hazard Codes T,N T,N,F F,T
Hazard statements
  • H370 Causes damage to organs 导致器官损伤
  • H331 Toxic if inhaled 吸入中毒
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H301 Toxic if swallowed 吞食有毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301+H311
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H315 Causes skin irritation 会刺激皮肤
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
Precautionary statements
  • P301+P310
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P305+P351+P338
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
Signal word Danger
RTECSSM9275000
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S7 Keep container tightly closed 保存在严格密闭容器中;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S37 Wear suitable gloves 戴适当手套;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Packing GroupIII
UN Number UN2020 2020
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R50/53
  • R11 Highly flammable 非常易燃
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性:吸入,皮肤接触和吞食都会产生十分严重的不可逆危险
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R52/53
Hazard Class6.1(b)
Storage condition APPROX 4°C 低温显示 储存温度2-8℃
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Blood - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-159

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 140 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   48RKAL "Industrial and Environmental Xenobiotics: Metabolism and
   Pharmacokinetics of Organic Chemicals and Metals, Proceedings of an
   International Conference, Prague

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 485 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - muscle weakness
REFERENCE :
   BECTA6 Bulletin of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   07094)  V.1-    1966-  Volume(issue)/page/year: 31,680,1983

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - gerbil
DOSE/DURATION           : 698 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   40,63,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : R

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 210 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBTXAC "Handbook of Toxicology,"

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 250 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 241,175,1990

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 3500 ug/L
REFERENCE :
   CMSHAF Chemosphere.  (Pergamon Press Inc., Maxwell House, Fairview Park,
   Elmsford, NY 10523) V.1-    1972-  Volume(issue)/page/year: 14,1617,1985

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 300 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   28,146,1974

其他信息

  • 外观性质:白色针状结晶,有强烈特殊气味。
  • 可燃性危险特性:可燃; 燃烧释放有毒氯化物烟雾
  • 类别:农药
  • 毒性分级:高毒
  • Alfa Aesar:2,3,4,6-Tetrachlorophenol, tech. 90%(58-90-2)
  • 有强烈特殊气味;蒸汽压 7.98kPa(190℃);溶解性:难溶于水,溶于丙酮、苯、乙醚、氯仿、四氯化碳、乙醇.稳定性:稳定;危险标记 15(有害品,远离食品);
  • Sigma Aldrich:58-90-2(sigmaaldrich)
  • TCI Shanghai:2,3,4,6-四氯苯酚(含约10%的五氯苯酚) 2,3,4,6-Tetrachlorophenol (contains ca. 10% Pentachlorophenol),>;90.0%(GC)(58-90-2)
  • MSDS 信息:2,3,4,6-四氯苯酚(58-90-2).msds
  • 砷原子吸收标样价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0068 2,3,4,6-四氯苯酚(含约10%的五氯苯酚) 2,3,4,6-Tetrachlorophenol (contains ca. 10% Pentachlorophenol) 25G 943元
  • 灭火剂:雾状水、泡沫、二氧化碳、砂土
  • MOL 文件:58-90-2.mol
  • 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂分开存放
  • 图谱信息:砷原子吸收标样(58-90-2)红外图谱(IR3) 砷原子吸收标样(58-90-2)核磁图( 1 HNMR) 砷原子吸收标样(58-90-2)红外图谱(IR1) 砷原子吸收标样(58-90-2)红外图谱(IR2) 砷原子吸收标样(58-90-2)质谱(MS) 砷原子吸收标样(58-90-2)核磁图( 13 CNMR)
  • 酚类单一化合物标准液
  • 职业标准:TWA 0.5 毫克/立方米; STEL 1.5 毫克/立方米
  • 急性毒性:口服-大鼠 LD50: 140 毫克/公斤;腹腔-小鼠LDL0: 250 毫克/公斤
  • 砷原子吸收标样价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 T0068 2,3,4,6-四氯苯酚(含约10%的五氯苯酚) 2,3,4,6-Tetrachlorophenol (contains ca. 10% Pentachlorophenol) 25G 857元
  • 用途一:用作杀虫剂、消毒剂和木材、乳胶、皮革防腐剂。

系列性分类


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