N,N-1,3-Phenylene Bismaleimide N,N-间苯撑双马来酰亚胺

CAS 3006-93-7 MFCD00022569

化学结构图

3006-93-7
SMILES: O=C1C=CC(=O)N1c1cccc(N2C(=O)C=CC2=O)c1

化学属性

Mol. FormulaC14H8N2O4
Mol. Weight268.22
Melting Point198-201 °C
Solubility可忽略 可溶
Appearance N,N'-间苯撑双马来酰亚胺(3006-93-7)为黄色或棕色粉末,比重1.44,可溶于二氧六环、四氢呋喃和热丙酮中,不溶于石油醚、氯仿、苯和水中。
Boiling Point499.3°C at 760 mmHg

别名和识别编码

Chemical NameN,N-1,3-Phenylene Bismaleimide
MDL NumberMFCD00022569
PubChem Substance ID87575090
CAS Number3006-93-7
EC Number221-112-8
Reaxys-RN249503
Synonym N,N-1,3-Phenylenedimaleimide {LY} N,N-1,3-Phenylenedimaleimide {} {LY} N,N-1,3-Phenylenedimaleimide {} {} {LY} N,N-1,3-Phenylenedimaleimide {} {} {} {LY} N,N-1,3-Phenylenedimaleimide {} {} {} {} {LY} N,N-1,3-Phenylenedimaleimide {} {} {} {} {} {LY} N,N-1,3-Phenylenedimaleimide {} {} {} {} {} {} {LY} N,N-1,3-Phenylenedimaleimide {} {} {} {} {} {} {} {LY} N,N-1,3-Phenylenedimaleimide {} {} {} {} {} {} {} {} {LY} N,N-1,3-Phenylenedimaleimide {} {} {} {} {} {} {} {} {} {LY} N,N-1,3-Phenylenedimaleimide {} {} {} {} {} {} {} {} {} {} {LY} N,N-1,3-Phenylenedimaleimide {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-1,3-Phenylenedimaleimide {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-1,3-Phenylenedimaleimide {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-1,3-Phenylenedimaleimide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-1,3-Phenylenedimaleimide {} {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name TranslationN,N-间苯撑双马来酰亚胺
Beilstein Registry Number249503
InChIKeyIPJGAEWUPXWFPL-UHFFFAOYSA-N
Wiswesser Line NotationT5VNVJ BR C- BT5VNVJ
LabNetwork Molecule IDLN00240894
Canonical SMILESC1=CC(=CC(=C1)N2C(=O)C=CC2=O)N3C(=O)C=CC3=O
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分类

  • {SNA} Acrylic Monomers, Maleimide, Materials Science, Monomers, Polymer Science
  • Acrylic Monomers, Maleimide, Materials Science, Monomers, Polymer Science
  • {SNA} Acrylic Monomers, Maleimide, Monomers, Polymer Science, 材料科学

相关文献及参考

  • Beil. 21 ,IV,4640
  • FT-IR 2 (2), 3070:D / FT-NMR 1 (2), 1455:A / RegBook 1 (2), 2077:G / Structure Index 1 , 328:D:8

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P312+P330
  • P304+P340+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard statements
  • H330 Fatal if inhaled 吸入致命
  • H302 Harmful if swallowed 吞食有害
  • H311 Toxic in contact with skin 皮肤接触中毒
Hazard Codes 6.1 T T+
RTECSON6125000
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
UN Number 2811 UN 2811 6.1/PG 2
Safety Statements
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
Packing GroupII
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class6.1
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 40(11),109,1975

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 55 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EPASR* United States Environmental Protection Agency, Office of Pesticides
   and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW,
   Washington, DC 20460)  History unknown.  Volume(issue)/page/year:
   8EHQ-0790-1023S

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1370 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 40(11),109,1975

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,22,1953

其他信息

  • N,N'-间苯撑双马来酰亚胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0976 N,N'-1,3-苯撑双马来酰亚胺 N,N'-1,3-Phenylenedimaleimide 500G 2750元 2014/06/02 P0976 N,N'-1,3-苯撑双马来酰亚胺 N,N'-1,3-Phenylenedimaleimide 25G 373元 2010/06/21 344760250 N,N'-间苯撑双马来酰亚胺 N,N'-m-Phenylenedimaleimide 97% 25 GR 305元
  • TCI Shanghai:N,N'-1,3-苯二马来酰亚胺 N,N'-1,3-Phenylenedimaleimide,>;95.0%(T)(3006-93-7)
  • 可燃性危险特性:可燃; 受热分解有毒氮氧化物烟雾
  • 类别:农药
  • 毒性分级:高毒
  • Acros Organics:间苯撑双马来酰亚胺 N,N'-m-Phenylenedimaleimide, 97%(3006-93-7)
  • MOL 文件:3006-93-7.mol
  • 灭火剂:干粉,泡沫,砂土,二氧化碳, 雾状水
  • Hazard Note:Irritant
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • MSDS 信息:N,N'-1,3-Phenylene bismaleimide(3006-93-7).msds
  • 急性毒性:口服-大鼠 LD50: 1370 毫克/公斤; 口服-小鼠 LD50: 250 毫克/公斤
  • 图谱信息:N,N'-间苯撑双马来酰亚胺(3006-93-7)红外图谱(IR1) N,N'-间苯撑双马来酰亚胺(3006-93-7)核磁图( 1 HNMR) N,N'-间苯撑双马来酰亚胺(3006-93-7)质谱(MS) N,N'-间苯撑双马来酰亚胺(3006-93-7)核磁图( 13 CNMR)
  • Sigma Aldrich:3006-93-7(sigmaaldrich)

系列性分类


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