Simazine 西玛津

CAS 122-34-9 MFCD00023174

化学结构图

122-34-9
SMILES: CCNc1nc(Cl)nc(NCC)n1

化学属性

Mol. FormulaC7H12ClN5
Mol. Weight202
Melting Point227-229°
TSCAYes
Density1.302
Solubility0.0005 G/100 ML
Flash Point100 °C

别名和识别编码

Chemical NameSimazine
MDL NumberMFCD00023174
PubChem Substance ID5216
Beilstein Registry Number0010895
CAS Number122-34-9
EC Number204-535-2
Synonym 2-CHLORO-4,6-BIS(ETHYLAMINO)-SYM-TRIAZINE A 2079 {Chemicalbook} 6-Chloro-N,N'-diethyl-1,3,5-triazine-2,4-diamine CALIBER W 6658 Radocon {Chemica Radokor Gesatop 50 Herbatoxol S G-27692(R) 2,4-Bis(aethylamino)-6-chlor-1,3,5-triazin GESAPUN 西玛津 溶液 {ALD} 阿米津(西玛津) LUSERB 西玛津标准品 G 27692 Azotop 2,4-B 2-氯-4,6-双(乙基氨基)-1,3,5-三嗪 Tri CAT 1-Chloro-3,5-bisethylamino-2,4,6-triazine; 2,4-Bis(ethylamino)-6-chloro-s-triazine 田保净 2,4-双(乙氨基)-6-氯-1,3,5-三嗪 2,4-BIS(ETHYLAMINO)-6-CHLORO-1,3,5-TRI Herbox 6-氯-N,N-二乙基-1,3,5-三嗪-2,4-二胺 Herbex 西玛嗪 Cekusan 2-CHLORO-4,6-BIS(ETHYLAMINO)-1,3,5-TRIAZINE {C 西玛津;2-氯-4,6-二乙氨基-1,3,5-三嗪 Simazine 80W CDT 1,3,5-Triazine-2,4-diamine, 6-chloro-N,N'-diethyl- 1-CHLORO-2,3-BIS(METHYLTHIO)BENZENE 2-氯-4,6-双(乙胺基)均三氮苯 西玛津可湿性粉剂(50%) CDT(R) 2-Chloro-4，6-di(eth {h {haz Batazine FLO 2,4-bis(ethylamino)-6-chloro-s-triazine Gesa Cekusima Geigy 27,692 Triazine A 38 2-氯-4,6-双(乙氨基)-1,3,5-三嗪 2-Chloro-4,6-bis(ethylamino)-s-triazine Aquazine GESATOP Herbazin Printop 2 4-BIS(ETHYLAMINO)-6-CHLORO-SYM-TRIAZINE Simanex Taphazine Tafazine {Chemicalboo 1-Chloro-3,5-bisethylamino-2,4,6-triazine C 2-Chloro-4,6-bis(ethylamino)-1,3,5-triazine
Merck Number14,8533
Chemical Name Translation西玛津
Wiswesser Line NotationT6N CN ENJ BM2 DM2 FG
InChIInChI=1S/C7H12ClN5/c1-3-9-6-11-5(8)12-7(13-6)10-4-2/h3-4H2,1-2H3,(H2,9,10,11,12,13)
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分类

  • {Chemicalbook} 农药: 除草剂: 有机杂环类除草剂
  • {SNA} 2000/60/EC, Algicides, Alphabetical Index of Analytical Standards, Analytical Standards, Chromatography, EPA, Endocrine Disruptors (Draft), Environmental Standards, European Community: ISO, DIN and DL 152, Method and Regulation Specific, Pesticides, Bactericides, Fungicides and Disinfectants, S, SA - SM, Standards for Personal Care and Cosmetic Products,
  • {S
  • {SNA} 2000/60/EC, Algicides, Alphabetical Index of Analytical Standards, Analytical Standards, Chromatography, EPA, Endocrine Disruptors (Draft), Environmental Standards, European Community: ISO, DIN and DL 152,
  • {SNA} Alphabetical Index of Analytical Standards,

产品应用

  • 该品为高效选择性除草剂，多用于防除玉米、高梁、甘蔗、茶园、果园等由种子繁殖的一年生和越年生阔叶杂草和多数单子叶杂草，还可用于铁路、公路、油田灭生性除草。

相关文献及参考

  • Merck: 14,8533

安全信息

WGK Germany1
GHS Symbol
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P310
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Hazard statements
  • H370 Causes damage to organs 导致器官损伤
  • H331 Toxic if inhaled 吸入中毒
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H301 Toxic if swallowed 吞食有毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H351 Suspected of causing cancer 怀疑致癌
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes Xn;N Xn;N,N,Xn,T,F F,T Xn,N
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
Signal word Danger Warning
RTECSXY5250000
Safety Statements
  • S46 If swallowed, seek medical advice immediately and show this container or label 食入时，立即求医并出示容器/标签；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S7 Keep container tightly closed 保存在严格密闭容器中；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
UN Number UN3077 2811 3077
Risk Statements
  • R11 Highly flammable 非常易燃
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R50/53
  • R36 Irritating to eyes 刺激眼睛
  • R22 Harmful if swallowed 吞咽有害
Packing GroupIII
Storage condition APPROX 4°C 储存温度2-8℃ 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 35 gm/kg/87W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   VOONAW Voprosy Onkologii.  Problems of Oncology.  For English translation,
   see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-10,
   1928-37; V.1-    1955-  Volume(issue)/page/year: 16(1),82,1970

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 16 gm/kg/61W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Gastrointestinal - tumors
   Tumorigenic - tumors at site of application
REFERENCE :
   VOONAW Voprosy Onkologii.  Problems of Oncology.  For English translation,
   see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-10,
   1928-37; V.1-    1955-  Volume(issue)/page/year: 16(1),82,1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NNGADV Nippon Noyaku Gakkaishi.  Journal of the Pesticide Science Society of
   Japan.  (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170,
   Japan)  V.1-    1976-  Volume(issue)/page/year: 15,315,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 971 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First

TYPE OF TEST            : LD50 - Let

TYPE OF TEST            : LC50 - Lethal concentrat

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#04003

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 1400 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 44(6),81,1979

{haz

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 1 mg/L
REFERENCE :
   BSIBAC Bolletino della Societe Italiana di Biologia Sperimentale.  (Casa
   Editrice Idelson, Via A. de Gasperi, 55, 80133 Naples, Italy)  V.2- 1927- 
   Volume(issue)/page/year: 60,2149,1984

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 400 mg/L
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB84-138973

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Parenteral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 396 umol/L
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)

TYPE OF TEST

TYPE OF TEST            : Dominant lethal test
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 6000 ppm
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue)/page/year: 3,691,1977

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Parenteral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 396 umol/L
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue)/page/year: 3,691,1977

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EX

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 3120 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured
   before birth)
REFERENCE :
   CHYCDW Zhonghua Yufangyixue Zazhi.  Chinese Journal of Preventive Medicine.
   (China International Book Trading Corp., POB 2820, Beijing, Peop. Rep.
   China)  Beginning history not known.  Volume(issue)/page/year: 15,83,1981

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 780 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   CHYCDW Zhonghua Yufangyixue Zazhi.  Chinese Journal of Preventive Medicine.
   (China International Book Trading Corp., POB 2820, Beijing, Peop. Rep.
   China)  Beginning history not known.  Volume(issue)/page/year: 15,83,1981

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 25 gm/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   CHYCDW Zhonghua Yufangyixue Zazhi.  Chinese Journal of Preventive Medicine.
   (China International Book Trading Corp., POB 2820, Beijing, Peop. Rep.
   China)  Beginning history not known.  Volume(issue)/page/year: 15,83,1981

TYPE OF TEST            : TDLo - Lowest publishe

其他信息

  • MOL 文件:122-34-9.mol
  • 方法一:以水为反应介质，在缚酸剂存在下于0℃左右将三
  • 毒性分级:中毒
  • 下游产品:2-甲硫基-4,6-二乙胺基-1,3,4-三嗪
  • 灭火剂:干粉、泡沫、砂土
  • 毒性:大鼠急性经口LD 50 >5000mg/kg；80%制剂对家兔急性经皮LD 50 >10000mg/kg。
  • Alfa Aesar:2-氯-4,6-二(乙基氨基)-1,3,5-三嗪,96% 2-Chloro-4,6-bis(ethylamino)-1,3,5-triazine, 96%(122-34-9)
  • 外观性质:无色结晶。
  • 用途三:均三嗪类除草剂。易被土壤吸附在表层，形成毒土层，浅根性杂草幼苗根系吸收到药剂即被杀死。对根系较深的多年生或深根杂草效果较差。用于玉米、甘蔗、高粱、茶树、橡胶及果园、苗圃除防由种子繁殖的一年生或越年生阔叶杂草和多数单子叶杂草；对由根茎或根芽繁殖的多年生杂草有明显的抑制作用；适当增大剂量也作森林防火道、铁路路基沿线、庭院、仓库存区、油罐区、贮木场等作灭生性除草剂。推荐用药量：玉米30～60g/100m 2 (夏玉米15～30g/100m 2 )；高粱30～66g/100m 2 ；甘蔗22.5～30g/100m 2 ；茶22.5～37.5g/100m 2 ；橡胶45～67.6g/100m 2 ；果园45～75g/100m 2 ；苗圃每平方米1～2g。对水配制成悬浮液喷洒土表。
  • 方法二:由三嗪氯氰与乙胺在酸接受体存在下反应而得。如果以水为反应介质，则在0℃左右加料，然后在70℃保温搅拌2h。如果反应在三氯乙烯等溶剂中进行，则反应温度为30-50℃。原料消耗定额：三聚氯氰（96%）1020kg/t、一乙胺（折100%）520kg/t、液碱
  • 用途四:该品为高效选
  • 中毒症状:对皮肤和呼吸道有中等刺激作用，不大量摄入不可能产生全身中毒。
  • 可燃性危险特性:燃烧产生有毒氮氧化物和氯化物气体; 中毒反应: 消瘦,红血球数降低
  • 储运特性:库房通风低温干燥
  • 类别:农药
  • 西玛津价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 L03947 2-氯-4,6-二(乙基氨基)-1,3,5-三嗪, 96% 2-Chloro-4,6-bis(ethylamino)-1,3,5-triazine, 96% 25g 486元 2010/05/25 L03947 2-氯-4,6-二(乙基氨基)-1,3,5-三嗪, 96% 2-Chloro-4,6-bis(ethylamino)-1,3,5-triazine, 96% 100g 1470元
  • MSDS 信息:西玛津(122-34-9).msds
  • 注意事项:[1]西玛津的残效期长，对某些敏感后茬作物生长有不良影响，如对小麦、大麦、燕麦、棉花、大豆、水稻、瓜类、油菜、花生、向日葵、十字花科蔬菜 等有药害。施用西玛津的地块，不宜套种豆类、瓜类等敏感作物，以免发生 药害。 [2]西玛津用药量应根据土壤的有机质含量、土壤质地，气温而定，一 般气温高有机质含量低的沙质土用量低，反之用量高，在有机质含量很高的 地块，因用量成本大，最好不要用西玛津。 [3]西玛津不可用于落叶松的新播 及换床苗圃
  • 用途二:在玉米田或果园芽前使用，用于防除阔叶和窄叶杂草
  • 不溶于水，甲醇中的溶解度为400ppm，化学性质稳定，无腐蚀性。
  • 用途一:属选择性内吸传导型土壤处理除草剂，用于防除一年生阔叶杂草及禾本科杂草
  • 图谱信息:西玛津(122-34-9)红外图
  • 急性毒性:口服- 大鼠 LD50: 971 毫克/公斤; 口服- 小鼠 LD50: 5000 毫克/ 公斤
  • 上游原料:三聚氯氰 --> 三氯乙烯 --> 三嗪
  • 职业标准:TWA 5毫克/立方米
  • 刺激数据:皮肤- 兔子 500 毫克 轻度

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Method Specific - Analytical Standards
  4. European Community: ISO, DIN and DL 152 - Method Specific
  5. 2000/60/EC - European Community: ISO, DIN and DL 152
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Method Specific - Analytical Standards
  4. EPA - Method Specific
  5. Endocrine Disruptors (Draft) - EPA
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Alpha sort - Pesticides & Metabolites
  7. Q-Z - Alpha sort
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. S - Alphabetic
  5. SA - SM - S

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