6-Bromoquinoline 6-溴喹啉

CAS 5332-25-2 MFCD00024023

化学结构图

5332-25-2
SMILES: Brc1ccc2ncccc2c1

化学属性

Mol. FormulaC9H6BrN
Mol. Weight208.06
Density1.538
Refractive index1.6600 to 1.6650
Flash Point>110°C
TSCAYes
Melting Point19°C
Stability对光敏感
Boiling Point278°C at 760 mmHg
pH:A

别名和识别编码

Chemical Name6-Bromoquinoline
CAS Number5332-25-2
Alfabeta NameBROMOQUINOLINE 6-
MDL NumberMFCD00024023
Synonym 6-Bromoquinoline {LY} 6-Bromoquinoline {} {LY} 6-Bromoquinoline {} {} {LY} 6-Bromoquinoline {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number226-238-7
Reaxys-RN112964
Beilstein Registry Number20(5)7,319
PubChem Substance ID79243
Chemical Name Translation6-溴喹啉
InChIKeyIFIHYLCUKYCKRH-UHFFFAOYSA-N
LabNetwork Molecule IDLN00120989
InChIInChI=1S/C9H6BrN/c10-8-3-4-9-7(6-8)2-1-5-11-9/h1-6H
Canonical SMILESC1=CC=C2C(=N1)C=CC(=C2)Br
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分类

  • Building Blocks, C8 to C10, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Quinolines
  • {SNA} Building Blocks, C8 to C10, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Quinolines

相关文献及参考

  • Beilstein:20(5)7,319

安全信息

Warnings IRRITANT
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Storage condition 2-8°C {LY} 2-8°C 2-8℃避光储存 Refrigerator Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
Hazard Codes Xi,Xn Xn Xi

其他信息

  • 用途和制备方法:3-溴喹啉与混酸作用生成3-溴-5-硝基喹啉,与高锰酸钾加热被氧化为5-溴-2,3-吡啶二甲酸。 6-溴喹啉与硝酸加热生成6-溴-8-硝基喹啉,与高锰酸钾作用被氧化为2,3- 吡啶二甲酸。 由2-羟基喹啉与五溴化磷作用制得2-溴喹啉。 由喹啉过溴化物于180℃加热制得3-溴喹啉。 由4-羟基喹啉与五溴化磷加热,或由4-氨基喹啉经重氮化反应制得4-溴喹啉。 5-溴喹啉由间溴苯胺、甘油、间溴硝基苯及浓硫酸加热,或由5-氨基喹啉经重氮化反应制取。 由对溴苯胺与甘油、浓硫酸、对溴硝基苯加热制得6-溴喹啉。 由7-氨基喹啉经重氮化反应制得7-溴喹啉。 8-溴喹啉由邻溴苯胺、甘油、浓硫酸及邻溴硝基苯加热制得。 用途:作有机合成试剂。
  • 6-溴喹啉价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B2015 6-溴喹啉 6-Bromoquinoline 5G 1280元 2014/06/02 B2015 6-溴喹啉 6-Bromoquinoline 1G 429元 2010/06/21 CC04510CB 6-溴喹啉 6-bromoquinoline 250 MG 900元
  • Acros Organics:6-溴喹啉 6-bromoquinoline(5332-25-2)
  • 图谱信息:6-溴喹啉(5332-25-2)质谱(MS) 6-溴喹啉(5332-25-2)红外图谱(IR1) 6-溴喹啉(5332-25-2)核磁图( 13 CNMR) 6-溴喹啉(5332-25-2)核磁图( 1 HNMR)
  • TCI Shanghai:6-溴喹啉 6-Bromoquinoline,>;95.0%(GC)(5332-25-2)
  • 检测方法:HPLC
  • 存储注意事项:氮气保护
  • MOL 文件:5332-25-2.mol
  • Hazard Note:Irritant
  • Sigma Aldrich:5332-25-2(sigmaaldrich)
  • 上游原料:氢氧化钠 --> 硫酸 --> 四氢呋喃 --> 甲苯 --> 正丁醇 --> 氯化锌 --> 甘油 --> 丙烯醛 --> 4-溴苯胺 --> 四氯苯醌 --> 1-溴-4-硝基苯
  • 溴喹啉:有七种位置异构体,其主要物性列表如下: 名称 熔点(℃) 沸点(℃) 溶解性 2-溴喹啉 48~49 溶于乙醚、氯仿、苯 3-溴喹啉 12~15 274~276、 95(66.66Pa) 4-溴喹啉 29~30 270(分解) 易溶于稀酸 5-溴喹啉 52(针状晶体) 280   6-溴喹啉 24 278 7-溴喹啉 52(针状晶体) 290 8-溴喹啉 80 165~166 (2399.79Pa)

系列性分类


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