1-Phenyl-2-(phenylsulfonyl)ethanone 1-苯基-2-(苯基磺酰基)乙酮

CAS 3406-03-9 MFCD00025043

化学结构图

3406-03-9
SMILES: O=C(CS(=O)(=O)c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC14H12O3S
Mol. Weight260.31
Melting Point93-95
Density1.422
TSCANo

别名和识别编码

Chemical Name1-Phenyl-2-(phenylsulfonyl)ethanone
CAS Number3406-03-9
Alfabeta NamePHENYLSULFONYLACETOPHENONE 2()-
MDL NumberMFCD00025043
Synonym 1-Phenyl-2-(phenylsulfonyl)ethan-1-one {LY} 1-Phenyl-2-(phenylsulfonyl)ethan-1-one {} {LY} 1-Phenyl-2-(phenylsulfonyl)ethan-1-one {} {} {LY} 1-Phenyl-2-(phenylsulfonyl)ethan-1-one {} {} {} {LY} 1-Phenyl-2-(phenylsulfonyl)ethan-1-one {} {} {} {} {LY} 1-Phenyl-2-(phenylsulfonyl)ethan-1-one {} {} {} {} {} {LY} 1-Phenyl-2-(phenylsulfonyl)ethan-1-one {} {} {} {} {} {} {LY} 1-Phenyl-2-(phenylsulfonyl)ethan-1-one {} {} {} {} {} {} {} {LY} 1-Phenyl-2-(phenylsulfonyl)ethan-1-one {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} 1-Phenyl-2-(phenylsulfonyl)ethan-1-one {} {} {} {} {} {} {} {} {} {LY} 1-Phenyl-2-(phenylsulfonyl)ethan-1-one {} {} {} {} {} {} {} {} {} {} {LY} 1-Phenyl-2-(phenylsulfonyl)ethan-1-one {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Phenyl-2-(phenylsulfonyl)ethan-1-one {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Phenyl-2-(phenylsulfonyl)ethan-1-one {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Phenyl-2-(phenylsulfonyl
EC Number222-292-0
Beilstein Registry Number1879574
PubChem Substance ID87574958
Chemical Name Translation1-苯基-2-(苯基磺酰基)乙酮
Reaxys-RN1879574
InChIKeyDREVPGKOIZVPQV-UHFFFAOYSA-N
LabNetwork Molecule IDLN00904488
InChIInChI=1S/C14H12O3S/c15-14(12-7-3-1-4-8-12)11-18(16,17)13-9-5-2-6-10-13/h1-10H,11H2
Canonical SMILESO=C(C=1C=CC=CC1)CS(=O)(=O)C=2C=CC=CC2
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; ketone; sulfone; 1fragment

相关文献及参考

  • Short: EINECS
  • Short: III/35E
  • ß-Keto sulfones can be metallated, e.g. with NaH or LDA. K2CO3 in DMF is also effective, e.g. in dialkylation with 1,2-dibromoethane to give a cyclopropane derivative: Synth. Commun., 18, 1433 (1988). The product can be cleaved to the sulfur-free cyclopropyl ketone with Raney nickel.

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • Acros Organics:2-(Phenylsulfonyl)acetophenone, 99%(3406-03-9)
  • TCI Shanghai:2-苯磺酰基苯乙酮 2-Phenylsulfonylacetophenone,>;98.0%(T)(3406-03-9)
  • Alfa Aesar:2-(苯基磺酰)苯乙酮,99% 2-(Phenylsulfonyl)acetophenone, 99%(3406-03-9)
  • MOL 文件:3406-03-9.mol
  • 2-(苯基磺酰)苯乙酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0828 2-苯磺酰基苯乙酮 2-Phenylsulfonylacetophenone 25G 1120元 2014/06/02 P0828 2-苯磺酰基苯乙酮 2-Phenylsulfonylacetophenone 10G 565元 2010/06/21 308610250 2-(苯基磺酰)苯乙酮 2-(Phenylsulfonyl)acetophenone 99% 25 GR 1027元
  • 图谱信息:2-(苯基磺酰)苯乙酮(3406-03-9)核磁图( 13 CNMR) 2-(苯基磺酰)苯乙酮(3406-03-9)红外图谱(IR2) 2-(苯基磺酰)苯乙酮(3406-03-9)红外图谱(IR1) 2-(苯基磺酰)苯乙酮(3406-03-9)质谱(MS) 2-(苯基磺酰)苯乙酮(3406-03-9)核磁图( 1 HNMR)
  • Sigma Aldrich:3406-03-9(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfones - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic Ketones

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