Tetrakis(Hydroxymethyl)Phosphonium Chloride 四羟甲基氯化鏻

CAS 124-64-1 MFCD00031687

化学结构图

124-64-1
SMILES: OC[P+](CO)(CO)CO.[Cl-]

化学属性

Mol. FormulaC4H12ClO4P
Mol. Weight190.56
Density1.341
Refractive indexn20/D 1.512
Melting Point154 °C
Solubility>=10 G/100 ML AT 20 ºC
Boiling Point115 °C at 760 mmHg

别名和识别编码

Chemical NameTetrakis(Hydroxymethyl)Phosphonium Chloride
MDL NumberMFCD00031687
CAS Number124-64-1
PubChem Substance ID87576501
Beilstein Registry Number3631669
EC Number204-707-7
Synonym Tetrakis(hydroxymethyl)phosphanium chloride {LY} Tetrakis(hydroxymethyl)phosphanium chloride {} {LY} Tetrakis(hydroxymethyl)phosphanium chloride {} {} {LY} Tetrakis(hydroxymethyl)phosphanium chloride {} {} {} {LY} Tetrakis(hydroxymethyl)phosphanium chloride {} {} {} {} {LY} Tetrakis(hydroxymethyl)phosphanium chloride {} {} {} {} {} {LY} Tetrakis(hydroxymethyl)phosphanium chloride {} {} {} {} {} {} {LY} Tetrakis(hydroxymethyl)phosphanium chloride {} {} {} {} {} {} {} {LY} Tetrakis(hydroxymethyl)phosphanium chloride {} {} {} {} {} {} {} {} {LY} Tetrakis(hydroxymethyl)phosphanium chloride {} {} {} {} {} {} {} {} {} {LY} Tetrakis(hydroxymethyl)phosphanium chloride {} {} {} {} {} {} {} {} {} {} {LY} Tetrakis(hydroxymethyl)phosphanium chloride {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrakis(hydroxymethyl)phosphanium chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrakis(hydroxymethyl)phosphanium chloride {} {} {} {} {} {} {} {} {}
Chemical Name Translation四羟甲基氯化鏻
Reaxys-RN3631669
Wiswesser Line NotationQ1P1Q1Q1Q &G
LabNetwork Molecule IDLN02219991
InChIInChI=1S/C4H12O4P.ClH/c5-1-9(2-6,3-7)4-8;/h5-8H,1-4H2;1H/q+1;/p-1
Canonical SMILESC(O)[P+](CO)(CO)CO.[Cl-]
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分类

  • {SNA} Chemical Synthesis, Phase Transfer Catalysts, Phosphonium Salts, Synthetic Reagents

安全信息

WGK Germany3
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下,戴呼吸防护。
  • P301+P310
  • P301+P310+P330
  • P301+P312
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P352
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P304+P341
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗(见本标签上的)。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P342+P311
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H302 Harmful if swallowed 吞食有害
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H312 Harmful in contact with skin 皮肤接触有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H330 Fatal if inhaled 吸入致命
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
RTECSTA2450000
GHS Symbol
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word Danger
Hazard Codes 6.1 T,N
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R25 Toxic if swallowed 吞咽有毒
  • R38 Irritating to skin 刺激皮肤
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R42/43
  • R51/53
UN Number 2810 2922
Packing GroupIII
Hazard Class8/6.1
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 3800 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   KOBUA3 Kobunshi.  High Polymers.  (Kobunshi Gakkai, 5-12-8, Ginza, Chuo-Ku,
   Tokyo 104, Japan) V.1-    1952-  Volume(issue)/page/year: 24,788,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 400 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   KOBUA3 Kobunshi.  High Polymers.  (Kobunshi Gakkai, 5-12-8, Ginza, Chuo-Ku,
   Tokyo 104, Japan) V.1-    1952-  Volume(issue)/page/year: 24,788,1975

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 125 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 7,789,1955

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 161 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-296,1987

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 5000 ppm
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue)/page/year: 6,259,1980

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 15 mg/L
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-296,1987

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 87 mg/L
REFERENCE :
   GMCRDC Gann Monograph on Cancer Research.  (Plenum Pub. Corp., 233 Spring
   St., New York, NY 10013) No. 11-    1971-  Volume(issue)/page/year:
   27,95,1981

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 6 mg/L
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-296,1987

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - mouse Embryo
DOSE/DURATION           : 5000 ppm
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue)/page/year: 6,259,1980

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - hamster Kidney
DOSE/DURATION           : 5000 ppm
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   V

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其他信息

  • MSDS 信息:Tetrakis(hydroxymethyl)phosphonium chloride(124-64-1).msds
  • TCI Shanghai:四羟甲基氯化磷(约80%的水溶液) Tetrakis(hydroxymethyl)phosphonium Chloride (ca. 80% in Water)(124-64-1)
  • 四羟甲基氯化磷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K8762001 四羟甲基氯化磷 100ml 663元 2011/04/16 T0607 四(羟甲基)氯化磷(约80%的水溶液) Tetrakis(hydroxymethyl)phosphonium Chloride (ca. 80% in Water) 500ML 1740元 2011/04/16 T0607 四(羟甲基)氯化磷(约80%的水溶液) Tetrakis(hydroxymethyl)phosphonium Chloride (ca. 80% in Water) 25ML 206元
  • 图谱信息:四羟甲基氯化磷(124-64-1)质谱(MS) 四羟甲基氯化磷(124-64-1)红外图谱(IR1)
  • 用途一:用于纺织品后处理,用作塑料、纸品阻燃剂,还用于有机合成
  • MOL 文件:124-64-1.mol
  • Sigma Aldrich:124-64-1(sigmaaldrich)
  • Acros Organics:四羟甲基氯化磷 Tetrakis(hydroxymethyl)phosphoniumchloride,ca.80%solutioninwater(124-64-1)

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