Diphenyliodonium Nitrate 二苯基碘硝酸盐

CAS 722-56-5 MFCD00031704

化学结构图

722-56-5
SMILES: O=[N+]([O-])[O-].c1ccc([I+]c2ccccc2)cc1

化学属性

Mol. FormulaC12H10INO3
Mol. Weight343.12
Melting Point150-154 °C
TSCANo
Solubility溶于热水
Density1.422
Stability对光敏感glass bottle

别名和识别编码

Chemical NameDiphenyliodonium Nitrate
Synonym diphenyliodonium nitrate {LY} diphenyliodonium nitrate {} {LY} diphenyliodonium nitrate {} {} {LY} diphenyliodonium nitrate {} {} {} {LY} diphenyliodonium nitrate {} {} {} {} {LY} diphenyliodonium nitrate {} {} {} {} {} {LY} diphenyliodonium nitrate {} {} {} {} {} {} {LY} diphenyliodonium nitrate {} {} {} {} {} {} {} {LY} diphenyliodonium nitrate {} {} {} {} {} {} {} {} {LY} diphenyliodonium nitrate {} {} {} {} {} {} {} {} {} {LY} diphenyliodonium nitrate {} {} {} {} {} {} {} {} {} {} {LY} diphenyliodonium nitrate {} {} {} {} {} {} {} {} {} {} {} {LY} diphenyliodonium nitrate {} {} {} {} {} {} {} {} {} {} {} {} {LY} diphenyliodonium nitrate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} diphenyliodonium nitrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} diphenyliodonium nitrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} diphenyliodonium nitrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} diphenyliodo
CAS Number722-56-5
PubChem Substance ID87568793
Beilstein Registry Number3922747
MDL NumberMFCD00031704
EC Number211-962-8
Reaxys-RN3922747
Chemical Name Translation二苯基碘硝酸盐
InChIKeyCQZCVYWWRJDZBO-UHFFFAOYSA-N
LabNetwork Molecule IDLN01346845
InChIInChI=1S/C12H10I.NO3/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;2-1(3)4/h1-10H;/q+1;-1
Canonical SMILES[O-][N+]([O-])=O.C1([I+]C2=CC=CC=C2)=CC=CC=C1
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分类

  • {SNA} Cationic Photoinitiators, Micro/NanoElectronics, Organic Photoinitiators, Photoacid Generators (PAGs), Photoresists, Polymer Science, Polymerization Initiators, Reagents for Polymerization, Self Assembly and Lithography, 材料科学
  • {SNA} Chemical Synthesis, Hypervalent Iodine, Oxidizing Agents, Synthetic Reagents
  • {SNA} Cationic Photoinitiators, Micro/NanoElectronics, Organic Photoinitiators, Photoacid Generators (PAGs), Photoresists, Polymer Science, Polymerization Initiators, Reagents for Polymerization, Self Assembly & Contact Printing, 材料科学
  • {SNA} Cationic Photoinitiators, Materials Science,

产品应用

  • 阳离子光引发剂。光酸产生剂。

相关文献及参考

  • FT-IR 2 (2), 1682:A / IR-Spectra (2), 524:G / IR-Spectra (3), 588:G / NMR-Reference 2 (1), 774:A

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H272 May intensify fire; oxidizer 可能加剧火势；氧化剂。
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes 5.1 O
RTECSNN6665000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P221 Take any precaution to avoid mixing with combustibles/… 采取一切防范措施，避免与可燃物混合/...
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 1479
Safety Statements
  • S17 Keep away from combustible material 远离可燃物料；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
Storage condition Light Sensitive 储存温度2-8℃
Packing GroupII
Hazard Class5.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#01941

其他信息

  • Alfa Aesar:二苯基碘硝酸盐,97% Diphenyliodonium nitrate, 97%(722-56-5)
  • TCI Shanghai:二苯基碘硝酸盐 Diphenyliodonium Nitrate,>;98.0%(T)(722-56-5)
  • Acros Organics:Diphenyliodonium nitrate, 97%(722-56-5)
  • Sigma Aldrich:722-56-5(sigmaaldrich)
  • F:8-10
  • MOL 文件:722-56-5.mol
  • 二苯基碘硝酸盐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D2357 二苯基碘硝酸盐 Diphenyliodonium Nitrate 5G 540元 2014/06/02 D2357 二苯基碘硝酸盐 Diphenyliodonium Nitrate 25G 1440元 2010/06/21 292340250 二苯基碘硝酸盐 Diphenyliodonium nitrate 97% 25 GR 12304元
  • 图谱信息:二苯基碘硝酸盐(722-56-5)核磁图( 13 CNMR) 二苯基碘硝酸盐(722-56-5)红外图谱(IR2) 二苯基碘硝酸盐(722-56-5)核磁图( 1 HNMR) 二苯基碘硝酸盐(722-56-5)红外图谱(IR1) 二苯基碘硝酸盐(722-56-5)质谱(MS)
  • 敏感性:Light Sensitive

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  4. Chromates - Oxidation
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  4. Hypervalent Iodine - Oxidation
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Polymerization Initiators - Polymer Science
  4. Organic Photoinitiators - Polymerization Initiators
  5. Cationic Photoinitiators - Organic Photoinitiators
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Hypervalent Iodine Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Iodonium, Sulfonium & Oxonium Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Polymerization Initiators
  4. Organic Photoinitiators
  5. Benzophenone