Parathion 对硫磷

CAS 56-38-2 MFCD00036219

化学结构图

56-38-2
SMILES:

化学属性

Mol. FormulaC10H14NO5PS
Mol. Weight291.28
Melting Point6°C
Boiling Point375°C
Density1.26
Solubility不溶于水，溶于多数有机溶剂。
Refractive index1.5370
Stability对光敏感
Flash Point120 °C

别名和识别编码

Chemical NameParathion
Synonym Pacol {uni_hamburg} {Chemicalbook} ENT 15108 Paraphos { 对硫磷(乙基对硫磷) BAY 1605 phosphorothioic acid, O,O-diethyl O-(p-nitrophenyl) ester O,O-Diethyl-O-p- diethyl 4- 一六零五微胶囊剂(25%) Gearphos O,O-Diethyl O-(4-nitrophenyl)thio-phosphate Lethalaire G-54 {Chemica Niran O,O-diethyl O-(4-nitrophenyl) phosphorothioate Oleofos 20 Diethyl parathion RCRA waste number P089 Oleoparathene Folidol E Diethyl p-nitrophenyl thionophosphate O,O-二乙基-O-(4-硝基苯基) Parathion-Ethyl Phosphorothioic acid, O,O-diethyl O-(4-nitrophenyl) ester NIRAN(R) Rhodiatox ORTHOPHOS(R) Fosfex Ekatox Alleron O,O-diethyl O-(4-nitrophenyl)phosphorothioate Folidol Etylpar {uni_ham thiophosphoric acid O,O'-diethyl ester O''-(4-nitro-phenyl) es Fosfer BAY E-605 DNTP 乙基一六○五 AAT Aralo {u RB Alkron ETHYL PARATHION Diethylparathion Diethyl para-nitrophenol thiophosphate Ecatox 20 一六O五,乙基1605,乙基对硫磷,对硫磷,O,O-二乙基-O-(4-硝基苯基)硫代磷酸酯,O,O-二乙基-O-(对硝基苯基)硫代磷酸酯 Bladan F Phosphorothioic acid, O,O-diethyl O-(p-nitrophenyl) ester O,O- Paramar 50 {uni_ Folidol E-605 Pestox plus O,O-Diethyl-O-(4-nitrophenyl) phosphorothioate {h 硝苯硫磷酯 O,O-Diethyl O-p-nitrophenyl thiophosphate Th
CAS Number56-38-2
PubChem Substance ID24869108
EC Number200-271-7
MDL NumberMFCD00036219
Beilstein Registry Number2059093
Chemical Name Translation对硫磷
Merck Number13,7105
Wiswesser Line NotationWNR DOPS&O2&O2
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分类

  • 2000/60/EC, Acaricides, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, European Community: ISO, DIN and DL 152, Insecticides, Method Specific, N-P, Oeko-Tex Standard 100, Organophorous, P, PA - PEN, Pesticides, Pesticides & Metabolites
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} 2000/60/EC, Acaricides, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography,

产品应用

  • 校准仪器和装置；评价方法；工作标准；质量保证/质量控制；其他。

相关文献及参考

  • Short: IV/20A
  • Short: IV/18A
  • Short: IV/20B
  • Merck:13,7105
  • Short: III/38A

安全信息

GHS Symbol
WGK Germany2
Hazard Codes F,Xn,N T+;N,N,T+,Xn,F T+;N
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSTF4550000
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+P310
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P331 Do NOT induce vomiting.. 不要催吐。
Signal word Danger
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R24 Toxic in contact with skin 与皮肤接触有毒
  • R48/25
  • R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒
  • R50/53
  • R11 Highly flammable 非常易燃
  • R38 Irritating to skin 刺激皮肤
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
UN Number 3278 UN 3278
Storage condition APPROX 4°C 低温(<5˚C)、干燥处储存。 避光、低温(<5˚C)、干燥处储存。
Packing GroupI
Hazard Class6.1(a)
Restrict 剧毒 {} 剧毒化学品
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1260 mg/kg/80W-C
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Endocrine - adrenal cortex tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-70,1979

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Mammal - cat
DOSE/DURATION           : 3 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Behavioral - ataxia
   Lungs, Thorax, or Respiration - respiratory stimulation
REFERENCE :
   JAMAAP JAMA, Journal of the American Medical Association.  (AMA, 535 N.
   Dearborn St., Chicago, IL 60610)  V.1-    1883-  Volume(issue)/page/year:
   144,104,1950

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - quail
DOSE/DURATION           : 4040 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PCBPBS Pesticide Biochemistry and Physiology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802)  V.1-    1971-  Volume(issue)/page/year:
   7,28,1977

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2 mg/kg
TOXIC EFFECTS :
   Biochemical - Enzyme inhibition, induction, or change in blood or tissue
   levels - true cholinesterase
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   11,546,1967

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 1330 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ASTTA8 ASTM Special Technical Publication.  (American Soc. for Testing
   Materials, 1916 Race St., Philadelphia, PA 19103)  No.1-    1911-
   Volume(issue)/page/year: (680),157,1979

TYPE OF TEST            :

TYPE OF TEST            : DNA damage
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 20 mg/kg/28D (Intermittent)
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 53,175,1978

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Human Fibroblast
DOSE/DURATION           : 10 umol/L
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S.

TYPE OF TEST            : DNA damage
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 3 ug/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 53,175,1978

TYPE OF TEST            : DNA damage
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 10 mg/kg/28D (Intermittent)
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 53,175,1978

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 5(Suppl
   1),3,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 500 ug/plate
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue)/page/year: 16,403,1985

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 22 mg/kg
SEX/DURATION            : female 1-22 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - biochemical and metabolic
REFERENCE :
   JJATDK JAT, Journal of Applied Toxicology.  (John Wiley & Sons Ltd., Baffins
   Lane, Chichester, W. Sussex PO19 1UD, UK)  V.1-    1981-
   Volume(issue)/page/year: 9,401,1989

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 360 ug/kg
SEX/DURATION            : female 2-22 day(s) after conception
                          lactating female 15 day(s) post-birth
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - biochemical and metabolic
   Reproductive - Effects on Newborn - other postnatal measures or effects
REFERENCE :
   TOLED5 Toxicology Letters.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1977-  Volume(issue)/page/year: 3,11,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 3 mg/kg
SEX/DURATION            : female 11 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   AEHLAU Archives of Environmental Health.  (Heldref Pub., 4000 Albemarle St.,
   NW, Washington, DC 20016)  V.1-    1960-  Volume(issue)/page/year:
   16,805,1968

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 3 mg/kg
SEX/DURATION            : female 11 day(s) after conception
TOXIC EFFECTS :
   Reproduct

其他信息

  • 蒸气压（20℃）为5×10-6kPa。水中溶解度为24mg/L（25℃）。微溶于石油醚及煤油，可与多数有机溶剂混溶。有蒜臭。在碱性介质中迅速地水解；在中性或微性溶液中较为稳定；对紫外光与空气都不稳定。
  • Sigma Aldrich:56-38-2(sigmaaldrich)
  • 可燃性危险特性:明火可燃; 受热放出有毒氧化磷、氧化氮、氧化硫气体
  • 方法一:由二乙基硫代磷酰氯在三甲胺催化下与对硝基酚钠合成则得。原料消耗定额：五硫化二磷370kg/t、无水乙醇330kg/t、对硝基酚钠330kg/t。
  • 注意事项:该药毒性大，规定在蔬菜、瓜果、茶叶、中草药上禁用
  • 类别:农药
  • 毒性分级:剧毒
  • MOL 文件:56-38-2.mol
  • 急救治疗:[1]用阿托品1～5mg皮下或静脉注射(按中毒轻重而定) [2]用解磷定0.4－1.2g 静脉注射(按中毒轻重而定) [3]禁用吗啡、茶硷、吩噻嗪、利血平。 [4]误服立即引吐、洗胃、导泻(清醒时才能引吐)。
  • 用途一:用于防治各种蚜虫、红蜘蛛等害虫
  • 用途三:对硫磷为广谱性杀虫剂，具有触杀、胃毒、熏蒸作用，无内吸传导作用，但能渗透入植物体内。对昆虫作用很快，高温时杀虫作用显著增快，可用于防治棉花、苹果、柑桔、梨、桃等果树害虫及麦红蜘蛛等。
  • MSDS 信息:对硫磷(56-38-2).msds
  • 灭火剂:砂土、干粉、泡沫
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 急性毒性:口服-大鼠 LD50: 2 毫克/公斤; 口服-小鼠 LD50: 5 毫克/公斤
  • 用途二:用于防治水稻、棉花、玉米等作物的害虫，也可用于防治果树、林木上多种咀嚼和刺吸口器害虫
  • 用途:对硫磷可应用于多种作物防治多种害虫和植食性螨类，同时也对天敌昆虫和捕食性螨类以及蜜蜂等益虫有很强毒性。主要采用乳油对水喷雾，在棉花、水稻、果树、大豆等作物上防治同翅目、鳞翅目、半翅目、鞘翅目、双翅目等咀嚼式口器和刺吸式口器害虫及叶螨。持效期约一星期。对某些虫卵、螨卵也有杀伤作用。对小麦等进行种子处理。可防治蝼蛄等土壤害虫。制成颗粒剂撒入玉米心叶期喇叭口，可防治玉米螟。一般使用下无药害，但瓜类，尤其是瓜苗敏感。在一定气候条件下，对某些观赏植物、梨和某些品种的苹果有药害种子处理时，某些高梁品种较敏感。对硫磷毒性高，在贮运和使用时严格注意安全防护。高秆作物地内禁止喷雾。蔬菜、茶树上禁用。禾谷类作物和果树上施药的收获前禁用期至少为30天。近似品种有甲基对硫磷、杀螟硫磷等8种。
  • 中毒症状:急性中毒多在12小时内发病，口服立即发病。 轻度：头痛、头昏、恶心、呕 吐、多汗、无力、胸闷、视力模糊、胃口不佳等，全血胆碱酯酶活力一般降 至正常值的70~50%。 中度：除上述症状外还出现轻度呼吸困难、肌肉震颤、瞳孔缩小、精神恍惚、行走不稳、大汗、流涎、腹疼、腹泻。重者还会出现昏迷、抽搐、呼吸困难、口吐白沫、大小便失禁，惊厥，呼吸麻痹。
  • 上游原料:乙醇 --> 氯 --> 二甲苯 --> 五硫化二磷 --> 乳化剂 --> 三甲胺 --> 二乙基硫代磷酰氯 --> 4-硝基苯酚钠
  • 外观性质:纯品为无色无臭的液体，工业品为棕色并有蒜臭的液体。
  • 产品特性:高毒广谱性硫逐式一硫代磷酸酯类杀虫杀螨剂，中国也称作一六O五。对高等动物毒性很高，药剂如通过眼睛、呼吸道、皮肤进入高等动物体内也很危险。气温升高时熏 蒸作用更为明显。无内吸性，有一定内渗作用，叶面施药能局部渗入叶内组织，而杀死相应叶背面的害虫。
  • 职业标准:TWA 0.1 毫克/立方米; STEL 0.3 毫克/立方米

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. P - Alphabetic
  5. PA - PEN - P
  1. Functional Group 官能团索引
  2. thiophosphoric acid ester

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