THORIUM OXIDE Thorium(IV)

CAS 1314-20-1 MFCD00036277

化学结构图

1314-20-1
SMILES: O=[Th]=O

化学属性

Mol. FormulaO2Th
Mol. Weight264.00
Melting Point3050°C
Boiling Point4400°C
Density9,86 g/cm3
Solubility不溶于水、碱,溶于酸。

别名和识别编码

Chemical Nameoxide (99.99%-Th) PURATREM
Synonym 方钍石,放射性氧化钍 氧化釷 钍氧 99.-th)spectro Thorotrast Thorium oxide (ThO2) 硝酸钍水合物 ThO2 THORIUM (IV) OXIDE Thorium(Ⅳ)oxide Thorium(IV)bisoxide thoriumoxide(tho2) Thorium anhydride thoriumanhydride Thorium(IV) oxide 二氧化钍 Thortrast Umbrathor ThO2 THORIUM OXIDE Thorium(IV) Thorium(IV)oxide(99.99%-Th)PURATREM thorium (IV) oxide 氧化钍,钍土 thorianite THORIUM (IV) OXIDE (99.-TH) PURATREM Thorium(IV)dioxide Thorium Oxide 氧化钍 Thorium dioxide Thoria
MDL NumberMFCD00036277
PubChem Substance ID24889185
EC Number215-225-1
CAS Number1314-20-1
Chemical Name TranslationThorium(IV)
Merck Number13,9455
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分类

  • {Chemicalbook} 无机化工产品: 无机盐: 其他无机化合物
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Thorium

相关文献及参考

  • Short: III/12c Title: Magnetic and Other Properties of Oxides and Related Compounds: Hexagonal Ferrites. Special Lanthanide and Actinide Compounds Author: Arons, R.R.; Bonnenberg, D.; Grünberg, P.; Hempel, K.A.; Köbler, U.; Lütgemeier, H.; Maletta, H.J.; Roos, W.; Sauer, Ch.; Zinn, W. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/12c Year: 1982 ISBN: 3-540-10137-3 ISBN: 978-3-540-10137-6 Internet Resource: DOI:10.1007/b19987 RefComment: 1034 figs., XI, 604 pages. Hardcover
  • Short: III/23b Title: Electronic Structure of Solids: Photoemission Spectra and Related Data Author: Goldmann, A.; Ishii, T.; Manzke, R.; Naegele, J.R.; Skibowski, M. Editor: Goldmann, A. Source: Landolt-Börnstein, New Series Volume: III/23b Year: 1994 ISBN: 3-540-53705-8 ISBN: 978-3-540-53705-2 Internet Resource: DOI:10.1007/b91258 RefComment: 647 figs., VIII, 327 pages. Hardcover Abstract: Photoelectron spectroscopy has matured considerably during the last decade. The experimental techniques were improved markedly. Photon line sources and,in particular, synchrotron radiation sources are now routinely available in many places. The volume summarizes data on the bulk electronic structure of solids. Besides the photoelectron results, a limited set of other data (such as lattice constants and work functions) useful in the context of band structure information is presented.
  • Short: III/24C Title: Physics of Solid Surfaces: Interaction of Charged Particles and Atoms with Surfaces Author: Alkemade, P.; Celli, V.; Chiarotti, G.; Rocca, M.; Zanazzi, E. Editor: Chiarotti, G. Source: Landolt-Börnstein, New Series Volume: III/24C Year: 1995 ISBN: 3-540-56071-8 ISBN: 978-3-540-56071-5 Internet Resource: DOI:10.1007/b87125 RefComment: 207 figs., XII, 328 pages. Hardcover Abstract: In the last two decades surface physics has experienced an explosive expansion caused by the development and/or substantial improvement of surfa

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P301+P310
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
Hazard statements
  • H350 May cause cancer 可能致癌
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Signal word Danger
UN Number UN 2910 7
Hazard Codes T,R
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
Risk Statements
  • R33 Danger of cumulative effects 有累积作用的危险
  • R45 May cause cancer 可能致癌
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 10 gm/kg
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Liver - tumors
   Blood - tumors
REFERENCE :
   BJCAAI British Journal of Cancer.  (Macmillan Press Ltd., Houndmills,
   Basingstoke, Hants. RG21 2XS, U

{h

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 10 mg/kg
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Liver - tumors
REFERENCE :
   BJCAAI British Journal of Cancer.  (Macmillan Press Ltd., Houndmills,
   Basingstoke, Hants. RG21 2XS, UK)  V.1-    1947-  Volume(issue)/page/year:
   9,253,1955

TYPE OF T

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Intraarterial
SPECIES OBSERVED        : Human - man
DOSE/DURATION           : 1190 mg/kg
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
   Blood - lymphoma, including Hodgkin's disease
REFERENCE :
   APMIAL Acta Pathologica et Microbiologica Scandinavica.  (Copenhagen,
   Denmark)  V.1-77, 1924-69.  For publisher information, see ACPADQ.
   Volume(issue)/page/year: 53,147,1961

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 3600 mg/kg
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Liver - tumors
   Blood - tumors
REFERENCE :
   PAMIAD Pathologica et Microbiologia.  (Basel, Switzerland)  V.23-43,
   1960-75.  For publisher information, see ECEBDI.  Volume(issue)/page/year:
   25,27,1962

RTECSXO6950000
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intratracheal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >1140 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EQSSDX Environmental Quality and Safety, Supplement.  (Stuttgart, Fed. Rep.
   Ger.)  V.1-5, 1975-76. Discontinued.  Volume(issue)/page/year: 1,1,1975

其他信息

  • 外观性质:白色结晶粉末。
  • MOL 文件:1314-20-1.mol
  • 毒性:放射性物质主要通过呼吸空气、饮水、食物和皮肤伤口进入体内造成内照射。生产场所空气中铀、钍、镭粉尘,通过呼吸道进人人体,还可通过消化道或破损的皮肤进入人体,造成对人体的内照射。 铀、钍粉尘最大容许浓度0.02 mg/m 3 ,可溶性天然铀日吸入量<2.5 mg。工作人员的体表、衣物及工作场所的设备、墙壁、地面的表面污染水平,按我国“放射防护规定”执行。 稀土生产中受天然铀和钍放射性污染的地面和设备表面,需常用水冲洗,手与人体表面以及劳保用品可用普通肥皂、洗衣粉洗涤。结合较牢的表面污染,可先用肥皂,去污粉清洗,后用专门的洗涤剂进行清洗。 生产人员工作时应戴口罩、防护手套及全身防护器具如工作服、帽、鞋、围裙、套袖、护目镜等。
  • RTECS号:XO6950000
  • 用途:用于制造高温陶瓷、原子能燃料、白炽灯、电子管阴极、电弧熔融用电极、光学玻璃。用作耐火材料、催化剂等。
  • 生产方法:参考标准 指标名称@指标 二氧化钍(ThO2)/%≥@99.5 氧化铈(CeO2)/%≤@合格 铁(Fe)/%≤@0.005 重金属(以Pb计)/%≤@0.005 氧化铝(A12O3)/%≤@0.05 氧化钛(TiO2)/%≤@0.05 二氧化硅(Si02)/%≤@0.01 碳酸盐(CO3 2- )/%≤@合格 灼烧减量/%≤@0.1
  • 参考质量标准:参考标准 指标名称 指标 氢氧化钍[Th(OH)4]/%≥ 98 稀土(Re2O3) 合格 氧化铁(Fe2O3)/%≤ 0.001 氧化铅(PbO)/%≤ 0.001 氧化钛(TiO2)/%≤ 0.001 硫酸根(SO 2- )/%≤ 0.01 硝酸根(NO3 - )/%≤ 0.08 水溶解试验 合格

系列性分类


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