(+)-Diacetyl-L-tartaric anhydride (+)-二乙酰基-L-酒石酸酐

CAS 6283-74-5 MFCD00037918

化学结构图

6283-74-5
SMILES: CC(=O)O[C@H]1C(=O)OC(=O)[C@@H]1OC(C)=O

化学属性

Mol. FormulaC8H8O7
Mol. Weight216.15
Melting Point130-135°C
TSCANo
Refractive index90 ° (C=0.5, CHCl3)
Boiling Point316.55 °C at 760 mmHg

别名和识别编码

Chemical NameDi-O-acetyl-L-tartaric Anhydride
CAS Number6283-74-5
Synonym (3R,4R)-2,5-Dioxotetrahydrofuran-3,4-diyl diacetate {LY} (3R,4R)-2,5-Dioxotetrahydrofuran-3,4-diyl diacetate DATAAN O,O-diacetyl tartaric acid anhydride {} {LY} (3R,4R)-2,5-Dioxotetrahydrofuran-3,4-diyl diacetate {} {} {LY} (3R,4R)-2,5-Dioxotetrahydrofuran-3,4-diyl diacetate {} {} {} {LY} (3R,4R)-2,5-Dioxotetrahydrofuran-3,4-diyl diacetate {} {} {} {} {LY} (3R,4R)-2,5-Dioxotetrahydrofuran-3,4-diyl diacetate {} {} {} {} {} {LY} (3R,4R)-2,5-Dioxotetrahydrofuran-3,4-diyl diacetate {} {} {} {} {} {} {LY} (3R,4R)-2,5-Dioxotetrahydrofuran-3,4-diyl diacetate {} {} {} {} {} {} {} {LY} (3R,4R)-2,5-Dioxotetrahydrofuran-3,4-diyl diacetate {} {} {} {} {} {} {} {} {LY} (3R,4R)-2,5-Dioxotetrahydrofuran-3,4-diyl diacetate {} {} {} {} {} {} {} {} {} {LY} (3R,4R)-2,5-Dioxotetrahydrofuran-3,4-diyl diacetate {} {} {} {} {} {} {} {} {} {} {LY} (3R,4R)-2,5-Dioxotetrahydrofuran-3,4-diyl diacetate {} {} {} {} {} {} {} {} {} {} {} {LY} (3R,4R)-2,5-Dioxotetrahydrofuran-
EC Number228-502-7
Beilstein Registry Number87315
MDL NumberMFCD00037918
PubChem Substance ID513914
Reaxys-RN87315
Chemical Name Translation(+)-二乙酰基-L-酒石酸酐
InChIKeyXAKITKDHDMPGPW-UHFFFAOYSA-N
LabNetwork Molecule IDLN01266705
InChIInChI=1S/C8H8O7/c1-3(9)13-5-6(14-4(2)10)8(12)15-7(5)11/h5-6H,1-2H3/t5-,6-/m1/s1
Canonical SMILESO=C1[C@H](OC(C)=O)[C@@H](OC(C)=O)C(O1)=O
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分类

  • {SNA} Analytical Reagents,
  • Analytical Reagents, Analytical/Chromatography, Asymmetric Synthesis, Carboxylic Acid Anhydrides, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Derivatization Reagents, Derivatization Reagents HPLC, Organic Building Blocks, UV-VIS
  • {SNA} Asymmetric Synthesis,
  • {SNA} Asymmetric Synthesis, Carboxylic Acid Anhydrides, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Derivatization Reagents, Derivatization Reagents HPLC, Organic Building Blocks, UV-VIS, 分析/色谱, 分析试剂

相关文献及参考

  • Beil. 18 ,IV,2296
  • FT-NMR 1 (1), 1179:C / RegBook 1 (1), 837:F / Structure Index 1 , 130:D:2

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning {} {} {} {TCI}
Storage condition -20°C, sealed storage, away from moisture {LY} -20°C, sealed storage, away from moisture 2-8°C <0°C <;0 Moisture Sensitive {} {LY} -20°C, sealed storage, away from moisture {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from mo
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

其他信息

  • Acros Organics:(+)-Diacetyl-L-tartaric anhydride, 97%(6283-74-5)
  • Sigma Aldrich:6283-74-5(sigmaaldrich)
  • Alfa Aesar:二-O-乙酰基-L-酒石酸酐,97% Di-O-acetyl-L-tartaric anhydride, 97%(6283-74-5)
  • 二-O-乙酰基-L-酒石酸酐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D1911 (+)-二乙酰基-L-酒石酸酐 (+)-Diacetyl-L-tartaric Anhydride 25G 435元 2010/06/21 336040050 二-O-乙酰基-L-酒石酸酐 (+)-Diacetyl-L-tartaric anhydride 97% 5 GR 316元 2010/06/21 336041000 二-O-乙酰基-L-酒石酸酐 (+)-Diacetyl-L-tartaric anhydride 97% 100 GR 1802元
  • TCI Shanghai:(+)-二乙酰基-L-酒石酸酐 (+)-Diacetyl-L-tartaric Anhydride,>;97.0%(T)(6283-74-5)
  • F:3-10-21
  • 敏感性:Moisture Sensitive
  • MOL 文件:6283-74-5.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents HPLC - Derivatization Reagents
  5. UV-VIS - Derivatization Reagents HPLC
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  4. Chiral Resolving Reagents - Chiral Resolution Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Carboxylic Acid Anhydrides - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Carboxylic Acid Anhydrides - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Optical Resolution
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Amino Alcohols 氨基醇
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Derivatization Reagents
  4. HPLC Derivatization Reagents, by Application
  5. Thiols
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents HPLC
  4. HPLC Derivatization Reagents, by Application
  5. Thiols
  1. Functional Group 官能团索引
  2. carboxylic acid anhydride

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