4-Fluorobenzeneboronic acid 4-氟苯硼酸

CAS 1765-93-1 MFCD00039136

化学结构图

1765-93-1
SMILES: OB(O)c1ccc(F)cc1

化学属性

Mol. FormulaC6H6BFO2
Mol. Weight139.92
Melting Point262-265
TSCANo
Density1.24
Appearance white to off-white pwdr.
Boiling Point258.4±42.0 °C at 760 mmHg

别名和识别编码

Chemical Name4-Fluorobenzeneboronic acid
CAS Number1765-93-1
Alfabeta NameFLUOROPHENYLBORONICACID 4-
MDL NumberMFCD00039136
Synonym 4-Fluorobenzeneboronic acid {LY} 4-Fluorobenzeneboronic acid {} {LY} 4-Fluorobenzeneboronic acid {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorob
Beilstein Registry Number2829653
PubChem Substance ID285645
Reaxys-RN2829653
EC Number250-023-7
Chemical Name Translation4-氟苯硼酸
LabNetwork Molecule IDLN00008272
InChIInChI=1S/C6H6BFO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H
Canonical SMILESFC1=CC=C(B(O)O)C=C1
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
  • Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents

产品应用

  • 用于四溴噻吩的Suzuki偶联反应中，也用于钯催化加腈。广泛用在和芳烃四氟硼酸重氮盐、碘盐的偶联反应，以及制造活性三联苯。

相关文献及参考

  • 8. Zhang, J.; et al. , Ligand-free copper-catalyzed coupling of nitroarenes with arylboronic acids Green Chem. 4th ed., 14 , 912-916, (2012)
  • 5. Inamoto, K.; et al. , Tandem-type Pd(II)-catalyzed oxidative Heck reaction/intramolecular C-H amidation sequence: a novel route to 4-aryl-2-quinolinones Chem. Commun. 36th ed., 48 , 4332-4334, (2012) 摘要
  • 7. Xue, F.; et al. , Rhodium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Nitroalkenes Using Olefin-Sulfoxide Ligands J. Org. Chem. 7th ed., 77 , 3071-3081, (2012) 摘要
  • 6. Dastbaravardeh, N.; Schnuerch, M.; Mihovilovic, M. D. , Ruthenium(0)-Catalyzed sp3 C-H Bond Arylation of Benzylic Amines Using Arylboronates Org. Lett. 7th ed., 14 , 1930-1933, (2012) 摘要
  • Beilstein: 16,IV,1666
  • For reactions of boronic acids, see Appendix 5.
  • GC reagent for diols: J. Chromat., 158, 33 (1978); 186, 307 (1979).

安全信息

Warnings IRRITANT
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes Xn Xn,Xi Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 用途二:用于四溴噻吩的Suzuki偶联反应中，也用于钯催化加腈。广泛用在和芳烃四氟硼酸重氮盐、碘盐的偶联反应，以及制造活性三联苯。
  • Alfa Aesar:4-氟苯硼酸,97% 4-Fluorobenzeneboronic acid, 97%(1765-93-1)
  • 下游产品:6-(4-氟苯基)吡啶-2-醛
  • Hazard Note:Irritant
  • Acros Organics:4-氟苯硼酸 4-Fluorophenylboronic acid, 97%(1765-93-1)
  • 用途一:Suzuki偶联反应中的常用有机合成试剂
  • F:10-21
  • 4-氟苯硼酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw070019 4-氟苯硼酸 10g 400元 2011/04/16 F0361 4-氟苯硼酸(含有数量不等的酸酐) 4-Fluorophenylboronic Acid (contains varying amounts of Anhydride) 25G 1550元 2011/04/16 F0361 4-氟苯硼酸(含有数量不等的酸酐) 4-Fluorophenylboronic Acid (contains varying amounts of Anhydride) 5G 580元
  • Sigma Aldrich:1765-93-1(sigmaaldrich)
  • MOL 文件:1765-93-1.mol
  • TCI Shanghai:4-氟苯硼酸(含有数量不等的酸酐) 4-Fluorophenylboronic Acid (contains varying amounts of Anhydride)(1765-93-1)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. F - Alphabetic
  5. FA - FL - F
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Aryl Boronic Acids - Boronic Acids
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Aryl Boronic Acids - Boronic Acids
  6. Monosubstituted Aryl Boronic Acids - Aryl Boronic Acids
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Alkyl
  1. Functional Group 官能团索引
  2. boronic acid
  1. Boronic Acid and Ester
  2. Boron

相关产品推荐

106-53-6
609-73-4
1679-18-1
5933-40-4
768-35-4
3900-89-8
1582-24-7
126689-01-8
768-35-4