4-Methoxyphenylboronic Acid 对甲氧基苯硼酸
CAS 5720-07-0 MFCD00039139
化学结构图
SMILES: COc1ccc(B(O)O)cc1
化学属性
| Mol. Formula | CH3OC6H4B(OH)2 |
|---|---|
| Mol. Weight | 151.96 |
| Melting Point | 204-206 |
| Density | 1.422 |
| TSCA | No |
| Appearance | white to off-white pwdr. |
| Boiling Point | 306.8°C at 760 mmHg |
别名和识别编码
| Chemical Name | 4-Methoxyphenylboronic Acid |
|---|---|
| CAS Number | 5720-07-0 |
| Alfabeta Name | METHOXYPHENYLBORONICACID 4- |
| MDL Number | MFCD00039139 |
| Synonym | 4-Methoxyphenylboronic acid {LY} 4-Methoxyphenylboronic acid {} {LY} 4-Methoxyphenylboronic acid {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxy |
| Beilstein Registry Number | 2936912 |
| PubChem Substance ID | 201262 |
| EC Number | 250-023-7 |
| Chemical Name Translation | 对甲氧基苯硼酸 |
| Reaxys-RN | 2936912 |
| InChIKey | VOAAEKKFGLPLLU-UHFFFAOYSA-N |
| Wiswesser Line Notation | QBQR DO1 |
| LabNetwork Molecule ID | LN00115930 |
| InChI | InChI=1S/C7H9BO3/c1-11-7-4-2-6(3-5-7)8(9)10/h2-5,9-10H,1H3 |
| Canonical SMILES | COC1=CC=C(B(O)O)C=C1 |
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分类
- {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
- Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
相关文献及参考
- 1. Pandiarajan, D.; Ramesh, R., Suzuki-Miyaura cross-coupling reaction of aryl bromides catalyzed by palladium(II) pyridoxal hydrazone complexes J. Organomet. Chem. 708-709 , 18-24, (2012)
- 2. Lv, T.; et al., Pd-catalyzed direct arylation of phenylpyrazole: Synthesis of fipronil derivatives with aryl boronic acids promoted by a stoichiometric amount of NIS J. Fluor. Chem. 137 , 44-49, (2012)
- 3. Sartori, G.; et al. , Highly effective synthesis of C-5-substituted 2'-deoxyuridine using Suzuki-Miyaura cross-coupling in water Synthesis 5th ed., 44 , 767-772, (2012)
- 4. Yao, B.; et al. , Palladium-Catalyzed Heck-Type Reactions of Allylic Esters with Arylboronic Acids or Potassium Aryltrifluoroborates Adv. Synth. Catal. 6th ed., 354 , 1069-1076, (2012)
- 5. Inamoto, K.; et al. , Tandem-type Pd(II)-catalyzed oxidative Heck reaction/intramolecular C-H amidation sequence: a novel route to 4-aryl-2-quinolinones Chem. Commun. 36th ed., 48 , 4332-4334, (2012) 摘要
- 6. Qi, Q.; et al. , Copper-Mediated Aerobic Fluoroalkylation of Arylboronic Acids with Fluoroalkyl Iodides at Room Temperature J. Am. Chem. Soc. 15th ed., 134 , 6548-6551, (2012) 摘要
- 7. Dastbaravardeh, N.; Schnuerch, M.; Mihovilovic, M. D. , Ruthenium(0)-Catalyzed sp3 C-H Bond Arylation of Benzylic Amines Using Arylboronates Org. Lett. 7th ed., 14 , 1930-1933, (2012) 摘要
- 8. Xue, F.; et al. , Rhodium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Nitroalkenes Using Olefin-Sulfoxide Ligands J. Org. Chem. 7th ed., 77 , 3071-3081, (2012) 摘要
- 9. Zhang, J.; et al. , Ligand-free copper-catalyzed coupling of nitroarenes with arylboronic acids Green Chem. 4th ed., 14 , 912-916, (2012)
- 10. Sindhuja, E.; Ramesh, R.; Liu, Y., Palladium(II) thiocarboxamide complexes: synthe
安全信息
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 200 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#00062
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