Bromoacetone 溴丙酮

CAS 598-31-2 MFCD00039188

化学结构图

598-31-2
SMILES: CC(=O)CBr

化学属性

Mol. FormulaC3H5BrO
Mol. Weight137
Refractive index1.4670 to 1.4740
Melting Point-37
Boiling Point137
Solubility微溶于水，溶于乙醇、丙酮。
Density1.63
Flash Point51°C(lit.)

别名和识别编码

Chemical NameBromoacetone
Synonym 1-BROMO-2-PROPANONE 1-Bromo-2-Propaone 1-Bromoacetone 1-bromo-2-propanon 1-bromo-propan-2-one 1-溴丙酮 2-Propanone, 1-bromo- 2-Propanone, bromo- 2-propanone,1-bromo- Acetonyl bromide Acetyl methyl bromide Acetylmethyl bromide B-Stoff BROMO-2-PROPANONE BROMOACETONE Bromaceton Bromo-2-propanone Bromomethyl methyl ketone Bromopropanone Martonite Monobromoacetone RCRA waste number P017 acetonylbromide acetylmethylbromide alpha-Bromoacetone bromo-2-propanon bromomethylmethylketone 溴丙酮
MDL NumberMFCD00039188
CAS Number598-31-2
EC Number209-928-2
Reaxys-RN741886
Merck Number1401
Beilstein Registry Number741886
PubChem Substance ID125308557
Chemical Name Translation溴丙酮
Wiswesser Line NotationE1V1
LabNetwork Molecule IDLN00226611
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分类

  • {uni_hamburg} no charge; ketone; 1fragment

相关文献及参考

  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSUC0525000
UN Number 1569
Signal word Danger
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P340+P310
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Storage condition 0-10 0-10°C
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
Packing GroupII
Hazard Class6.1/3
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R11 Highly flammable 非常易燃
GHS Symbol
Warnings 危化品目录(2015) 
TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 572 ppm/10M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB214-270

Hazard Codes 6.1
Restrict 危险品

其他信息

  • 上游原料:乙酸 --> 碳酸钠 --> 溴 --> 丙酮 --> 无水氯化钙
  • 可燃性危险特性:明火可燃; 受热分解有毒溴化物气体
  • 毒性分级:高毒
  • 灭火剂:泡沫、干粉、砂土、二氧化碳
  • 方法一:由丙酮和溴反应得到。
  • TCI Shanghai:溴丙酮(含稳定剂氧化镁) Bromoacetone (stabilized with MgO),>;90.0%(GC)(598-31-2)
  • 急性毒性:吸入- 人 LCL0: 572 PPM/ 10分
  • 下游产品:萘丙胺 --> 三溴甲烷 --> 4,5,6,7-四氢-2-甲基呋喃[3,2-C]并吡啶 --> 1,1-二苯基丙酮 --> 羟基丙酮 --> 2-甲氧基-3-溴丙烯 --> 1-(4-氯苯基)-1-苯基丙酮
  • 用途一:有机合成中间体。
  • 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂分开存放
  • MOL 文件:598-31-2.mol
  • 外观性质:无色液体, 有刺激性臭味, 接触空气转变成紫色。
  • 溴丙酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0642 溴丙酮(含稳定剂氧化镁) Bromoacetone (stabilized with MgO) 500G 12150元 2014/06/02 B0642 溴丙酮(含稳定剂氧化镁) Bromoacetone (stabilized with MgO) 25G 1300元
  • 图谱信息:溴丙酮(598-31-2)红外图谱(IR1) 溴丙酮(598-31-2)质谱(MS) 溴丙酮(598-31-2)核磁图( 13 CNMR) 溴丙酮(598-31-2)核磁图( 1 HNMR)
  • MSDS 信息:溴丙酮(598-31-2).msds
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds

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