Bis(4-(Dimethylamino)Phenyl)Methanethione 4,4-双(二甲氨基)硫代二甲酮

CAS 1226-46-6 MFCD00040477

化学结构图

1226-46-6
SMILES: CN(C)c1ccc(C(=S)c2ccc(N(C)C)cc2)cc1

化学属性

Mol. FormulaC17H20N2S
Mol. Weight284.42
Melting Point202-206°C
Density1.1052
Boiling Point430.0±55.0 °C at 760 mmHg
Flash Point213.8±31.5 °C

别名和识别编码

Chemical NameBis(4-(Dimethylamino)Phenyl)Methanethione
Synonym Thiomichler's ketone {LY} Thiomichler's ketone thio-Michler's ketone {} {LY} Thiomichler's ketone {} {} {LY} Thiomichler's ketone {} {} {} {LY} Thiomichler's ketone {} {} {} {} {LY} Thiomichler's ketone {} {} {} {} {} { {} {} {} {} {} {LY} Thiomichler's ketone {} {} {} {} {} {} { {} {} {} {} {} {} {LY} Thiomichler's ketone {} {} {} {} {} {} {} {LY} Thiomichler's ketone {} {} {} {} {} {} {} {} {LY} Thiomichler's ketone {} {} {} {} {} {} {} {} {} {LY} Thiomichler's ketone {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Thiomichler's ketone {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Thiomichler's ketone {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiomichler's ketone {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiomichler's ketone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiomichler's ketone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00040477
CAS Number1226-46-6
PubChem Substance ID71045
EC Number214-962-6
Reaxys-RN2215339
Beilstein Registry Number2215339
Chemical Name Translation4,4-双(二甲氨基)硫代二甲酮
InChIKeyKFUJUTFTRXYQMG-UHFFFAOYSA-N
LabNetwork Molecule IDLN01024877
InChIInChI=1S/C17H20N2S/c1-18(2)15-9-5-13(6-10-15)17(20)14-7-11-16(12-8-14)19(3)4/h5-12H,1-4H3
Canonical SMILESCN(C1=CC=C(C(C2=CC=C(N(C)C)C=C2)=S)C=C1)C
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfur Compounds, Thiocarbonyl Compounds
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

产品应用

  • 测定金、钯、铂、汞和银的灵敏光度试剂。也用于测定残留氯（residual chlorine）

相关文献及参考

  • Beilstein: 14,100
  • Short: III/35D2
  • Short: EINECS

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
UN Number 2811

其他信息

  • MSDS 信息:N,N,N',N'-Tetramethyl-4,4'-diaminothiobenzophenone(1226-46-6).msds
  • MOL 文件:1226-46-6.mol
  • 易溶于热乙醇、苯和乙酸，溶于盐酸中呈深蓝色，溶于氯仿中呈深红色，不溶于石油醚和水。半数致死量(小鼠，腹腔) 250mg/kg。
  • 外观性质:深红色结晶。易溶于热乙醇、苯和乙酸，溶于盐酸中呈深蓝色，溶于氯仿中呈深红色，不溶于石油醚和水。半数致死量(小鼠，腹腔) 250mg/kg。熔点：202℃
  • 硫代米氏酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30023160 4，4-双（二甲氨基）硫代二苯甲酮 5g 120.5元 2011/04/16 A5201 硫代米蚩酮[用于金,银,汞和钯的灵敏分光光度试剂和残留氯的测定] Thiomichler's Ketone [Sensitive spectrophotometric reagent for Au, Ag, Hg and Pd, use for the determination of residual chlorine] 1G 354元 2011/04/16 A5201 硫代米蚩酮[用于金,银,汞和钯的灵敏分光光度试剂和残留氯的测定] Thiomichler's Ketone [Sensitive spectrophotometric reagent for Au, Ag, Hg and Pd, use for the determination of residual chlorine] 10G 1510元
  • 海关编码:29309070
  • 图谱信息:硫代米氏酮(1226-46-6)红外图谱(IR2) 硫代米氏酮(1226-46-6)核磁图( 13 CNMR) 硫代米氏酮(1226-46-6)质谱(MS) 硫代米氏酮(1226-46-6)核磁图( 1 HNMR) 硫代米氏酮(1226-46-6)红外图谱(IR1)
  • 用途二:测定金、钯、铂、汞和银的灵敏光度试剂。也用于测定残留氯（residual chlorine）
  • 用途一:用作测定钨的试剂
  • TCI Shanghai:硫代米蚩酮[用于金,银,汞和钯的灵敏分光光度试剂和残留氯的测定] Thiomichler's Ketone [Sensitive spectrophotometric reagent for Au, Ag, Hg and Pd, use for the determination of residual chlorine](1226-46-6)
  • Sigma Aldrich:1226-46-6(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiocarbonyl Compounds - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiocarbonyl Compounds - Sulfur Compounds
  1. Functional Group 官能团索引
  2. thioketone

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