2-Acetoxy-2-methylpropionyl bromide 2-乙酰氧基异丁酰溴

CAS 40635-67-4 MFCD00040923

化学结构图

40635-67-4
SMILES: CC(=O)OC(C)(C)C(=O)Br

化学属性

Mol. FormulaCH3COOC(CH3)2COBr
Mol. Weight209
Refractive indexn20/D 1.457(lit.)
Boiling Point75-77 °C/12 mmHg(lit.)
Density1.431 g/mL at 25 °C(lit.)
Flash Point>110°(230°F)
TSCANo

别名和识别编码

Chemical Name2-Acetoxy-2-methylpropionyl bromide
Synonym 乙酸 1-溴羰基-1-甲基乙酯 2-乙酰氧基异丁酰溴 2-Acetoxy-2-methylpropionyl bromide α-乙酰氧基异丁酰溴 2-乙酰氧基异丁酰溴 α-乙酰氧基异丁酰溴 2-Acetoxy-2-methylpropionyl bromide1-Bromocarbonyl-1-methylethyl acetate
PubChem Substance ID24862463
Beilstein Registry Number2432585
MDL NumberMFCD00040923
CAS Number40635-67-4
Chemical Name Translation2-乙酰氧基异丁酰溴
LabNetwork Molecule IDLN01281159
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分类

  • {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks

相关文献及参考

  • Reagent for conversion of glycols to bromoacetates, useful in the formation of 3'-deoxynucleosides: J. Am. Chem. Soc., 95, 4016 (1973); Tetrahedron Lett., 26, 4295 (1985); 30, 6257 (1989).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Danger
Packing GroupII
UN Number UN3265
Risk Statements
  • R37 Irritating to respiratory system 刺激呼吸道
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Storage condition Moisture Sensitive
Hazard Codes C

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Acid Halides 酸性卤化物(酰氯等)

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