4-Trifluoromethoxyaniline 对三氟甲氧基苯胺

CAS 461-82-5 MFCD00041314

化学结构图

461-82-5
SMILES: Nc1ccc(OC(F)(F)F)cc1

化学属性

Mol. FormulaC7H6F3NO
Mol. Weight177.13
Boiling Point192.4°C at 760 mmHg
Refractive index1.4620 to 1.4640
Density1.32
Flash Point81°C
TSCANo
Stability对光敏感
Appearance 1.4630，相对密度 1.3010，不溶于水，溶于苯、甲苯。 D 本品为无色液体，b.p.73～75℃/1.34kpa，n 20
pH:A

别名和识别编码

Chemical Name4-Trifluoromethoxyaniline
CAS Number461-82-5
Alfabeta NameTRIFLUOROMETHOXYANILINE 4()-
MDL NumberMFCD00041314
Synonym 4-(Trifluoromethoxy)aniline {LY} 4-(Trifluoromethoxy)aniline {} {LY} 4-(Trifluoromethoxy)aniline {} {} {LY} 4-(Trifluoromethoxy)aniline {} {} {} {LY} 4-(Trifluoromethoxy)aniline {} {} {} {} {LY} 4-(Trifluoromethoxy)aniline {} {} {} {} {} {LY} 4-(Trifluoromethoxy)aniline {} {} {} {} {} {} {LY} 4-(Trifluoromethoxy)aniline {} {} {} {} {} {} {} {LY} 4-(Trifluoromethoxy)aniline {} {} {} {} {} {} {} {} {LY} 4-(Trifluoromethoxy)aniline {} {} {} {} {} {} {} {} {} {LY} 4-(Trifluoromethoxy)aniline {} {} {} {} {} {} {} {} {} {} {LY} 4-(Trifluoromethoxy)aniline {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(Trifluoromethoxy)aniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(Trifluoromethoxy)aniline {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(Trifluoromethoxy)aniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(Trifluoromethoxy)aniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(Trifluoromethoxy)aniline {} {} {} {} {} {} {} {}
PubChem Substance ID600848
EC Number207-317-5
Beilstein Registry Number2090209
Reaxys-RN2090209
Chemical Name Translation对三氟甲氧基苯胺
LabNetwork Molecule IDLN00115331
Canonical SMILESNC1=CC=C(OC(F)(F)F)C=C1
InChIInChI=1S/C7H6F3NO/c8-7(9,10)12-6-3-1-5(11)2-4-6/h1-4H,11H2
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分类

  • Amines, Building Blocks, C7, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Amines, Building Blocks, C7, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • {Chemicalbook} 农药中间体: 杀虫剂中间体: 苯甲酰脲类杀虫剂

产品应用

  • 用于合成含氟医药、农药中间体

相关文献及参考

  • Short: III/35E
  • Beilstein: 13,IV,1030
  • Short: III/35C1

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany2
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H310 Fatal in contact with skin 皮肤接触致命
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H301 Toxic if swallowed 吞食有毒
  • H318 Causes serious eye damage 严重伤害眼睛
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes T T,Xi,Xn Xn
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P332+P313
  • P302+P350
  • P301+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338+P310
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P403+P235
  • P302+P352+P310+P361+P364
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P301+P310+P330
  • P405 Store locked up. 上锁保管。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R38 Irritating to skin 刺激皮肤
  • R33 Danger of cumulative effects 有累积作用的危险
UN Number 2941 2810
Packing GroupIII
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class6.1

其他信息

  • MSDS 信息:4-(Trifluoromethoxy)aniline(461-82-5).msds
  • 海关编码:29222900
  • 用途三:用于合成含氟医药、农药中间体
  • 对三氟甲氧基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1345 4-(三氟甲氧基)苯胺 4-(Trifluoromethoxy)aniline 250G 3850元 2014/06/02 T1345 4-(三氟甲氧基)苯胺 4-(Trifluoromethoxy)aniline 25G 775元 2014/06/02 T1345 4-(三氟甲氧基)苯胺 4-(Trifluoromethoxy)aniline 5G 262元
  • 下游产品:杀虫脲 --> 利鲁唑
  • Acros Organics:4-三氟甲氧基苯胺 4-(Trifluoromethoxy)aniline, 99+%(461-82-5)
  • 遇光呈红棕色
  • 图谱信息:对三氟甲氧基苯胺(461-82-5)核磁图( 13 CNMR) 对三氟甲氧基苯胺(461-82-5)质谱(MS) 对三氟甲氧基苯胺(461-82-5)红外图谱(IR1) 对三氟甲氧基苯胺(461-82-5)核磁图( 1 HNMR)
  • Sigma Aldrich:461-82-5(sigmaaldrich)
  • Hazard Note:Toxic
  • Alfa Aesar:4-(三氟甲氧基)苯胺,98% 4-(Trifluoromethoxy)aniline, 98%(461-82-5)
  • 用途一:用于合成含氟医药、农药中间体等
  • 用途二:4-三氟甲氧基苯胺是杀虫剂杀铃脲的中间体。
  • MOL 文件:461-82-5.mol
  • 方法一:其制备方法是将 4-三氟甲氧基硝基苯还原，得到 4-三氟甲氧基苯胺。 或用 4-三氟甲氧基苯甲酰胺在氢氧化钾水溶液中与溴反应而制得。
  • 上游原料:氢氧化钾 --> 1-硝基-4-(三氟甲氧基)苯 --> 4-(三氟甲氧基)苯甲酰胺
  • TCI Shanghai:4-三氟甲氧基苯胺 4-(Trifluoromethoxy)aniline,>;97.0%(GC)(461-82-5)

系列性分类

  1. C7 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. C10 to C11 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Fluorous Chemistry 氟化学
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺
  6. C2 to C6

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