(1,1,2,2-Tetrafluoroethoxy)benzene 1,1,2,2-四氟苯乙醚

CAS 350-57-2 MFCD00042102

化学结构图

350-57-2
SMILES: FC(F)C(F)(F)Oc1ccccc1

化学属性

Mol. FormulaC8H6F4O
Mol. Weight194.1262528
Boiling Point152-153 °C at 760 mmHg
Refractive indexn20/D 1.4200(lit.)
Density1.275
Flash Point46°(115°F)
TSCANo

别名和识别编码

Chemical Name(1,1,2,2-Tetrafluoroethoxy)benzene
CAS Number350-57-2
Alfabeta NameTETRAFLUOROETHOXYBENZENE 1122()-,,,
MDL NumberMFCD00042102
Synonym (1,1,2,2-Tetrafluoroethoxy)benzene {LY} (1,1,2,2-Tetrafluoroethoxy)benzene {} {LY} (1,1,2,2-Tetrafluoroethoxy)benzene {} {} {LY} (1,1,2,2-Tetrafluoroethoxy)benzene {} {} {} {LY} (1,1,2,2-Tetrafluoroethoxy)benzene {} {} {} {} {LY} (1,1,2,2-Tetrafluoroethoxy)benzene {} {} {} {} {} {LY} (1,1,2,2-Tetrafluoroethoxy)benzene {} {} {} {} {} {} {LY} (1,1,2,2-Tetrafluoroethoxy)benzene {} {} {} {} {} {} {} {LY} (1,1,2,2-Tetrafluoroethoxy)benzene {} {} {} {} {} {} {} {} {LY} (1,1,2,2-Tetrafluoroethoxy)benzene {} {} {} {} {} {} {} {} {} {LY} (1,1,2,2-Tetrafluoroethoxy)benzene {} {} {} {} {} {} {} {} {} {} {LY} (1,1,2,2-Tetrafluoroethoxy)benzene {} {} {} {} {} {} {} {} {} {} {} {LY} (1,1,2,2-Tetrafluoroethoxy)benzene {} {} {} {} {} {} {} {} {} {} {} {} {LY} (1,1,2,2-Tetrafluoroethoxy)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (1,1,2,2-Tetrafluoroethoxy)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (1,1,2,2-Tetrafluoroethoxy)benzene {} {} {} {} {} {} {} {} {}
PubChem Substance ID67692
EC Number206-505-4
Chemical Name Translation1,1,2,2-四氟苯乙醚
InChIKeyGRDIVJPQARIBNZ-UHFFFAOYSA-N
Beilstein Registry Number2255899
LabNetwork Molecule IDLN00112136
InChIInChI=1S/C8H6F4O/c9-7(10)8(11,12)13-6-4-2-1-3-5-6/h1-5,7H
Canonical SMILESFC(F)C(F)(F)OC1=CC=CC=C1
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分类

  • {SNA} Aryl Fluorinated Building Blocks, Building Blocks, C7-C8, C8, Chemical Synthesis, Difluoromethyl, Ethers, Fluorinated Building Blocks, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks, Oxygen Compounds
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.

安全信息

Warnings FLAMMABLE
GHS Symbol
WGK Germany2
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSDC0340000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P317
  • P337+P317
  • P362+P364
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Packing GroupIII
UN Number 1993
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
Hazard Codes 3 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 29(11),51,1985

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 29(11),51,1985

Storage condition

其他信息

  • Sigma Aldrich:350-57-2(sigmaaldrich)
  • MOL 文件:350-57-2.mol
  • Alfa Aesar:1,1,2,2-四氟乙基苯基醚,98% (1,1,2,2-Tetrafluoroethoxy)benzene, 98%(350-57-2)
  • Hazard Note:Toxic
  • 1,1,2,2-四氟苯乙醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 B25189 1,1,2,2-四氟乙基苯基醚,98% (1,1,2,2-Tetrafluoroethoxy)benzene, 98% 5g 1240元 2010/05/25 B25189 1,1,2,2-四氟乙基苯基醚,98% (1,1,2,2-Tetrafluoroethoxy)benzene, 98% 25g 4816元 2010/05/25 B25189 1,1,2,2-四氟乙基苯基醚,98% (1,1,2,2-Tetrafluoroethoxy)benzene, 98% 1g 339元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  6. C9 - Ethers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Functional Group 官能团索引
  2. orthocarboxylic acid derivative

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