Carbonyl fluoride 碳酰氟

CAS 353-50-4 MFCD00042568

化学结构图

353-50-4
SMILES: O=C(F)F

化学属性

Mol. FormulaCF2O
Mol. Weight66.01
Boiling Point-84°C
Solubility溶于水,溶于乙醇。
Melting Point-114°C
Density1,139 g/cm3

别名和识别编码

Chemical NameCarbonyl fluoride
Synonym CARBONYL DIFLUORIDE CARBONYL FLUORIDE COF2 Carbon difluoride oxide Carbon fluoride oxide Carbon fluoride oxide (COF2) Carbon oxyfiuoride Carbon oxyfluoride Carbon oxyfluoride (COF2) Carbonic difluoride Carbonyl difluoride (COF2) Carbonyl fluoride (COF2) Carbonylfluorid Difluoroformaldehyde Difluorooxomethane Difluorophosgene Fluophosgene Fluoroformyl fluoride Fluorophosgene carbondifluorideoxide carbonfluorideoxide carbonfluorideoxide(cof2) carbonicdifluoride carbonoxyfluoride carbonoxyfluoride(cof2) carbonyl difluoride carbonyl fluoride 氟光气 氟化羰
EC Number206-534-2
CAS Number353-50-4
Chemical Name Translation碳酰氟
PubChem Substance ID9623
InChIInChI=1S/CF2O/c2-1(3)4
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分类

  • {uni_hamburg} no charge; carbonyl fluoride; 1fragment

相关文献及参考

  • Short: II/14a Title: Molecular Constants: Diamagnetic Molecules Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/14a Page: 1-788 Year: 1982 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-11365-7 ISBN: 978-3-540-11365-2 Internet Resource: DOI:10.1007/b19966 RefComment: 196 figs., XI
  • Short: II/24B Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24B Year: 2000 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-65345-7 ISBN: 978-3-540-65345-5 Internet Resource: DOI:10.1007/b58835 RefComment: VIII, 525 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24B contains an introduction and tables of rotational and centrifugal distortion constants of asymmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
  • Short: II/25B Title: Structure Data Of Free Polyatomic Molecule

安全信息

Hazard Codes T
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S3/7 Keep container tightly closed in a cool place 将容器严格密闭保存在阴凉处;
  • S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时,佩带适当的呼吸器;
Risk Statements
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R34 Causes burns 会导致灼伤
UN Number 2417
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品
Hazard statements
  • H280 Contains gas under pressure; may explode if heated 内含高压气体,遇热可能爆炸。
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H330 Fatal if inhaled 吸入致命
  • H331 Toxic if inhaled 吸入中毒
  • H370 Causes damage to organs 导致器官损伤
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P330+P331
  • P302+P352
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P307+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗(见本标签上的)。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P403+P233
  • P404 Store in a closed container. 贮存于密闭容器中。
  • P405 Store locked up. 上锁保管。
  • P410+P403
  • P501 Dispose of contents/container to..… 处理内容物/容器.....

其他信息

  • 外观性质:带有刺激性的无色气体, 遇水分解。
  • HazardClass:2.3
  • Hazard Note:Highly Toxic
  • MOL 文件:353-50-4.mol

系列性分类


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