tert-Butyl 2-(dimethoxyphosphoryl)acetate 2-(二甲氧基磷酰基)乙酸叔丁酯
CAS 62327-21-3 MFCD00042939
化学结构图
SMILES: CC(C)(C)OC(=O)CP(=O)(OC)OC
化学属性
| Mol. Formula | (CH3O)2P(O)CH2COOC(CH3)3 |
|---|---|
| Mol. Weight | 224 |
| Refractive index | 1.4310 to 1.4350 |
| Boiling Point | 86-87 °C/0.02 mmHg(lit.) |
| Density | 1.131 g/mL at 20 °C(lit.) |
别名和识别编码
| Chemical Name | tert-Butyl 2-(dimethoxyphosphoryl)acetate |
|---|---|
| Synonym | (叔丁氧羰基)甲基膦酸二甲酯 tert-Butyl ((oxo)dimethoxyphosphino)acetate tert-Butyl (dimethoxyphosphinyl)acetate P,P-二甲基膦酰乙酸叔丁酯 |
| CAS Number | 62327-21-3 |
| PubChem Substance ID | 354333228 |
| Beilstein Registry Number | 4861886 |
| MDL Number | MFCD00042939 |
| Chemical Name Translation | 2-(二甲氧基磷酰基)乙酸叔丁酯 |
| Reaxys-RN | 4861886 |
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分类
- {SNA} C-C Bond Formation, Chemical Synthesis, Horner-Wadsworth-Emmons Reagents, Olefination, Synthetic Reagents
相关文献及参考
- 1. Perez-Anes, A.; et al. Org. Biomolecular Chem. 7 , 3491, (2009)
- 2. Yamazaki, Y.; et al. Tetrahedron 65 , 3688, (2009)
- 3. Saito, N.; et al J. Org. Chem. , 2759, (2008)
- 4. Lira, R.; et al. Bioorg. Med. Chem. Lett. 17 , 6797, (2007)
- 5. Moore, J. D.; et al. J. Org. Chem. 67 , 8123, (2002)
- 6. Y. Fukuyama et al. J. Am. Chem. Soc. 99 , 646, (1977) 摘要
- 7. G.W.J. Fleet et al. J. Chem. Soc. Perkin Trans. I , 905, (1984)
- 8. C. Kuroda et al. J. Org. Chem. 51 , 956, (1986)
- 9. W.J. Guilford et al. J. Am. Chem. Soc. 109 , 5013, (1987)
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P305+P351+P338+P337+P313
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P302+P352+P332+P313+P362+P364
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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