(S)-4-((Benzyloxy)Methyl)-2,2-Dimethyl-1,3-Dioxolane (S)-4-苄氧甲基-2,2-二甲基-1,3-二氧戊环
CAS 16495-03-7 MFCD00043000
化学结构图
SMILES: CC1(C)OC[C@H](COCc2ccccc2)O1
化学属性
| Mol. Formula | C13H18O3 |
|---|---|
| Mol. Weight | 222 |
| Density | 1.050 g/mL at 20 °C(lit.) |
| Boiling Point | 79-80 °C/0.05 mmHg(lit.) |
| Refractive index | 1.4920 to 1.4960 |
| Flash Point | 100°C(lit.) |
别名和识别编码
| Chemical Name | (S)-4-((Benzyloxy)Methyl)-2,2-Dimethyl-1,3-Dioxolane |
|---|---|
| CAS Number | 16495-03-7 |
| Synonym | 3-苄基-1,2-异亚丙基-sn-甘油 D-α,β-异亚丙基甘油-γ-苄醚 3-苄基-1,2-异亚丙基-sn-甘油 (4S)- 3-苄基-1,2-异亚丙基-sn-甘油 D-α,β-异亚丙基甘油-γ-苄醚 D-α,β-异亚丙基甘油-γ-苄醚 (S)-4-苄氧甲基-2,2-二甲基-1,3-二氧戊环 D-α,β-异亚丙基甘油-γ-苄醚 |
| MDL Number | MFCD00043000 |
| PubChem Substance ID | 87565005 |
| Beilstein Registry Number | 19(5)2,365 |
| Reaxys-RN | 82963 |
| Chemical Name Translation | (S)-4-苄氧甲基-2,2-二甲基-1,3-二氧戊环 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Protected Alcohols
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Protected Alcohols
产品应用
- Used in the preparation of the analogs of dioxolanes Dexoxadrol and Etoxadrol as potential phencyclidine-like agents.
相关文献及参考
- Nacro, K., et al.: Bioorg. Med. Chem. Lett., 10, 1401 (2000),
- Rodriguez, J., et al.: Anal. Biochem., 375, 196 (2008),
- 1. J. Oehlenschläger, G. Gercken Lipids 13 , 557, (1978)
- 2. B.T. Golding, P.V. Ioannou Synthesis , 423, (1977)
- 3. G. Hirth, R. Barner Helv. Chim. Acta 65 , 1059, (1982)
- 4. K. Yamauchi et al. J. Chem. Soc. Perkin Trans. I , 765, (1986)
- Beil. 19 ,V,2,365
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