6,6'-Methylenebis(2-(tert-butyl)-4-methylphenol) 2,2′-亚甲基双(6-叔丁基-4-甲基苯酚)

CAS 119-47-1 MFCD00043641

化学结构图

119-47-1
SMILES: Cc1cc(Cc2cc(C)cc(C(C)(C)C)c2O)c(O)c(C(C)(C)C)c1

化学属性

Mol. FormulaC23H32O2
Mol. Weight340.50
Melting Point123-127 °C
Density1.04g/cm3
Boiling Point187 °C at 760 mmHg

别名和识别编码

Chemical Name6,6'-Methylenebis(2-(tert-butyl)-4-methylphenol)
MDL NumberMFCD00043641
PubChem Substance ID87572307
CAS Number119-47-1
EC Number204-327-1
Reaxys-RN2062676
Synonym GERI-BP002-A {LY} GERI-BP002-A {} {LY} GERI-BP002-A {} {} {LY} GERI-BP002-A {} {} {} {LY} GERI-BP002-A {} {} {} {} {LY} GERI-BP002-A {} {} {} {} {} {LY} GERI-BP002-A {} {} {} {} {} {} {LY} GERI-BP002-A {} {} {} {} {} {} {} {LY} GERI-BP002-A {} {} {} {} {} {} {} {} {LY} GERI-BP002-A {} {} {} {} {} {} {} {} {} {LY} GERI-BP002-A {} {} {} {} {} {} {} {} {} {} {LY} GERI-BP002-A {} {} {} {} {} {} {} {} {} {} {} {LY} GERI-BP002-A {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} GERI-BP002-A {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} GERI-BP002-A {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} GERI-BP002-A {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} GERI-BP002-A {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Chemical Name Translation2,2′-亚甲基双(6-叔丁基-4-甲基苯酚)
Beilstein Registry Number2062676
Wiswesser Line Notation1X1&1&R BQ C3R BQ CX1&1&1
LabNetwork Molecule IDLN00192775
Canonical SMILESOC1=C(C(C)(C)C)C=C(C)C=C1CC2=CC(C)=CC(C(C)(C)C)=C2O
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分类

  • Materials Science, Polymer Additives, Polymer Science, Stabilizers
  • {SA} Materials Science, Polymer Additives, Polymer Science, Stabilizers
  • {SNA} Polymer Additives, Polymer Science, Stabilizers, 材料科学

相关文献及参考

  • Beil. 6 ,III,5561
  • FT-IR 2 (2), 1874:A / Structure Index 1 , 196:D:6

安全信息

RTECSPA3500000
WGK Germany1
GHS Symbol
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
Hazard statements
  • H303 May be harmfully swallowed 吞食可能有害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
Hazard Codes Xi Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R53 May cause long-term adverse effects in the aquatic environment 对水生环境有长期的有害作用
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 10 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 38(8),28,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 11 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JTSCDR Journal of Toxicological Sciences.  (Japanese Soc. of Toxicological
   Sciences, 4th Floor, Gakkai Center Bldg., 4-16, Yayoi 2-chome, Bunkyo-ku,
   Tokyo 113, Japan)  V.1-    1976-  Volume(issue)/page/year: 19,77,1994

Storage condition RT, stored under nitrogen {LY} RT, stored under nitrogen {} {LY} RT, stored under nitrogen {} {} {LY} RT, stored under nitrogen {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 上游原料:甲醛 --> 叔丁醇 --> 异丁烯
  • MSDS 信息:2,2'-Methylenebis(6-tert-butyl-4-methylphenol)(119-47-1).msds
  • 用途二:抗氧化剂2246(2,2-亚甲基双-(4-甲基-6-叔丁基苯酚))是一种性能卓越的高效非污染型抗氧剂。在橡胶工业中, 抗氧化剂2246是合成橡胶, 胶乳和天然胶的抗氧剂, 是酚类抗氧剂中较优良的品种之一。加入抗氧化剂2246(119-47-1)的橡胶制品可抗热氧老化, 部分地防止光照臭氧老化和多次变形的破坏。并能钝化可变价金属的盐类。用于浅色和有色橡胶制品, 在塑料工业中, 抗氧化剂2246能阻止氯化聚醚, 耐冲击聚苯乙烯, ABS树脂, 聚甲醛, 纤维素树脂的热老化和光老化, 用量为0.5-1%
  • MOL 文件:119-47-1.mol
  • TCI Shanghai:2,2'-亚甲基双-(4-甲基-6-叔丁基苯酚) 2,2'-Methylenebis(6-tert-butyl-p-cresol),>;99.0%(GC)(119-47-1)
  • 检测项目参考:纯度： ≥99% 灰份：≤0.1% 色度(APHA)：50-100 铜含量：≤5ppm 挥发物：≤0.3% 锰含量：≤1 ppm 100目筛余物： 无
  • 图谱信息:2,2'-亚甲基双-(4-甲基-6-叔丁基苯酚)(119-47-1)红外图谱(IR1) 2,2'-亚甲基双-(4-甲基-6-叔丁基苯酚)(119-47-1)质谱(MS) 2,2'-亚甲基双-(4-甲基-6-叔丁基苯酚)(119-47-1)红外图谱(IR2) 2,2'-亚甲基双-(4-甲基-6-叔丁基苯酚)(119-47-1)核磁图( 1 HNMR) 2,2'-亚甲基双-(4-甲基-6-叔丁基苯酚)(119-47-1)核磁图( 13 CNMR)
  • Sigma Aldrich:119-47-1(sigmaaldrich)
  • 2,2'-亚甲基双-(4-甲基-6-叔丁基苯酚)价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0217 2,2'-亚甲基双(6-叔丁基对甲酚) 2,2'-Methylenebis(6-tert-butyl-p-cresol) 500G 1140元 2014/06/02 M0217 2,2'-亚甲基双(6-叔丁基对甲酚) 2,2'-Methylenebis(6-tert-butyl-p-cresol) 25G 185元
  • 用途一:通用型酚类防老剂，广泛用于天然橡胶、合成橡胶、乳胶、其他多种合成材料和石油制品中作抗氧剂
  • 海关编码:29072900
  • 外观:乳白色、白色、灰白至浅黄色粉末

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Protected Alcohols/Phenols - Oxygen Compounds
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Polymer Additives - Polymer Science
  4. Stabilizers - Polymer Additives

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