N1,N4-Di-Sec-Butylbenzene-1,4-Diamine N,N-二仲丁基对苯二胺

CAS 101-96-2 MFCD00043658

化学结构图

101-96-2
SMILES: CCC(C)Nc1ccc(NC(C)CC)cc1

化学属性

Mol. FormulaC14H24N2
Mol. Weight220.36
Refractive index1.5330 to 1.5390
Melting Point17.8 °C
Density0.942 g/mL at 20 °C(lit.)
Solubility<0.1 G/100 ML AT 20 ºC
Flash Point100°C
Boiling Point159 °C at 7 mmHg

别名和识别编码

Chemical NameN1,N4-Di-Sec-Butylbenzene-1,4-Diamine
MDL NumberMFCD00043658
CAS Number101-96-2
Synonym N1,N4-Di-sec-butylbenzene-1,4-diamine {LY} N1,N4-Di-sec-butylbenzene-1,4-diamine {} {LY} N1,N4-Di-sec-butylbenzene-1,4-diamine {} {} {LY} N1,N4-Di-sec-butylbenzene-1,4-diamine {} {} {} {LY} N1,N4-Di-sec-butylbenzene-1,4-diamine {} {} {} {} {LY} N1,N4-Di-sec-butylbenzene-1,4-diamine {} {} {} {} {} {LY} N1,N4-Di-sec-butylbenzene-1,4-diamine {} {} {} {} {} {} {LY} N1,N4-Di-sec-butylbenzene-1,4-diamine {} {} {} {} {} {} {} {LY} N1,N4-Di-sec-butylbenzene-1,4-diamine {} {} {} {} {} {} {} {} {LY} N1,N4-Di-sec-butylbenzene-1,4-diamine {} {} {} {} {} {} {} {} {} {LY} N1,N4-Di-sec-butylbenzene-1,4-diamine {} {} {} {} {} {} {} {} {} {} {LY} N1,N4-Di-sec-butylbenzene-1,4-diamine {} {} {} {} {} {} {} {} {} {} {} {LY} N1,N4-Di-sec-butylbenzene-1,4-diamine {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} N1,N4-Di-sec-butylbenzene-1,4-diamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N1,N4-Di-sec-butylbenzene
EC Number202-992-2
Beilstein Registry Number13(4)111
Reaxys-RN2805827
PubChem Substance ID87568705
Chemical Name TranslationN,N-二仲丁基对苯二胺
Wiswesser Line Notation2Y1&MR DMY2&1
LabNetwork Molecule IDLN01325547
InChIInChI=1S/C14H24N2/c1-5-11(3)15-13-7-9-14(10-8-13)16-12(4)6-2/h7-12,15-16H,5-6H2,1-4H3
Canonical SMILESCCC(NC1=CC=C(NC(C)CC)C=C1)C
信息真实价格透明    资金保障    专业采购外包团队在线服务   
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品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Amines, Building Blocks, C14, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

产品应用

  • 本品属性能优良的胺类抗氧剂,特别适合用作裂解或热裂解法汽油(高烯烃含量汽油)添加剂,能有效阻止烯烃氧化产生凝胶,此外,本品还可用作天然胶、合成胶的通用型抗氧剂。

相关文献及参考

  • Beilstein:13(4)111
  • Short: EINECS
  • Short: IV/20C

安全信息

Hazard Codes T,N C C,N,T
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R50/53
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R34 Causes burns 会导致灼伤
  • R38 Irritating to skin 刺激皮肤
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
UN Number 2922 UN 2922 8/PG 2
GHS Symbol
WGK Germany3
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H318 Causes serious eye damage 严重伤害眼睛
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
RTECSSS9040000
Packing GroupIII
Hazard Class8/6.1
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 148 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Gastrointestinal - other changes
   Kidney, Ureter, Bladder - other changes in urine composition
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0555010

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 600 mg/m3/6H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   KODAK* Kodak Company Reports.  (343 State St., Rochester, NY 14650)
   Volume(issue)/page/year: 21MAY1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 10 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   IPSTB3 International Polymer Science and Technology.  (Rapra Technology
   Ltd., Shawbury, Shrewsbury, Shropshire SY4 4NR, UK) Volume(issue)/page/year:
   3,93,1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2806 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Kidney, Ureter, Bladder - other changes in urine composition
   Skin and Appendages - dermatitis, other (after systemic exposure)
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse

TYPE OF TEST

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 禁忌物:酸类、氧化剂
  • 蒸发热(cal/mol):15300
  • MSDS 信息:N,N'-Di-sec-butyl-p-phenylenediamine(101-96-2).msds
  • 用途二:本品属性能优良的胺类抗氧剂,特别适合用作裂解或热裂解法汽油(高烯烃含量汽油)添加剂,能有效阻止烯烃氧化产生凝胶,从而避免油品使用过程中在燃烧室、活塞顶、汽缸盖等部位产生积炭,与其他胺类抗氧剂相比,本品用量少、抗氧化效果好,大大减少环境污染。此外,本品还可用作天然胶、合成胶的通用型抗氧剂。
  • 稳定性:正常温度和压力下稳定
  • 与烃油完全混溶,溶于稀无机酸,难溶于稀碱和水。
  • 图谱信息:N,N'-二仲丁基对苯二胺(101-96-2)质谱(MS) N,N'-二仲丁基对苯二胺(101-96-2)红外图谱(IR1) N,N'-二仲丁基对苯二胺(101-96-2)核磁图( 1 HNMR) N,N'-二仲丁基对苯二胺(101-96-2)核磁图( 13 CNMR)
  • Sigma Aldrich:101-96-2(sigmaaldrich)
  • TCI Shanghai:N,N'-二仲丁基-1,4苯二胺 N,N'-Di-sec-butyl-1,4-phenylenediamine,>;98.0%(GC)(101-96-2)
  • F:10-23
  • 包装:铁桶包装
  • 外观:红色至棕色液体,无特殊气味。
  • 储运:贮存于阴凉、通风、干燥处,按一般化学品运输。
  • N,N'-二仲丁基对苯二胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D2268 N,N'-二仲丁基-1,4苯二胺 N,N'-Di-sec-butyl-1,4-phenylenediamine 500ML 1890元 2014/06/02 D2268 N,N'-二仲丁基-1,4苯二胺 N,N'-Di-sec-butyl-1,4-phenylenediamine 25ML 319元
  • MOL 文件:101-96-2.mol
  • 用途一:101-96-2(抗氧剂44PD)是性能优良的胺类抗氧剂,在多种石油产品中起到优异的抗氧化效果。具有优异的自由基和脱硫性能。广泛应用于矿物油、加氢油、合成油和植物油等。
  • 分解产物:一氧化碳、二氧化碳、氮氧化物、氮
  • 饱和蒸气压(Kpa):10.0mmHg/170℃
  • 危险类别:第8.2类碱性腐蚀品(国内暂不属于危险化学品范畴)

系列性分类


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