Bis(Triphenylphosphine)Rhodium(I) Carbonyl Chloride 双(三苯基膦)合氯化羰基铑(I)

CAS 13938-94-8 MFCD00044273

化学结构图

13938-94-8
SMILES: [C-]#[O+].Cl[Rh].C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1.C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaRhCl(CO)(P(C6H5)3)2
Mol. Weight691
Melting Point224-227 °C (dec.)(lit.)
SolubilitySoluble in acetone, chloroform, ethanol
TSCANo

别名和识别编码

Chemical NameBis(Triphenylphosphine)Rhodium(I) Carbonyl Chloride
Synonym Carbonylbis(triphenylphosphine)rhodium(I) chloride 氯化羰基双三苯基磷基铷 双(三苯基膦)合氯化羰基铑(I) 二(三苯基膦)羰基氯化铑(I) 羰基双三苯基磷氯化铑 RhCl(CO)(PPh3)2 二(三苯基膦)羰基氯化铑(I) 羰基双三苯基磷氯化铑
MDL NumberMFCD00044273
PubChem Substance ID87564593
Beilstein Registry Number16(4)954
EC Number237-712-8
CAS Number13938-94-8
Reaxys-RN4618896
Chemical Name Translation双(三苯基膦)合氯化羰基铑(I)
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium

相关文献及参考

  • Catalyst for the decarbonylation of aldehydes and acyl halides: J. Am. Chem. Soc., 89, 2338 (1967); 90, 99 (1968); Tetrahedron Lett., 4713 (1966).
  • Effective catalyst for the high-yield, stereoselective chloroesterification of terminal alkynes with alkyl chloroformates: J. Am. Chem. Soc., 120, 12365 (1998):

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Hazard Codes Xn
Storage condition Hygroscopic
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
GHS Symbol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rhodium 铑
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rhodium 铑
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Functional Group 官能团索引
  2. phosphine

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